Cargando…

(E)-4-Meth­oxy-2-[3-(trifluoro­meth­yl)phenyl­imino­meth­yl]phenol

The title compound, C(15)H(12)F(3)NO(2), adopts the phenol–imine tautomeric form, with the H atom attached to oxygen rather than to nitro­gen. There are two independent mol­ecules aligned nearly parallel in the asymmetric unit with their trifloramethyl groups pointing in opposite directions. The dih...

Descripción completa

Detalles Bibliográficos
Autores principales: Keleşoğlu, Zeynep, Büyükgüngör, Orhan, Albayrak, Çiğdem, Odabaşoğlu, Mustafa
Formato: Texto
Lenguaje:English
Publicado: International Union of Crystallography 2009
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2971825/
https://www.ncbi.nlm.nih.gov/pubmed/21578946
http://dx.doi.org/10.1107/S160053680905034X
_version_ 1782190678322708480
author Keleşoğlu, Zeynep
Büyükgüngör, Orhan
Albayrak, Çiğdem
Odabaşoğlu, Mustafa
author_facet Keleşoğlu, Zeynep
Büyükgüngör, Orhan
Albayrak, Çiğdem
Odabaşoğlu, Mustafa
author_sort Keleşoğlu, Zeynep
collection PubMed
description The title compound, C(15)H(12)F(3)NO(2), adopts the phenol–imine tautomeric form, with the H atom attached to oxygen rather than to nitro­gen. There are two independent mol­ecules aligned nearly parallel in the asymmetric unit with their trifloramethyl groups pointing in opposite directions. The dihedral angles between the aromatic rings are 40.43 (1)° in the first mol­ecule and 36.12 (1)° in the second. Strong intra­molecular O—H⋯N hydrogen bonding generates S(6) ring motifs. Weak inter­molecular C—H⋯O hydrogen bonds link the independent mol­ecules separately into sheets normal to [010]. In addition, C—H⋯π inter­actions are also observed. The F atoms of the trifluoro­methyl groups are disordered over two sets of sites with refined site occupancies of 0.59 (2)/0.41 (2) and 0.62 (3)/0.38 (3), respectively.
format Text
id pubmed-2971825
institution National Center for Biotechnology Information
language English
publishDate 2009
publisher International Union of Crystallography
record_format MEDLINE/PubMed
spelling pubmed-29718252010-12-30 (E)-4-Meth­oxy-2-[3-(trifluoro­meth­yl)phenyl­imino­meth­yl]phenol Keleşoğlu, Zeynep Büyükgüngör, Orhan Albayrak, Çiğdem Odabaşoğlu, Mustafa Acta Crystallogr Sect E Struct Rep Online Organic Papers The title compound, C(15)H(12)F(3)NO(2), adopts the phenol–imine tautomeric form, with the H atom attached to oxygen rather than to nitro­gen. There are two independent mol­ecules aligned nearly parallel in the asymmetric unit with their trifloramethyl groups pointing in opposite directions. The dihedral angles between the aromatic rings are 40.43 (1)° in the first mol­ecule and 36.12 (1)° in the second. Strong intra­molecular O—H⋯N hydrogen bonding generates S(6) ring motifs. Weak inter­molecular C—H⋯O hydrogen bonds link the independent mol­ecules separately into sheets normal to [010]. In addition, C—H⋯π inter­actions are also observed. The F atoms of the trifluoro­methyl groups are disordered over two sets of sites with refined site occupancies of 0.59 (2)/0.41 (2) and 0.62 (3)/0.38 (3), respectively. International Union of Crystallography 2009-11-28 /pmc/articles/PMC2971825/ /pubmed/21578946 http://dx.doi.org/10.1107/S160053680905034X Text en © Keleşoğlu et al. 2009 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Organic Papers
Keleşoğlu, Zeynep
Büyükgüngör, Orhan
Albayrak, Çiğdem
Odabaşoğlu, Mustafa
(E)-4-Meth­oxy-2-[3-(trifluoro­meth­yl)phenyl­imino­meth­yl]phenol
title (E)-4-Meth­oxy-2-[3-(trifluoro­meth­yl)phenyl­imino­meth­yl]phenol
title_full (E)-4-Meth­oxy-2-[3-(trifluoro­meth­yl)phenyl­imino­meth­yl]phenol
title_fullStr (E)-4-Meth­oxy-2-[3-(trifluoro­meth­yl)phenyl­imino­meth­yl]phenol
title_full_unstemmed (E)-4-Meth­oxy-2-[3-(trifluoro­meth­yl)phenyl­imino­meth­yl]phenol
title_short (E)-4-Meth­oxy-2-[3-(trifluoro­meth­yl)phenyl­imino­meth­yl]phenol
title_sort (e)-4-meth­oxy-2-[3-(trifluoro­meth­yl)phenyl­imino­meth­yl]phenol
topic Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2971825/
https://www.ncbi.nlm.nih.gov/pubmed/21578946
http://dx.doi.org/10.1107/S160053680905034X
work_keys_str_mv AT kelesogluzeynep e4methoxy23trifluoromethylphenyliminomethylphenol
AT buyukgungororhan e4methoxy23trifluoromethylphenyliminomethylphenol
AT albayrakcigdem e4methoxy23trifluoromethylphenyliminomethylphenol
AT odabasoglumustafa e4methoxy23trifluoromethylphenyliminomethylphenol