trans-Dichloridobis[tris­(4-methoxy­phen­yl)phosphine]palladium(II) benzene monosolvate

The structure of the title compound, [PdCl(2)(C(21)H(21)O(3)P)(2)]·C(6)H(6), shows a square-planar geometry for the Pd(II) atom within a Cl(2)[P(PhOMe)(3)](2) ligand set. The crystal structure contains benzene as solvent. The Pd(II) atom sits on a centre of inversion and therefore the asymmetric uni...

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Detalles Bibliográficos
Autores principales: van Blerk, Charmaine, Holzapfel, Cedric W.
Formato: Texto
Lenguaje:English
Publicado: International Union of Crystallography 2009
Materias:
Metal-Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2971806/
https://www.ncbi.nlm.nih.gov/pubmed/21578578
http://dx.doi.org/10.1107/S1600536809046261
Descripción
Sumario:The structure of the title compound, [PdCl(2)(C(21)H(21)O(3)P)(2)]·C(6)H(6), shows a square-planar geometry for the Pd(II) atom within a Cl(2)[P(PhOMe)(3)](2) ligand set. The crystal structure contains benzene as solvent. The Pd(II) atom sits on a centre of inversion and therefore the asymmetric unit contains the Pd(II) atom, one Cl atom, one tris­(4-methoxy­phen­yl)phosphine ligand and one half of the benzene solvent mol­ecule.

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