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Tetraguanidinium bis[citrato(3−)]cuprate(II) dihydrate
The asymmetric unit of the title compound, (CH(6)N(3))(4)[Cu(C(6)H(5)O(7))(2)]·2H(2)O, contains one-half of a centrosymmetric Cu(II) complex anion, two guanidinium cations and a water molecule. The Cu(II) ion, lying on a crystallographic inversion center, is hexacoordinated with two citrate anions...
| Autores principales: | , , , , |
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| Formato: | Texto |
| Lenguaje: | English |
| Publicado: |
International Union of Crystallography
2009
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| Materias: | |
| Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2971813/ https://www.ncbi.nlm.nih.gov/pubmed/21578581 http://dx.doi.org/10.1107/S1600536809046170 |
| _version_ | 1782190675382501376 |
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| author | Al-Dajani, Mohammad T. M. Abdallah, Hassan H. Mohamed, Nornisah Yeap, Chin Sing Fun, Hoong-Kun |
| author_facet | Al-Dajani, Mohammad T. M. Abdallah, Hassan H. Mohamed, Nornisah Yeap, Chin Sing Fun, Hoong-Kun |
| author_sort | Al-Dajani, Mohammad T. M. |
| collection | PubMed |
| description | The asymmetric unit of the title compound, (CH(6)N(3))(4)[Cu(C(6)H(5)O(7))(2)]·2H(2)O, contains one-half of a centrosymmetric Cu(II) complex anion, two guanidinium cations and a water molecule. The Cu(II) ion, lying on a crystallographic inversion center, is hexacoordinated with two citrate anions in a distorted octahedral geometry. An intramolecular O—H⋯O hydrogen bond generates an S(6) ring motif. In the crystal structure, molecules are linked into a three-dimensional framework by intermolecular N—H⋯O and O—H⋯O hydrogen bonds. |
| format | Text |
| id | pubmed-2971813 |
| institution | National Center for Biotechnology Information |
| language | English |
| publishDate | 2009 |
| publisher | International Union of Crystallography |
| record_format | MEDLINE/PubMed |
| spelling | pubmed-29718132010-12-30 Tetraguanidinium bis[citrato(3−)]cuprate(II) dihydrate Al-Dajani, Mohammad T. M. Abdallah, Hassan H. Mohamed, Nornisah Yeap, Chin Sing Fun, Hoong-Kun Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers The asymmetric unit of the title compound, (CH(6)N(3))(4)[Cu(C(6)H(5)O(7))(2)]·2H(2)O, contains one-half of a centrosymmetric Cu(II) complex anion, two guanidinium cations and a water molecule. The Cu(II) ion, lying on a crystallographic inversion center, is hexacoordinated with two citrate anions in a distorted octahedral geometry. An intramolecular O—H⋯O hydrogen bond generates an S(6) ring motif. In the crystal structure, molecules are linked into a three-dimensional framework by intermolecular N—H⋯O and O—H⋯O hydrogen bonds. International Union of Crystallography 2009-11-07 /pmc/articles/PMC2971813/ /pubmed/21578581 http://dx.doi.org/10.1107/S1600536809046170 Text en © Al-Dajani et al. 2009 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited. |
| spellingShingle | Metal-Organic Papers Al-Dajani, Mohammad T. M. Abdallah, Hassan H. Mohamed, Nornisah Yeap, Chin Sing Fun, Hoong-Kun Tetraguanidinium bis[citrato(3−)]cuprate(II) dihydrate |
| title | Tetraguanidinium bis[citrato(3−)]cuprate(II) dihydrate |
| title_full | Tetraguanidinium bis[citrato(3−)]cuprate(II) dihydrate |
| title_fullStr | Tetraguanidinium bis[citrato(3−)]cuprate(II) dihydrate |
| title_full_unstemmed | Tetraguanidinium bis[citrato(3−)]cuprate(II) dihydrate |
| title_short | Tetraguanidinium bis[citrato(3−)]cuprate(II) dihydrate |
| title_sort | tetraguanidinium bis[citrato(3−)]cuprate(ii) dihydrate |
| topic | Metal-Organic Papers |
| url | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2971813/ https://www.ncbi.nlm.nih.gov/pubmed/21578581 http://dx.doi.org/10.1107/S1600536809046170 |
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