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[μ-Bis(diphenylarsino)methane-1:2κ(2) As:As′]nonacarbonyl-1κ(3) C,2κ(3) C,3κ(3) C-[tris(4-fluorophenyl)phosphine-3κP]-triangulo-triruthenium(0)
In the title triangulo-triruthenium compound, [Ru(3)(C(25)H(22)(As(2))(C(18)H(12)F(3)P)(CO)(9)], the bis(diphenylarsino)methane ligand bridges an Ru—Ru bond and the monodentate phosphine ligand bonds to the third Ru atom. Both the phosphine and arsine ligands are equatorial with respect to the Ru(...
Autores principales: | , , , |
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Formato: | Texto |
Lenguaje: | English |
Publicado: |
International Union of Crystallography
2009
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Materias: | |
Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2971801/ https://www.ncbi.nlm.nih.gov/pubmed/21578643 http://dx.doi.org/10.1107/S1600536809047229 |
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author | Shawkataly, Omar bin Khan, Imthyaz Ahmed Yeap, Chin Sing Fun, Hoong-Kun |
author_facet | Shawkataly, Omar bin Khan, Imthyaz Ahmed Yeap, Chin Sing Fun, Hoong-Kun |
author_sort | Shawkataly, Omar bin |
collection | PubMed |
description | In the title triangulo-triruthenium compound, [Ru(3)(C(25)H(22)(As(2))(C(18)H(12)F(3)P)(CO)(9)], the bis(diphenylarsino)methane ligand bridges an Ru—Ru bond and the monodentate phosphine ligand bonds to the third Ru atom. Both the phosphine and arsine ligands are equatorial with respect to the Ru(3) triangle. Additionally, each Ru atom carries one equatorial and two axial terminal carbonyl ligands. The three phosphine-substituted rings make dihedral angles of 87.76 (13), 57.43 (13) and 73.81 (12)° with each other. The dihedral angles between the pairs of rings are 69.78 (14) and 83.38 (16)° for the two diphenylarsino groups. In the crystal packing, molecules are linked by intermolecular C—H⋯F and C—H⋯O hydrogen bonds, forming two-dimensional planes parallel to the ab plane. These planes are also linked by intermolecular C—H⋯O hydrogen bonds into a three-dimensional framework. Intermolecular C—H⋯π interactions further stabilize the crystal structure. |
format | Text |
id | pubmed-2971801 |
institution | National Center for Biotechnology Information |
language | English |
publishDate | 2009 |
publisher | International Union of Crystallography |
record_format | MEDLINE/PubMed |
spelling | pubmed-29718012010-12-30 [μ-Bis(diphenylarsino)methane-1:2κ(2) As:As′]nonacarbonyl-1κ(3) C,2κ(3) C,3κ(3) C-[tris(4-fluorophenyl)phosphine-3κP]-triangulo-triruthenium(0) Shawkataly, Omar bin Khan, Imthyaz Ahmed Yeap, Chin Sing Fun, Hoong-Kun Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers In the title triangulo-triruthenium compound, [Ru(3)(C(25)H(22)(As(2))(C(18)H(12)F(3)P)(CO)(9)], the bis(diphenylarsino)methane ligand bridges an Ru—Ru bond and the monodentate phosphine ligand bonds to the third Ru atom. Both the phosphine and arsine ligands are equatorial with respect to the Ru(3) triangle. Additionally, each Ru atom carries one equatorial and two axial terminal carbonyl ligands. The three phosphine-substituted rings make dihedral angles of 87.76 (13), 57.43 (13) and 73.81 (12)° with each other. The dihedral angles between the pairs of rings are 69.78 (14) and 83.38 (16)° for the two diphenylarsino groups. In the crystal packing, molecules are linked by intermolecular C—H⋯F and C—H⋯O hydrogen bonds, forming two-dimensional planes parallel to the ab plane. These planes are also linked by intermolecular C—H⋯O hydrogen bonds into a three-dimensional framework. Intermolecular C—H⋯π interactions further stabilize the crystal structure. International Union of Crystallography 2009-11-21 /pmc/articles/PMC2971801/ /pubmed/21578643 http://dx.doi.org/10.1107/S1600536809047229 Text en © Shawkataly et al. 2009 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited. |
spellingShingle | Metal-Organic Papers Shawkataly, Omar bin Khan, Imthyaz Ahmed Yeap, Chin Sing Fun, Hoong-Kun [μ-Bis(diphenylarsino)methane-1:2κ(2) As:As′]nonacarbonyl-1κ(3) C,2κ(3) C,3κ(3) C-[tris(4-fluorophenyl)phosphine-3κP]-triangulo-triruthenium(0) |
title | [μ-Bis(diphenylarsino)methane-1:2κ(2)
As:As′]nonacarbonyl-1κ(3)
C,2κ(3)
C,3κ(3)
C-[tris(4-fluorophenyl)phosphine-3κP]-triangulo-triruthenium(0) |
title_full | [μ-Bis(diphenylarsino)methane-1:2κ(2)
As:As′]nonacarbonyl-1κ(3)
C,2κ(3)
C,3κ(3)
C-[tris(4-fluorophenyl)phosphine-3κP]-triangulo-triruthenium(0) |
title_fullStr | [μ-Bis(diphenylarsino)methane-1:2κ(2)
As:As′]nonacarbonyl-1κ(3)
C,2κ(3)
C,3κ(3)
C-[tris(4-fluorophenyl)phosphine-3κP]-triangulo-triruthenium(0) |
title_full_unstemmed | [μ-Bis(diphenylarsino)methane-1:2κ(2)
As:As′]nonacarbonyl-1κ(3)
C,2κ(3)
C,3κ(3)
C-[tris(4-fluorophenyl)phosphine-3κP]-triangulo-triruthenium(0) |
title_short | [μ-Bis(diphenylarsino)methane-1:2κ(2)
As:As′]nonacarbonyl-1κ(3)
C,2κ(3)
C,3κ(3)
C-[tris(4-fluorophenyl)phosphine-3κP]-triangulo-triruthenium(0) |
title_sort | [μ-bis(diphenylarsino)methane-1:2κ(2)
as:as′]nonacarbonyl-1κ(3)
c,2κ(3)
c,3κ(3)
c-[tris(4-fluorophenyl)phosphine-3κp]-triangulo-triruthenium(0) |
topic | Metal-Organic Papers |
url | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2971801/ https://www.ncbi.nlm.nih.gov/pubmed/21578643 http://dx.doi.org/10.1107/S1600536809047229 |
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