trans-Dichloridobis[tris­(4-methoxy­phen­yl)phosphine]palladium(II) benzene monosolvate

The structure of the title compound, [PdCl(2)(C(21)H(21)O(3)P)(2)]·C(6)H(6), shows a square-planar geometry for the Pd(II) atom within a Cl(2)[P(PhOMe)(3)](2) ligand set. The crystal structure contains benzene as solvent. The Pd(II) atom sits on a centre of inversion and therefore the asymmetric uni...

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Detalles Bibliográficos
Autores principales: van Blerk, Charmaine, Holzapfel, Cedric W.
Formato: Texto
Lenguaje:English
Publicado: International Union of Crystallography 2009
Materias:
Metal-Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2971806/
https://www.ncbi.nlm.nih.gov/pubmed/21578578
http://dx.doi.org/10.1107/S1600536809046261
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author van Blerk, Charmaine
Holzapfel, Cedric W.
author_facet van Blerk, Charmaine
Holzapfel, Cedric W.
author_sort van Blerk, Charmaine
collection PubMed
description The structure of the title compound, [PdCl(2)(C(21)H(21)O(3)P)(2)]·C(6)H(6), shows a square-planar geometry for the Pd(II) atom within a Cl(2)[P(PhOMe)(3)](2) ligand set. The crystal structure contains benzene as solvent. The Pd(II) atom sits on a centre of inversion and therefore the asymmetric unit contains the Pd(II) atom, one Cl atom, one tris­(4-methoxy­phen­yl)phosphine ligand and one half of the benzene solvent mol­ecule.
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spelling pubmed-29718062010-12-30 trans-Dichloridobis[tris­(4-methoxy­phen­yl)phosphine]palladium(II) benzene monosolvate van Blerk, Charmaine Holzapfel, Cedric W. Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers The structure of the title compound, [PdCl(2)(C(21)H(21)O(3)P)(2)]·C(6)H(6), shows a square-planar geometry for the Pd(II) atom within a Cl(2)[P(PhOMe)(3)](2) ligand set. The crystal structure contains benzene as solvent. The Pd(II) atom sits on a centre of inversion and therefore the asymmetric unit contains the Pd(II) atom, one Cl atom, one tris­(4-methoxy­phen­yl)phosphine ligand and one half of the benzene solvent mol­ecule. International Union of Crystallography 2009-11-07 /pmc/articles/PMC2971806/ /pubmed/21578578 http://dx.doi.org/10.1107/S1600536809046261 Text en © Blerk and Holzapfel 2009 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Metal-Organic Papers
van Blerk, Charmaine
Holzapfel, Cedric W.
trans-Dichloridobis[tris­(4-methoxy­phen­yl)phosphine]palladium(II) benzene monosolvate
title trans-Dichloridobis[tris­(4-methoxy­phen­yl)phosphine]palladium(II) benzene monosolvate
title_full trans-Dichloridobis[tris­(4-methoxy­phen­yl)phosphine]palladium(II) benzene monosolvate
title_fullStr trans-Dichloridobis[tris­(4-methoxy­phen­yl)phosphine]palladium(II) benzene monosolvate
title_full_unstemmed trans-Dichloridobis[tris­(4-methoxy­phen­yl)phosphine]palladium(II) benzene monosolvate
title_short trans-Dichloridobis[tris­(4-methoxy­phen­yl)phosphine]palladium(II) benzene monosolvate
title_sort trans-dichloridobis[tris­(4-methoxy­phen­yl)phosphine]palladium(ii) benzene monosolvate
topic Metal-Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2971806/
https://www.ncbi.nlm.nih.gov/pubmed/21578578
http://dx.doi.org/10.1107/S1600536809046261
work_keys_str_mv AT vanblerkcharmaine transdichloridobistris4methoxyphenylphosphinepalladiumiibenzenemonosolvate
AT holzapfelcedricw transdichloridobistris4methoxyphenylphosphinepalladiumiibenzenemonosolvate

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