Cargando…

[μ-Bis(diphenyl­arsino)methane-1:2κ(2) As:As′]nona­carbonyl-1κ(3) C,2κ(3) C,3κ(3) C-[tris­(4-fluoro­phen­yl)phosphine-3κP]-triangulo-triruthenium(0)

In the title triangulo-triruthenium compound, [Ru(3)(C(25)H(22)(As(2))(C(18)H(12)F(3)P)(CO)(9)], the bis­(diphenyl­arsino)methane ligand bridges an Ru—Ru bond and the monodentate phosphine ligand bonds to the third Ru atom. Both the phosphine and arsine ligands are equatorial with respect to the Ru(...

Descripción completa

Detalles Bibliográficos
Autores principales: Shawkataly, Omar bin, Khan, Imthyaz Ahmed, Yeap, Chin Sing, Fun, Hoong-Kun
Formato: Texto
Lenguaje:English
Publicado: International Union of Crystallography 2009
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2971801/
https://www.ncbi.nlm.nih.gov/pubmed/21578643
http://dx.doi.org/10.1107/S1600536809047229
_version_ 1782190672519888896
author Shawkataly, Omar bin
Khan, Imthyaz Ahmed
Yeap, Chin Sing
Fun, Hoong-Kun
author_facet Shawkataly, Omar bin
Khan, Imthyaz Ahmed
Yeap, Chin Sing
Fun, Hoong-Kun
author_sort Shawkataly, Omar bin
collection PubMed
description In the title triangulo-triruthenium compound, [Ru(3)(C(25)H(22)(As(2))(C(18)H(12)F(3)P)(CO)(9)], the bis­(diphenyl­arsino)methane ligand bridges an Ru—Ru bond and the monodentate phosphine ligand bonds to the third Ru atom. Both the phosphine and arsine ligands are equatorial with respect to the Ru(3) triangle. Additionally, each Ru atom carries one equatorial and two axial terminal carbonyl ligands. The three phosphine-substituted rings make dihedral angles of 87.76 (13), 57.43 (13) and 73.81 (12)° with each other. The dihedral angles between the pairs of rings are 69.78 (14) and 83.38 (16)° for the two diphenyl­arsino groups. In the crystal packing, mol­ecules are linked by inter­molecular C—H⋯F and C—H⋯O hydrogen bonds, forming two-dimensional planes parallel to the ab plane. These planes are also linked by inter­molecular C—H⋯O hydrogen bonds into a three-dimensional framework. Inter­molecular C—H⋯π inter­actions further stabilize the crystal structure.
format Text
id pubmed-2971801
institution National Center for Biotechnology Information
language English
publishDate 2009
publisher International Union of Crystallography
record_format MEDLINE/PubMed
spelling pubmed-29718012010-12-30 [μ-Bis(diphenyl­arsino)methane-1:2κ(2) As:As′]nona­carbonyl-1κ(3) C,2κ(3) C,3κ(3) C-[tris­(4-fluoro­phen­yl)phosphine-3κP]-triangulo-triruthenium(0) Shawkataly, Omar bin Khan, Imthyaz Ahmed Yeap, Chin Sing Fun, Hoong-Kun Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers In the title triangulo-triruthenium compound, [Ru(3)(C(25)H(22)(As(2))(C(18)H(12)F(3)P)(CO)(9)], the bis­(diphenyl­arsino)methane ligand bridges an Ru—Ru bond and the monodentate phosphine ligand bonds to the third Ru atom. Both the phosphine and arsine ligands are equatorial with respect to the Ru(3) triangle. Additionally, each Ru atom carries one equatorial and two axial terminal carbonyl ligands. The three phosphine-substituted rings make dihedral angles of 87.76 (13), 57.43 (13) and 73.81 (12)° with each other. The dihedral angles between the pairs of rings are 69.78 (14) and 83.38 (16)° for the two diphenyl­arsino groups. In the crystal packing, mol­ecules are linked by inter­molecular C—H⋯F and C—H⋯O hydrogen bonds, forming two-dimensional planes parallel to the ab plane. These planes are also linked by inter­molecular C—H⋯O hydrogen bonds into a three-dimensional framework. Inter­molecular C—H⋯π inter­actions further stabilize the crystal structure. International Union of Crystallography 2009-11-21 /pmc/articles/PMC2971801/ /pubmed/21578643 http://dx.doi.org/10.1107/S1600536809047229 Text en © Shawkataly et al. 2009 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Metal-Organic Papers
Shawkataly, Omar bin
Khan, Imthyaz Ahmed
Yeap, Chin Sing
Fun, Hoong-Kun
[μ-Bis(diphenyl­arsino)methane-1:2κ(2) As:As′]nona­carbonyl-1κ(3) C,2κ(3) C,3κ(3) C-[tris­(4-fluoro­phen­yl)phosphine-3κP]-triangulo-triruthenium(0)
title [μ-Bis(diphenyl­arsino)methane-1:2κ(2) As:As′]nona­carbonyl-1κ(3) C,2κ(3) C,3κ(3) C-[tris­(4-fluoro­phen­yl)phosphine-3κP]-triangulo-triruthenium(0)
title_full [μ-Bis(diphenyl­arsino)methane-1:2κ(2) As:As′]nona­carbonyl-1κ(3) C,2κ(3) C,3κ(3) C-[tris­(4-fluoro­phen­yl)phosphine-3κP]-triangulo-triruthenium(0)
title_fullStr [μ-Bis(diphenyl­arsino)methane-1:2κ(2) As:As′]nona­carbonyl-1κ(3) C,2κ(3) C,3κ(3) C-[tris­(4-fluoro­phen­yl)phosphine-3κP]-triangulo-triruthenium(0)
title_full_unstemmed [μ-Bis(diphenyl­arsino)methane-1:2κ(2) As:As′]nona­carbonyl-1κ(3) C,2κ(3) C,3κ(3) C-[tris­(4-fluoro­phen­yl)phosphine-3κP]-triangulo-triruthenium(0)
title_short [μ-Bis(diphenyl­arsino)methane-1:2κ(2) As:As′]nona­carbonyl-1κ(3) C,2κ(3) C,3κ(3) C-[tris­(4-fluoro­phen­yl)phosphine-3κP]-triangulo-triruthenium(0)
title_sort [μ-bis(diphenyl­arsino)methane-1:2κ(2) as:as′]nona­carbonyl-1κ(3) c,2κ(3) c,3κ(3) c-[tris­(4-fluoro­phen­yl)phosphine-3κp]-triangulo-triruthenium(0)
topic Metal-Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2971801/
https://www.ncbi.nlm.nih.gov/pubmed/21578643
http://dx.doi.org/10.1107/S1600536809047229
work_keys_str_mv AT shawkatalyomarbin mbisdiphenylarsinomethane12k2asasnonacarbonyl1k3c2k3c3k3ctris4fluorophenylphosphine3kptriangulotriruthenium0
AT khanimthyazahmed mbisdiphenylarsinomethane12k2asasnonacarbonyl1k3c2k3c3k3ctris4fluorophenylphosphine3kptriangulotriruthenium0
AT yeapchinsing mbisdiphenylarsinomethane12k2asasnonacarbonyl1k3c2k3c3k3ctris4fluorophenylphosphine3kptriangulotriruthenium0
AT funhoongkun mbisdiphenylarsinomethane12k2asasnonacarbonyl1k3c2k3c3k3ctris4fluorophenylphosphine3kptriangulotriruthenium0