Bis[2-(ethoxy­carbonyl­amino)ethan­aminium] hexa­bromidostannate

In the title salt, (C(5)H(13)N(2)O(2))(2)[SnBr(6)], the Sn atom (site symmetry [Image: see text]) exists in a slightly distorted octa­hedral geometry. The cation is non-planar as the terminal CH(2)NH(3) (+) residue lies below the plane defined by the remaining non-H atoms. In the crystal, cations as...

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Autores principales: Howie, R. Alan, de Lima, Geraldo M., Tiekink, Edward R. T., Wardell, James L., Wardell, Solange M. S. V.
Formato: Texto
Lenguaje:English
Publicado: International Union of Crystallography 2009
Materias:
Metal-Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2971790/
https://www.ncbi.nlm.nih.gov/pubmed/21578598
http://dx.doi.org/10.1107/S160053680904687X
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author Howie, R. Alan
de Lima, Geraldo M.
Tiekink, Edward R. T.
Wardell, James L.
Wardell, Solange M. S. V.
author_facet Howie, R. Alan
de Lima, Geraldo M.
Tiekink, Edward R. T.
Wardell, James L.
Wardell, Solange M. S. V.
author_sort Howie, R. Alan
collection PubMed
description In the title salt, (C(5)H(13)N(2)O(2))(2)[SnBr(6)], the Sn atom (site symmetry [Image: see text]) exists in a slightly distorted octa­hedral geometry. The cation is non-planar as the terminal CH(2)NH(3) (+) residue lies below the plane defined by the remaining non-H atoms. In the crystal, cations associate via N—H⋯O hydrogen bonds involving the ammonium and carbonyl residues, forming a 14-membered {⋯HNC(2)NCO}(2) synthon. The cations and anions are arranged in alternating layers arranged along the a-axis direction, the major association between them being N—H⋯Br contacts.
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spelling pubmed-29717902010-12-30 Bis[2-(ethoxy­carbonyl­amino)ethan­aminium] hexa­bromidostannate Howie, R. Alan de Lima, Geraldo M. Tiekink, Edward R. T. Wardell, James L. Wardell, Solange M. S. V. Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers In the title salt, (C(5)H(13)N(2)O(2))(2)[SnBr(6)], the Sn atom (site symmetry [Image: see text]) exists in a slightly distorted octa­hedral geometry. The cation is non-planar as the terminal CH(2)NH(3) (+) residue lies below the plane defined by the remaining non-H atoms. In the crystal, cations associate via N—H⋯O hydrogen bonds involving the ammonium and carbonyl residues, forming a 14-membered {⋯HNC(2)NCO}(2) synthon. The cations and anions are arranged in alternating layers arranged along the a-axis direction, the major association between them being N—H⋯Br contacts. International Union of Crystallography 2009-11-11 /pmc/articles/PMC2971790/ /pubmed/21578598 http://dx.doi.org/10.1107/S160053680904687X Text en © Howie et al. 2009 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Metal-Organic Papers
Howie, R. Alan
de Lima, Geraldo M.
Tiekink, Edward R. T.
Wardell, James L.
Wardell, Solange M. S. V.
Bis[2-(ethoxy­carbonyl­amino)ethan­aminium] hexa­bromidostannate
title Bis[2-(ethoxy­carbonyl­amino)ethan­aminium] hexa­bromidostannate
title_full Bis[2-(ethoxy­carbonyl­amino)ethan­aminium] hexa­bromidostannate
title_fullStr Bis[2-(ethoxy­carbonyl­amino)ethan­aminium] hexa­bromidostannate
title_full_unstemmed Bis[2-(ethoxy­carbonyl­amino)ethan­aminium] hexa­bromidostannate
title_short Bis[2-(ethoxy­carbonyl­amino)ethan­aminium] hexa­bromidostannate
title_sort bis[2-(ethoxy­carbonyl­amino)ethan­aminium] hexa­bromidostannate
topic Metal-Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2971790/
https://www.ncbi.nlm.nih.gov/pubmed/21578598
http://dx.doi.org/10.1107/S160053680904687X
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