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Diacetato{4′-[4-(benzyloxy)phenyl]-2,2′:6′,2′′-terpyridine}zinc(II)
In the title compound, [Zn(CH(3)COO)(2)(C(28)H(21)N(3)O)], the Zn(II) ion is in a trigonal–bipyramidal ZnN(3)O(2) coordination with a tridentate N-chelating 4′-[4-(benzyloxy)phenyl)-2,2′:6′,2′′-terpyridine ligand in the equatorial position and two acetate anions in the axial positions. The three p...
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Formato: | Texto |
Lenguaje: | English |
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International Union of Crystallography
2009
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Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2971799/ https://www.ncbi.nlm.nih.gov/pubmed/21578680 http://dx.doi.org/10.1107/S1600536809049502 |
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author | Li, Wei Lu, Zhan Guo |
author_facet | Li, Wei Lu, Zhan Guo |
author_sort | Li, Wei |
collection | PubMed |
description | In the title compound, [Zn(CH(3)COO)(2)(C(28)H(21)N(3)O)], the Zn(II) ion is in a trigonal–bipyramidal ZnN(3)O(2) coordination with a tridentate N-chelating 4′-[4-(benzyloxy)phenyl)-2,2′:6′,2′′-terpyridine ligand in the equatorial position and two acetate anions in the axial positions. The three pyridine rings are approximately coplanar, with a maximum deviation of 0.03 Å from the mean plane. The phenoxy substituent makes a dihedral angle of 18.1 (2)° with the central pyridine ring. The benzyl group has a C—O—C—C torsion angle of 77.62 (8)° relative to the phenoxy ring. In the crystal, molecules are linked via C—H⋯O hydrogen bonds. |
format | Text |
id | pubmed-2971799 |
institution | National Center for Biotechnology Information |
language | English |
publishDate | 2009 |
publisher | International Union of Crystallography |
record_format | MEDLINE/PubMed |
spelling | pubmed-29717992010-12-30 Diacetato{4′-[4-(benzyloxy)phenyl]-2,2′:6′,2′′-terpyridine}zinc(II) Li, Wei Lu, Zhan Guo Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers In the title compound, [Zn(CH(3)COO)(2)(C(28)H(21)N(3)O)], the Zn(II) ion is in a trigonal–bipyramidal ZnN(3)O(2) coordination with a tridentate N-chelating 4′-[4-(benzyloxy)phenyl)-2,2′:6′,2′′-terpyridine ligand in the equatorial position and two acetate anions in the axial positions. The three pyridine rings are approximately coplanar, with a maximum deviation of 0.03 Å from the mean plane. The phenoxy substituent makes a dihedral angle of 18.1 (2)° with the central pyridine ring. The benzyl group has a C—O—C—C torsion angle of 77.62 (8)° relative to the phenoxy ring. In the crystal, molecules are linked via C—H⋯O hydrogen bonds. International Union of Crystallography 2009-11-25 /pmc/articles/PMC2971799/ /pubmed/21578680 http://dx.doi.org/10.1107/S1600536809049502 Text en © Li and Lu 2009 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited. |
spellingShingle | Metal-Organic Papers Li, Wei Lu, Zhan Guo Diacetato{4′-[4-(benzyloxy)phenyl]-2,2′:6′,2′′-terpyridine}zinc(II) |
title | Diacetato{4′-[4-(benzyloxy)phenyl]-2,2′:6′,2′′-terpyridine}zinc(II) |
title_full | Diacetato{4′-[4-(benzyloxy)phenyl]-2,2′:6′,2′′-terpyridine}zinc(II) |
title_fullStr | Diacetato{4′-[4-(benzyloxy)phenyl]-2,2′:6′,2′′-terpyridine}zinc(II) |
title_full_unstemmed | Diacetato{4′-[4-(benzyloxy)phenyl]-2,2′:6′,2′′-terpyridine}zinc(II) |
title_short | Diacetato{4′-[4-(benzyloxy)phenyl]-2,2′:6′,2′′-terpyridine}zinc(II) |
title_sort | diacetato{4′-[4-(benzyloxy)phenyl]-2,2′:6′,2′′-terpyridine}zinc(ii) |
topic | Metal-Organic Papers |
url | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2971799/ https://www.ncbi.nlm.nih.gov/pubmed/21578680 http://dx.doi.org/10.1107/S1600536809049502 |
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