Sodium scandium diphosphate, NaScP(2)O(7), isotypic with α-NaTi(III)P(2)O(7)

Crystals of the title compound, NaScP(2)O(7), were grown by a flux method. The crystal structure is isotypic with those of α-NaTiP(2)O(7), NaYbP(2)O(7) and NaLuP(2)O(7), and is closely related to that of NaYP(2)O(7). The structural set-up consists of a three-dimensional framework of P(2)O(7) units t...

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Detalles Bibliográficos
Autores principales: Cempírek, Jan, Škoda, Radek, Žák, Zdirad
Formato: Texto
Lenguaje:English
Publicado: International Union of Crystallography 2009
Materias:
Inorganic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2971830/
https://www.ncbi.nlm.nih.gov/pubmed/21578541
http://dx.doi.org/10.1107/S1600536809046224
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author Cempírek, Jan
Škoda, Radek
Žák, Zdirad
author_facet Cempírek, Jan
Škoda, Radek
Žák, Zdirad
author_sort Cempírek, Jan
collection PubMed
description Crystals of the title compound, NaScP(2)O(7), were grown by a flux method. The crystal structure is isotypic with those of α-NaTiP(2)O(7), NaYbP(2)O(7) and NaLuP(2)O(7), and is closely related to that of NaYP(2)O(7). The structural set-up consists of a three-dimensional framework of P(2)O(7) units that are corner-shared by ScO(6) octa­hedra, forming tunnels running parallel to [010]. The Na atoms are situated in the tunnels and are surrounded by nine O atoms in a distorted environment.
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spelling pubmed-29718302010-12-30 Sodium scandium diphosphate, NaScP(2)O(7), isotypic with α-NaTi(III)P(2)O(7) Cempírek, Jan Škoda, Radek Žák, Zdirad Acta Crystallogr Sect E Struct Rep Online Inorganic Papers Crystals of the title compound, NaScP(2)O(7), were grown by a flux method. The crystal structure is isotypic with those of α-NaTiP(2)O(7), NaYbP(2)O(7) and NaLuP(2)O(7), and is closely related to that of NaYP(2)O(7). The structural set-up consists of a three-dimensional framework of P(2)O(7) units that are corner-shared by ScO(6) octa­hedra, forming tunnels running parallel to [010]. The Na atoms are situated in the tunnels and are surrounded by nine O atoms in a distorted environment. International Union of Crystallography 2009-11-07 /pmc/articles/PMC2971830/ /pubmed/21578541 http://dx.doi.org/10.1107/S1600536809046224 Text en © Cempírek et al. 2009 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Inorganic Papers
Cempírek, Jan
Škoda, Radek
Žák, Zdirad
Sodium scandium diphosphate, NaScP(2)O(7), isotypic with α-NaTi(III)P(2)O(7)
title Sodium scandium diphosphate, NaScP(2)O(7), isotypic with α-NaTi(III)P(2)O(7)
title_full Sodium scandium diphosphate, NaScP(2)O(7), isotypic with α-NaTi(III)P(2)O(7)
title_fullStr Sodium scandium diphosphate, NaScP(2)O(7), isotypic with α-NaTi(III)P(2)O(7)
title_full_unstemmed Sodium scandium diphosphate, NaScP(2)O(7), isotypic with α-NaTi(III)P(2)O(7)
title_short Sodium scandium diphosphate, NaScP(2)O(7), isotypic with α-NaTi(III)P(2)O(7)
title_sort sodium scandium diphosphate, nascp(2)o(7), isotypic with α-nati(iii)p(2)o(7)
topic Inorganic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2971830/
https://www.ncbi.nlm.nih.gov/pubmed/21578541
http://dx.doi.org/10.1107/S1600536809046224
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AT zakzdirad sodiumscandiumdiphosphatenascp2o7isotypicwithanatiiiip2o7

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