Tetra­aqua­bis(pyridine-κN)cobalt(II) bis­[4-amino-N-(6-chloro­pyridazin-3-yl)benzene­sulfonamidate]

The structure of the title compound, [Co(C(5)H(5)N)(2)(H(2)O)(4)](C(10)H(8)ClN(4)O(2)S)(2), consists of a discrete tetra­aqua­bis(pyridine-κN)cobalt(II) cation and two 4-amino-N-(6-chloro­pyridazin-3-yl)benzene­sulfonamidate anions. In the cation, the Co(II) ion sits on an inversion centre and is oc...

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Detalles Bibliográficos
Autores principales: Li, Nan, Zou, Hong-Li, Song, Xiao-Yan, Liu, Yan-Cheng, Chen, Zhen-Feng
Formato: Texto
Lenguaje:English
Publicado: International Union of Crystallography 2009
Materias:
Metal-Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2971792/
https://www.ncbi.nlm.nih.gov/pubmed/21578676
http://dx.doi.org/10.1107/S1600536809049599
Descripción
Sumario:The structure of the title compound, [Co(C(5)H(5)N)(2)(H(2)O)(4)](C(10)H(8)ClN(4)O(2)S)(2), consists of a discrete tetra­aqua­bis(pyridine-κN)cobalt(II) cation and two 4-amino-N-(6-chloro­pyridazin-3-yl)benzene­sulfonamidate anions. In the cation, the Co(II) ion sits on an inversion centre and is octa­hedrally coordinated by two pyridine N atoms and four O atoms. A two-dimensional network parallel to (010) is formed via inter­molecular O—H⋯O, O—H⋯N, N—H⋯N and N—H⋯O hydrogen bonds.

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