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[μ-Bis(diphenyl­arsino)methane-1:2κ(2) As:As′]nona­carbonyl-1κ(3) C,2κ(3) C,3κ(3) C-[tris­(4-fluoro­phen­yl)phosphine-3κP]-triangulo-triruthenium(0)

In the title triangulo-triruthenium compound, [Ru(3)(C(25)H(22)(As(2))(C(18)H(12)F(3)P)(CO)(9)], the bis­(diphenyl­arsino)methane ligand bridges an Ru—Ru bond and the monodentate phosphine ligand bonds to the third Ru atom. Both the phosphine and arsine ligands are equatorial with respect to the Ru(...

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Detalles Bibliográficos
Autores principales: Shawkataly, Omar bin, Khan, Imthyaz Ahmed, Yeap, Chin Sing, Fun, Hoong-Kun
Formato: Texto
Lenguaje:English
Publicado: International Union of Crystallography 2009
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2971801/
https://www.ncbi.nlm.nih.gov/pubmed/21578643
http://dx.doi.org/10.1107/S1600536809047229
Descripción
Sumario:In the title triangulo-triruthenium compound, [Ru(3)(C(25)H(22)(As(2))(C(18)H(12)F(3)P)(CO)(9)], the bis­(diphenyl­arsino)methane ligand bridges an Ru—Ru bond and the monodentate phosphine ligand bonds to the third Ru atom. Both the phosphine and arsine ligands are equatorial with respect to the Ru(3) triangle. Additionally, each Ru atom carries one equatorial and two axial terminal carbonyl ligands. The three phosphine-substituted rings make dihedral angles of 87.76 (13), 57.43 (13) and 73.81 (12)° with each other. The dihedral angles between the pairs of rings are 69.78 (14) and 83.38 (16)° for the two diphenyl­arsino groups. In the crystal packing, mol­ecules are linked by inter­molecular C—H⋯F and C—H⋯O hydrogen bonds, forming two-dimensional planes parallel to the ab plane. These planes are also linked by inter­molecular C—H⋯O hydrogen bonds into a three-dimensional framework. Inter­molecular C—H⋯π inter­actions further stabilize the crystal structure.