Poly[aqua­bis(μ(4)-naphthalene-1,4-di­carboxyl­ato)(1,10-phenanthroline-5,6-dione)dimanganese(II)]

The three-dimensional coordination polymer, [Mn(2)(C(12)H(6)O(4))(2)(C(12)H(6)N(2)O(2))(H(2)O)](n), features a water-coord­inated Mn(II) ion and an N-heterocycle-chelated Mn(II) ion, both in six-coordinate octa­hedral geometries. Of the two rigid dianions, one is bonded to four Mn(II) ions, with eac...

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Detalles Bibliográficos
Autores principales: Cong, Fang-Di, Yu, Feng-Yang, Wei, Zhen, Ng, Seik Weng
Formato: Texto
Lenguaje:English
Publicado: International Union of Crystallography 2009
Materias:
Metal-Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2971822/
https://www.ncbi.nlm.nih.gov/pubmed/21578583
http://dx.doi.org/10.1107/S1600536809046388
Descripción
Sumario:The three-dimensional coordination polymer, [Mn(2)(C(12)H(6)O(4))(2)(C(12)H(6)N(2)O(2))(H(2)O)](n), features a water-coord­inated Mn(II) ion and an N-heterocycle-chelated Mn(II) ion, both in six-coordinate octa­hedral geometries. Of the two rigid dianions, one is bonded to four Mn(II) ions, with each of the O atoms being connected to a different metal ion. The other dianion uses one carboxyl­ate group to chelate to one Mn(II) ion and its other carboxyl­ate group to bind to two Mn(II) ions.

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