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[(Z)-O-Ethyl-N-propyl­thio­carbamato-κS](triphenyl­phosphine-κP)gold(I)

The title compound, [Au(C(6)H(12)NOS)(C(18)H(15)P)], features a linear S,P-donor set about the central Au atom with a deviation from linearity [S—Au—P = 176.66 (5)°] due to an intra­molecular Au⋯O contact [2.991 (5) Å]. Supra­molecular dimers are formed in the crystal structure mediated by C—H⋯N int...

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Detalles Bibliográficos
Autores principales: Tadbuppa, Primjira P., Tiekink, Edward R. T.
Formato: Texto
Lenguaje:English
Publicado: International Union of Crystallography 2009
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2971786/
https://www.ncbi.nlm.nih.gov/pubmed/21578605
http://dx.doi.org/10.1107/S1600536809047254
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author Tadbuppa, Primjira P.
Tiekink, Edward R. T.
author_facet Tadbuppa, Primjira P.
Tiekink, Edward R. T.
author_sort Tadbuppa, Primjira P.
collection PubMed
description The title compound, [Au(C(6)H(12)NOS)(C(18)H(15)P)], features a linear S,P-donor set about the central Au atom with a deviation from linearity [S—Au—P = 176.66 (5)°] due to an intra­molecular Au⋯O contact [2.991 (5) Å]. Supra­molecular dimers are formed in the crystal structure mediated by C—H⋯N inter­actions.
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spelling pubmed-29717862010-12-30 [(Z)-O-Ethyl-N-propyl­thio­carbamato-κS](triphenyl­phosphine-κP)gold(I) Tadbuppa, Primjira P. Tiekink, Edward R. T. Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers The title compound, [Au(C(6)H(12)NOS)(C(18)H(15)P)], features a linear S,P-donor set about the central Au atom with a deviation from linearity [S—Au—P = 176.66 (5)°] due to an intra­molecular Au⋯O contact [2.991 (5) Å]. Supra­molecular dimers are formed in the crystal structure mediated by C—H⋯N inter­actions. International Union of Crystallography 2009-11-14 /pmc/articles/PMC2971786/ /pubmed/21578605 http://dx.doi.org/10.1107/S1600536809047254 Text en © Tadbuppa and Tiekink 2009 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Metal-Organic Papers
Tadbuppa, Primjira P.
Tiekink, Edward R. T.
[(Z)-O-Ethyl-N-propyl­thio­carbamato-κS](triphenyl­phosphine-κP)gold(I)
title [(Z)-O-Ethyl-N-propyl­thio­carbamato-κS](triphenyl­phosphine-κP)gold(I)
title_full [(Z)-O-Ethyl-N-propyl­thio­carbamato-κS](triphenyl­phosphine-κP)gold(I)
title_fullStr [(Z)-O-Ethyl-N-propyl­thio­carbamato-κS](triphenyl­phosphine-κP)gold(I)
title_full_unstemmed [(Z)-O-Ethyl-N-propyl­thio­carbamato-κS](triphenyl­phosphine-κP)gold(I)
title_short [(Z)-O-Ethyl-N-propyl­thio­carbamato-κS](triphenyl­phosphine-κP)gold(I)
title_sort [(z)-o-ethyl-n-propyl­thio­carbamato-κs](triphenyl­phosphine-κp)gold(i)
topic Metal-Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2971786/
https://www.ncbi.nlm.nih.gov/pubmed/21578605
http://dx.doi.org/10.1107/S1600536809047254
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