Hexaaqua­manganese(II) tetra­aqua­bis(2-amino­pyrazine-κN (4))manganese(II) disulfate dihydrate

The reaction of manganese(II) sulfate and 2-amino­pyrazine affords the title salt, [Mn(H(2)O)(6)][Mn(C(4)H(5)N(3))(2)(H(2)O)(4)](SO(4))(2)·2H(2)O. The metal atoms in the tetra­aqua-coordinated and hexa­aqua-coordinated cations lie on centers of inversion in octa­hedral geometries. The cations, anion...

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Detalles Bibliográficos
Autores principales: Huo, Li-Hua, Gao, Shan, Ng, Seik Weng
Formato: Texto
Lenguaje:English
Publicado: International Union of Crystallography 2009
Materias:
Metal-Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2971817/
https://www.ncbi.nlm.nih.gov/pubmed/21578555
http://dx.doi.org/10.1107/S1600536809045322
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author Huo, Li-Hua
Gao, Shan
Ng, Seik Weng
author_facet Huo, Li-Hua
Gao, Shan
Ng, Seik Weng
author_sort Huo, Li-Hua
collection PubMed
description The reaction of manganese(II) sulfate and 2-amino­pyrazine affords the title salt, [Mn(H(2)O)(6)][Mn(C(4)H(5)N(3))(2)(H(2)O)(4)](SO(4))(2)·2H(2)O. The metal atoms in the tetra­aqua-coordinated and hexa­aqua-coordinated cations lie on centers of inversion in octa­hedral geometries. The cations, anions and solvent water mol­ecules are linked by O—H⋯O, N—H⋯O and O—H⋯N hydrogen bonds into a three-dimensional network.
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spelling pubmed-29718172010-12-30 Hexaaqua­manganese(II) tetra­aqua­bis(2-amino­pyrazine-κN (4))manganese(II) disulfate dihydrate Huo, Li-Hua Gao, Shan Ng, Seik Weng Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers The reaction of manganese(II) sulfate and 2-amino­pyrazine affords the title salt, [Mn(H(2)O)(6)][Mn(C(4)H(5)N(3))(2)(H(2)O)(4)](SO(4))(2)·2H(2)O. The metal atoms in the tetra­aqua-coordinated and hexa­aqua-coordinated cations lie on centers of inversion in octa­hedral geometries. The cations, anions and solvent water mol­ecules are linked by O—H⋯O, N—H⋯O and O—H⋯N hydrogen bonds into a three-dimensional network. International Union of Crystallography 2009-11-04 /pmc/articles/PMC2971817/ /pubmed/21578555 http://dx.doi.org/10.1107/S1600536809045322 Text en © Huo et al. 2009 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Metal-Organic Papers
Huo, Li-Hua
Gao, Shan
Ng, Seik Weng
Hexaaqua­manganese(II) tetra­aqua­bis(2-amino­pyrazine-κN (4))manganese(II) disulfate dihydrate
title Hexaaqua­manganese(II) tetra­aqua­bis(2-amino­pyrazine-κN (4))manganese(II) disulfate dihydrate
title_full Hexaaqua­manganese(II) tetra­aqua­bis(2-amino­pyrazine-κN (4))manganese(II) disulfate dihydrate
title_fullStr Hexaaqua­manganese(II) tetra­aqua­bis(2-amino­pyrazine-κN (4))manganese(II) disulfate dihydrate
title_full_unstemmed Hexaaqua­manganese(II) tetra­aqua­bis(2-amino­pyrazine-κN (4))manganese(II) disulfate dihydrate
title_short Hexaaqua­manganese(II) tetra­aqua­bis(2-amino­pyrazine-κN (4))manganese(II) disulfate dihydrate
title_sort hexaaqua­manganese(ii) tetra­aqua­bis(2-amino­pyrazine-κn (4))manganese(ii) disulfate dihydrate
topic Metal-Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2971817/
https://www.ncbi.nlm.nih.gov/pubmed/21578555
http://dx.doi.org/10.1107/S1600536809045322
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AT gaoshan hexaaquamanganeseiitetraaquabis2aminopyrazinekn4manganeseiidisulfatedihydrate
AT ngseikweng hexaaquamanganeseiitetraaquabis2aminopyrazinekn4manganeseiidisulfatedihydrate

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