Di-μ-ethano­lato-bis­[diethano­lato(2-methyl­quinolin-8-olato)titanium(IV)]

In the centrosymmetric dinuclear title compound, [Ti(2)(C(10)H(8)NO)(2)(C(2)H(5)O)(6)], the Ti atom is bonded to an N,O-bidentate quinolin-8-olate ligand, two terminal ethano­late anions and two bridging ethano­late anions in a distorted TiNO(5) octa­hedral geometry. An intra­molecular C—H⋯O hydroge...

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Detalles Bibliográficos
Autores principales: Fazaeli, Yousef, Najafi, Ezzatollah, Amini, Mostafa M., Khavasi, Hamid Reza
Formato: Texto
Lenguaje:English
Publicado: International Union of Crystallography 2009
Materias:
Metal-Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2971800/
https://www.ncbi.nlm.nih.gov/pubmed/21578574
http://dx.doi.org/10.1107/S1600536809045796
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author Fazaeli, Yousef
Najafi, Ezzatollah
Amini, Mostafa M.
Khavasi, Hamid Reza
author_facet Fazaeli, Yousef
Najafi, Ezzatollah
Amini, Mostafa M.
Khavasi, Hamid Reza
author_sort Fazaeli, Yousef
collection PubMed
description In the centrosymmetric dinuclear title compound, [Ti(2)(C(10)H(8)NO)(2)(C(2)H(5)O)(6)], the Ti atom is bonded to an N,O-bidentate quinolin-8-olate ligand, two terminal ethano­late anions and two bridging ethano­late anions in a distorted TiNO(5) octa­hedral geometry. An intra­molecular C—H⋯O hydrogen bond occurs; in the crystal, inter­molecular C—H⋯O inter­actions help to establish the packing.
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spelling pubmed-29718002010-12-30 Di-μ-ethano­lato-bis­[diethano­lato(2-methyl­quinolin-8-olato)titanium(IV)] Fazaeli, Yousef Najafi, Ezzatollah Amini, Mostafa M. Khavasi, Hamid Reza Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers In the centrosymmetric dinuclear title compound, [Ti(2)(C(10)H(8)NO)(2)(C(2)H(5)O)(6)], the Ti atom is bonded to an N,O-bidentate quinolin-8-olate ligand, two terminal ethano­late anions and two bridging ethano­late anions in a distorted TiNO(5) octa­hedral geometry. An intra­molecular C—H⋯O hydrogen bond occurs; in the crystal, inter­molecular C—H⋯O inter­actions help to establish the packing. International Union of Crystallography 2009-11-07 /pmc/articles/PMC2971800/ /pubmed/21578574 http://dx.doi.org/10.1107/S1600536809045796 Text en © Fazaeli et al. 2009 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Metal-Organic Papers
Fazaeli, Yousef
Najafi, Ezzatollah
Amini, Mostafa M.
Khavasi, Hamid Reza
Di-μ-ethano­lato-bis­[diethano­lato(2-methyl­quinolin-8-olato)titanium(IV)]
title Di-μ-ethano­lato-bis­[diethano­lato(2-methyl­quinolin-8-olato)titanium(IV)]
title_full Di-μ-ethano­lato-bis­[diethano­lato(2-methyl­quinolin-8-olato)titanium(IV)]
title_fullStr Di-μ-ethano­lato-bis­[diethano­lato(2-methyl­quinolin-8-olato)titanium(IV)]
title_full_unstemmed Di-μ-ethano­lato-bis­[diethano­lato(2-methyl­quinolin-8-olato)titanium(IV)]
title_short Di-μ-ethano­lato-bis­[diethano­lato(2-methyl­quinolin-8-olato)titanium(IV)]
title_sort di-μ-ethano­lato-bis­[diethano­lato(2-methyl­quinolin-8-olato)titanium(iv)]
topic Metal-Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2971800/
https://www.ncbi.nlm.nih.gov/pubmed/21578574
http://dx.doi.org/10.1107/S1600536809045796
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AT najafiezzatollah dimethanolatobisdiethanolato2methylquinolin8olatotitaniumiv
AT aminimostafam dimethanolatobisdiethanolato2methylquinolin8olatotitaniumiv
AT khavasihamidreza dimethanolatobisdiethanolato2methylquinolin8olatotitaniumiv

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