[2-(4-Methyl­piperazin-1-ylmeth­yl)phen­yl]diphenyl­phosphane

In the title compound, C(24)H(27)N(2)P, the P atom is bonded to three C atoms in a trigonal–pyramidal geometry. The overall Ψ-trigonal-bipyramidal coordination of the P atom is established when the contribution of the electron lone pair and of the N—P donor–acceptor distance of 3.051 (3)Å are consid...

Descripción completa

Detalles Bibliográficos
Autores principales: Covaci, Ancuţa, Raţ, Ciprian I., Silvestru, Cristian
Formato: Texto
Lenguaje:English
Publicado: International Union of Crystallography 2009
Materias:
Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2971789/
https://www.ncbi.nlm.nih.gov/pubmed/21578904
http://dx.doi.org/10.1107/S1600536809049526
_version_ 1782190669614284800
author Covaci, Ancuţa
Raţ, Ciprian I.
Silvestru, Cristian
author_facet Covaci, Ancuţa
Raţ, Ciprian I.
Silvestru, Cristian
author_sort Covaci, Ancuţa
collection PubMed
description In the title compound, C(24)H(27)N(2)P, the P atom is bonded to three C atoms in a trigonal–pyramidal geometry. The overall Ψ-trigonal-bipyramidal coordination of the P atom is established when the contribution of the electron lone pair and of the N—P donor–acceptor distance of 3.051 (3)Å are considered. The 4-methyl­piperazinyl ring adopts a chair conformation. Intra- and inter­molecular C—H⋯π hydrogen bonding leads to the consolidation of the structure.
format Text
id pubmed-2971789
institution National Center for Biotechnology Information
language English
publishDate 2009
publisher International Union of Crystallography
record_format MEDLINE/PubMed
spelling pubmed-29717892010-12-30 [2-(4-Methyl­piperazin-1-ylmeth­yl)phen­yl]diphenyl­phosphane Covaci, Ancuţa Raţ, Ciprian I. Silvestru, Cristian Acta Crystallogr Sect E Struct Rep Online Organic Papers In the title compound, C(24)H(27)N(2)P, the P atom is bonded to three C atoms in a trigonal–pyramidal geometry. The overall Ψ-trigonal-bipyramidal coordination of the P atom is established when the contribution of the electron lone pair and of the N—P donor–acceptor distance of 3.051 (3)Å are considered. The 4-methyl­piperazinyl ring adopts a chair conformation. Intra- and inter­molecular C—H⋯π hydrogen bonding leads to the consolidation of the structure. International Union of Crystallography 2009-11-25 /pmc/articles/PMC2971789/ /pubmed/21578904 http://dx.doi.org/10.1107/S1600536809049526 Text en © Covaci et al. 2009 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Organic Papers
Covaci, Ancuţa
Raţ, Ciprian I.
Silvestru, Cristian
[2-(4-Methyl­piperazin-1-ylmeth­yl)phen­yl]diphenyl­phosphane
title [2-(4-Methyl­piperazin-1-ylmeth­yl)phen­yl]diphenyl­phosphane
title_full [2-(4-Methyl­piperazin-1-ylmeth­yl)phen­yl]diphenyl­phosphane
title_fullStr [2-(4-Methyl­piperazin-1-ylmeth­yl)phen­yl]diphenyl­phosphane
title_full_unstemmed [2-(4-Methyl­piperazin-1-ylmeth­yl)phen­yl]diphenyl­phosphane
title_short [2-(4-Methyl­piperazin-1-ylmeth­yl)phen­yl]diphenyl­phosphane
title_sort [2-(4-methyl­piperazin-1-ylmeth­yl)phen­yl]diphenyl­phosphane
topic Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2971789/
https://www.ncbi.nlm.nih.gov/pubmed/21578904
http://dx.doi.org/10.1107/S1600536809049526
work_keys_str_mv AT covaciancuta 24methylpiperazin1ylmethylphenyldiphenylphosphane
AT ratcipriani 24methylpiperazin1ylmethylphenyldiphenylphosphane
AT silvestrucristian 24methylpiperazin1ylmethylphenyldiphenylphosphane

Ejemplares similares