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Diacetato{4′-[4-(benz­yloxy)phen­yl]-2,2′:6′,2′′-terpyridine}zinc(II)

In the title compound, [Zn(CH(3)COO)(2)(C(28)H(21)N(3)O)], the Zn(II) ion is in a trigonal–bipyramidal ZnN(3)O(2) coordination with a tridentate N-chelating 4′-[4-(benz­yloxy)phen­yl)-2,2′:6′,2′′-terpyridine ligand in the equatorial position and two acetate anions in the axial positions. The three p...

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Detalles Bibliográficos
Autores principales: Li, Wei, Lu, Zhan Guo
Formato: Texto
Lenguaje:English
Publicado: International Union of Crystallography 2009
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2971799/
https://www.ncbi.nlm.nih.gov/pubmed/21578680
http://dx.doi.org/10.1107/S1600536809049502
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author Li, Wei
Lu, Zhan Guo
author_facet Li, Wei
Lu, Zhan Guo
author_sort Li, Wei
collection PubMed
description In the title compound, [Zn(CH(3)COO)(2)(C(28)H(21)N(3)O)], the Zn(II) ion is in a trigonal–bipyramidal ZnN(3)O(2) coordination with a tridentate N-chelating 4′-[4-(benz­yloxy)phen­yl)-2,2′:6′,2′′-terpyridine ligand in the equatorial position and two acetate anions in the axial positions. The three pyridine rings are approximately coplanar, with a maximum deviation of 0.03 Å from the mean plane. The phen­oxy substituent makes a dihedral angle of 18.1 (2)° with the central pyridine ring. The benzyl group has a C—O—C—C torsion angle of 77.62 (8)° relative to the phen­oxy ring. In the crystal, mol­ecules are linked via C—H⋯O hydrogen bonds.
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spelling pubmed-29717992010-12-30 Diacetato{4′-[4-(benz­yloxy)phen­yl]-2,2′:6′,2′′-terpyridine}zinc(II) Li, Wei Lu, Zhan Guo Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers In the title compound, [Zn(CH(3)COO)(2)(C(28)H(21)N(3)O)], the Zn(II) ion is in a trigonal–bipyramidal ZnN(3)O(2) coordination with a tridentate N-chelating 4′-[4-(benz­yloxy)phen­yl)-2,2′:6′,2′′-terpyridine ligand in the equatorial position and two acetate anions in the axial positions. The three pyridine rings are approximately coplanar, with a maximum deviation of 0.03 Å from the mean plane. The phen­oxy substituent makes a dihedral angle of 18.1 (2)° with the central pyridine ring. The benzyl group has a C—O—C—C torsion angle of 77.62 (8)° relative to the phen­oxy ring. In the crystal, mol­ecules are linked via C—H⋯O hydrogen bonds. International Union of Crystallography 2009-11-25 /pmc/articles/PMC2971799/ /pubmed/21578680 http://dx.doi.org/10.1107/S1600536809049502 Text en © Li and Lu 2009 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Metal-Organic Papers
Li, Wei
Lu, Zhan Guo
Diacetato{4′-[4-(benz­yloxy)phen­yl]-2,2′:6′,2′′-terpyridine}zinc(II)
title Diacetato{4′-[4-(benz­yloxy)phen­yl]-2,2′:6′,2′′-terpyridine}zinc(II)
title_full Diacetato{4′-[4-(benz­yloxy)phen­yl]-2,2′:6′,2′′-terpyridine}zinc(II)
title_fullStr Diacetato{4′-[4-(benz­yloxy)phen­yl]-2,2′:6′,2′′-terpyridine}zinc(II)
title_full_unstemmed Diacetato{4′-[4-(benz­yloxy)phen­yl]-2,2′:6′,2′′-terpyridine}zinc(II)
title_short Diacetato{4′-[4-(benz­yloxy)phen­yl]-2,2′:6′,2′′-terpyridine}zinc(II)
title_sort diacetato{4′-[4-(benz­yloxy)phen­yl]-2,2′:6′,2′′-terpyridine}zinc(ii)
topic Metal-Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2971799/
https://www.ncbi.nlm.nih.gov/pubmed/21578680
http://dx.doi.org/10.1107/S1600536809049502
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