(2,2′-Bipyrid­yl)bis­[N-(2-hydroxy­ethyl)-N-n-propyl­dithio­carbamato-κ(2) S,S′]cadmium(II) acetonitrile solvate

The title complex, [Cd(C(6)H(12)NOS(2))(2)(C(10)H(8)N(2))]·CH(3)CN, features a distorted octa­hedral N(2)S(4) geometry for the Cd(II) centre defined by a pair of asymmetrically chelating dithio­carbamate ligands as well as a 2,2′-bipyridine ligand. Supra­molecular chains along [001] are formed in th...

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Detalles Bibliográficos
Autores principales: Song, Juyoung C., Tiekink, Edward R. T.
Formato: Texto
Lenguaje:English
Publicado: International Union of Crystallography 2009
Materias:
Metal-Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2971818/
https://www.ncbi.nlm.nih.gov/pubmed/21578678
http://dx.doi.org/10.1107/S1600536809049666
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author Song, Juyoung C.
Tiekink, Edward R. T.
author_facet Song, Juyoung C.
Tiekink, Edward R. T.
author_sort Song, Juyoung C.
collection PubMed
description The title complex, [Cd(C(6)H(12)NOS(2))(2)(C(10)H(8)N(2))]·CH(3)CN, features a distorted octa­hedral N(2)S(4) geometry for the Cd(II) centre defined by a pair of asymmetrically chelating dithio­carbamate ligands as well as a 2,2′-bipyridine ligand. Supra­molecular chains along [001] are formed in the crystal structure, mediated by O—H⋯S hydrogen bonds; the acetonitrile solvent mol­ecules are associated with the chains via O—H⋯N hydrogen bonds.
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spelling pubmed-29718182010-12-30 (2,2′-Bipyrid­yl)bis­[N-(2-hydroxy­ethyl)-N-n-propyl­dithio­carbamato-κ(2) S,S′]cadmium(II) acetonitrile solvate Song, Juyoung C. Tiekink, Edward R. T. Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers The title complex, [Cd(C(6)H(12)NOS(2))(2)(C(10)H(8)N(2))]·CH(3)CN, features a distorted octa­hedral N(2)S(4) geometry for the Cd(II) centre defined by a pair of asymmetrically chelating dithio­carbamate ligands as well as a 2,2′-bipyridine ligand. Supra­molecular chains along [001] are formed in the crystal structure, mediated by O—H⋯S hydrogen bonds; the acetonitrile solvent mol­ecules are associated with the chains via O—H⋯N hydrogen bonds. International Union of Crystallography 2009-11-25 /pmc/articles/PMC2971818/ /pubmed/21578678 http://dx.doi.org/10.1107/S1600536809049666 Text en © Song and Tiekink 2009 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Metal-Organic Papers
Song, Juyoung C.
Tiekink, Edward R. T.
(2,2′-Bipyrid­yl)bis­[N-(2-hydroxy­ethyl)-N-n-propyl­dithio­carbamato-κ(2) S,S′]cadmium(II) acetonitrile solvate
title (2,2′-Bipyrid­yl)bis­[N-(2-hydroxy­ethyl)-N-n-propyl­dithio­carbamato-κ(2) S,S′]cadmium(II) acetonitrile solvate
title_full (2,2′-Bipyrid­yl)bis­[N-(2-hydroxy­ethyl)-N-n-propyl­dithio­carbamato-κ(2) S,S′]cadmium(II) acetonitrile solvate
title_fullStr (2,2′-Bipyrid­yl)bis­[N-(2-hydroxy­ethyl)-N-n-propyl­dithio­carbamato-κ(2) S,S′]cadmium(II) acetonitrile solvate
title_full_unstemmed (2,2′-Bipyrid­yl)bis­[N-(2-hydroxy­ethyl)-N-n-propyl­dithio­carbamato-κ(2) S,S′]cadmium(II) acetonitrile solvate
title_short (2,2′-Bipyrid­yl)bis­[N-(2-hydroxy­ethyl)-N-n-propyl­dithio­carbamato-κ(2) S,S′]cadmium(II) acetonitrile solvate
title_sort (2,2′-bipyrid­yl)bis­[n-(2-hydroxy­ethyl)-n-n-propyl­dithio­carbamato-κ(2) s,s′]cadmium(ii) acetonitrile solvate
topic Metal-Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2971818/
https://www.ncbi.nlm.nih.gov/pubmed/21578678
http://dx.doi.org/10.1107/S1600536809049666
work_keys_str_mv AT songjuyoungc 22bipyridylbisn2hydroxyethylnnpropyldithiocarbamatok2sscadmiumiiacetonitrilesolvate
AT tiekinkedwardrt 22bipyridylbisn2hydroxyethylnnpropyldithiocarbamatok2sscadmiumiiacetonitrilesolvate

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