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[(Z)-N-(3-Chlorophenyl)-O-ethylthiocarbamato-κS](triphenylphosphine-κP)gold(I)
The title compound, [Au(C(9)H(9)ClNOS)(C(18)H(15)P)], reveals a near linear geometry for the Au atom defined by a S,P-donor set [S—Au—P = 175.86 (3)°]. The deviation from linearity is ascribed to the proximate O atom derived from the thiocarbamato anion [Au⋯O = 2.967 (3) Å].
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| Formato: | Texto |
| Lenguaje: | English |
| Publicado: |
International Union of Crystallography
2009
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| Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2971815/ https://www.ncbi.nlm.nih.gov/pubmed/21578673 http://dx.doi.org/10.1107/S1600536809049551 |
| _version_ | 1782190675856457728 |
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| author | Tadbuppa, Primjira P. Tiekink, Edward R. T. |
| author_facet | Tadbuppa, Primjira P. Tiekink, Edward R. T. |
| author_sort | Tadbuppa, Primjira P. |
| collection | PubMed |
| description | The title compound, [Au(C(9)H(9)ClNOS)(C(18)H(15)P)], reveals a near linear geometry for the Au atom defined by a S,P-donor set [S—Au—P = 175.86 (3)°]. The deviation from linearity is ascribed to the proximate O atom derived from the thiocarbamato anion [Au⋯O = 2.967 (3) Å]. |
| format | Text |
| id | pubmed-2971815 |
| institution | National Center for Biotechnology Information |
| language | English |
| publishDate | 2009 |
| publisher | International Union of Crystallography |
| record_format | MEDLINE/PubMed |
| spelling | pubmed-29718152010-12-30 [(Z)-N-(3-Chlorophenyl)-O-ethylthiocarbamato-κS](triphenylphosphine-κP)gold(I) Tadbuppa, Primjira P. Tiekink, Edward R. T. Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers The title compound, [Au(C(9)H(9)ClNOS)(C(18)H(15)P)], reveals a near linear geometry for the Au atom defined by a S,P-donor set [S—Au—P = 175.86 (3)°]. The deviation from linearity is ascribed to the proximate O atom derived from the thiocarbamato anion [Au⋯O = 2.967 (3) Å]. International Union of Crystallography 2009-11-25 /pmc/articles/PMC2971815/ /pubmed/21578673 http://dx.doi.org/10.1107/S1600536809049551 Text en © Tadbuppa and Tiekink 2009 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited. |
| spellingShingle | Metal-Organic Papers Tadbuppa, Primjira P. Tiekink, Edward R. T. [(Z)-N-(3-Chlorophenyl)-O-ethylthiocarbamato-κS](triphenylphosphine-κP)gold(I) |
| title | [(Z)-N-(3-Chlorophenyl)-O-ethylthiocarbamato-κS](triphenylphosphine-κP)gold(I) |
| title_full | [(Z)-N-(3-Chlorophenyl)-O-ethylthiocarbamato-κS](triphenylphosphine-κP)gold(I) |
| title_fullStr | [(Z)-N-(3-Chlorophenyl)-O-ethylthiocarbamato-κS](triphenylphosphine-κP)gold(I) |
| title_full_unstemmed | [(Z)-N-(3-Chlorophenyl)-O-ethylthiocarbamato-κS](triphenylphosphine-κP)gold(I) |
| title_short | [(Z)-N-(3-Chlorophenyl)-O-ethylthiocarbamato-κS](triphenylphosphine-κP)gold(I) |
| title_sort | [(z)-n-(3-chlorophenyl)-o-ethylthiocarbamato-κs](triphenylphosphine-κp)gold(i) |
| topic | Metal-Organic Papers |
| url | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2971815/ https://www.ncbi.nlm.nih.gov/pubmed/21578673 http://dx.doi.org/10.1107/S1600536809049551 |
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