Hexaaqua­manganese(II) tetra­aqua­bis(2-amino­pyrazine-κN (4))manganese(II) disulfate dihydrate

The reaction of manganese(II) sulfate and 2-amino­pyrazine affords the title salt, [Mn(H(2)O)(6)][Mn(C(4)H(5)N(3))(2)(H(2)O)(4)](SO(4))(2)·2H(2)O. The metal atoms in the tetra­aqua-coordinated and hexa­aqua-coordinated cations lie on centers of inversion in octa­hedral geometries. The cations, anion...

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Detalles Bibliográficos
Autores principales: Huo, Li-Hua, Gao, Shan, Ng, Seik Weng
Formato: Texto
Lenguaje:English
Publicado: International Union of Crystallography 2009
Materias:
Metal-Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2971817/
https://www.ncbi.nlm.nih.gov/pubmed/21578555
http://dx.doi.org/10.1107/S1600536809045322
Descripción
Sumario:The reaction of manganese(II) sulfate and 2-amino­pyrazine affords the title salt, [Mn(H(2)O)(6)][Mn(C(4)H(5)N(3))(2)(H(2)O)(4)](SO(4))(2)·2H(2)O. The metal atoms in the tetra­aqua-coordinated and hexa­aqua-coordinated cations lie on centers of inversion in octa­hedral geometries. The cations, anions and solvent water mol­ecules are linked by O—H⋯O, N—H⋯O and O—H⋯N hydrogen bonds into a three-dimensional network.

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