Cargando…
[2-(4-Methylpiperazin-1-ylmethyl)phenyl]diphenylphosphane
In the title compound, C(24)H(27)N(2)P, the P atom is bonded to three C atoms in a trigonal–pyramidal geometry. The overall Ψ-trigonal-bipyramidal coordination of the P atom is established when the contribution of the electron lone pair and of the N—P donor–acceptor distance of 3.051 (3)Å are consid...
| Autores principales: | , , |
|---|---|
| Formato: | Texto |
| Lenguaje: | English |
| Publicado: |
International Union of Crystallography
2009
|
| Materias: | |
| Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2971789/ https://www.ncbi.nlm.nih.gov/pubmed/21578904 http://dx.doi.org/10.1107/S1600536809049526 |
| Sumario: | In the title compound, C(24)H(27)N(2)P, the P atom is bonded to three C atoms in a trigonal–pyramidal geometry. The overall Ψ-trigonal-bipyramidal coordination of the P atom is established when the contribution of the electron lone pair and of the N—P donor–acceptor distance of 3.051 (3)Å are considered. The 4-methylpiperazinyl ring adopts a chair conformation. Intra- and intermolecular C—H⋯π hydrogen bonding leads to the consolidation of the structure. |
|---|