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4-[(2-Chloro­ethyl)amino]quinolinium chloride monohydrate

In the title salt hydrate, C(11)H(12)ClN(2) (+)·Cl(−)·H(2)O, the quinolin­ium core is essentially planar (r.m.s. deviation = 0.027 Å) with the chloro­ethyl side chain being almost orthogonal to the core [C—N—C—C torsion angle = −80.0 (3)°]. In the crystal packing, the water mol­ecule bridges three s...

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Detalles Bibliográficos
Autores principales: de Souza, Marcus V. N., Tiekink, Edward R. T., Wardell, James L., Wardell, Solange M. S. V.
Formato: Texto
Lenguaje:English
Publicado: International Union of Crystallography 2009
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2971810/
https://www.ncbi.nlm.nih.gov/pubmed/21578845
http://dx.doi.org/10.1107/S160053680904834X
Descripción
Sumario:In the title salt hydrate, C(11)H(12)ClN(2) (+)·Cl(−)·H(2)O, the quinolin­ium core is essentially planar (r.m.s. deviation = 0.027 Å) with the chloro­ethyl side chain being almost orthogonal to the core [C—N—C—C torsion angle = −80.0 (3)°]. In the crystal packing, the water mol­ecule bridges three species, forming donor inter­actions to two chloride anions and accepting a hydrogen bond from the quinolinium H atom. The chloride anion accepts a hydrogen bond from the amine N atom with the result that a two-dimensional supra­molecular array is formed in the ac plane. A C—H⋯Cl interaction also occurs.