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2-Isopropyl-5-methylcyclohexyl 5-acetoxy-1,3-oxathiolane-2-carboxylate
In the title compound, C(16)H(26)O(5)S, the oxathiolane ring adopts an envelope conformation, with the S atom 0.793 (3) Å out of the mean plane of the remaining four atoms. The cyclohexane ring of the menthol fragment adopts an almost ideal chair conformation, with all substituents in the equatori...
Autores principales: | , , , , |
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Formato: | Texto |
Lenguaje: | English |
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International Union of Crystallography
2009
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Materias: | |
Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2971831/ https://www.ncbi.nlm.nih.gov/pubmed/21578885 http://dx.doi.org/10.1107/S1600536809046492 |
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author | Dutkiewicz, Grzegorz Chidan Kumar, C. S. Yathirajan, H. S. Mayekar, A. N. Kubicki, Maciej |
author_facet | Dutkiewicz, Grzegorz Chidan Kumar, C. S. Yathirajan, H. S. Mayekar, A. N. Kubicki, Maciej |
author_sort | Dutkiewicz, Grzegorz |
collection | PubMed |
description | In the title compound, C(16)H(26)O(5)S, the oxathiolane ring adopts an envelope conformation, with the S atom 0.793 (3) Å out of the mean plane of the remaining four atoms. The cyclohexane ring of the menthol fragment adopts an almost ideal chair conformation, with all substituents in the equatorial positions. In the crystal, relatively strong, short and linear C—H⋯O hydrogen bonds link the molecules into the chains along [100] direction. The chains are packed into the crystal structure by means of weak dispersive interactions. Intermolecular C—H⋯S interactions are also observed. |
format | Text |
id | pubmed-2971831 |
institution | National Center for Biotechnology Information |
language | English |
publishDate | 2009 |
publisher | International Union of Crystallography |
record_format | MEDLINE/PubMed |
spelling | pubmed-29718312010-12-30 2-Isopropyl-5-methylcyclohexyl 5-acetoxy-1,3-oxathiolane-2-carboxylate Dutkiewicz, Grzegorz Chidan Kumar, C. S. Yathirajan, H. S. Mayekar, A. N. Kubicki, Maciej Acta Crystallogr Sect E Struct Rep Online Organic Papers In the title compound, C(16)H(26)O(5)S, the oxathiolane ring adopts an envelope conformation, with the S atom 0.793 (3) Å out of the mean plane of the remaining four atoms. The cyclohexane ring of the menthol fragment adopts an almost ideal chair conformation, with all substituents in the equatorial positions. In the crystal, relatively strong, short and linear C—H⋯O hydrogen bonds link the molecules into the chains along [100] direction. The chains are packed into the crystal structure by means of weak dispersive interactions. Intermolecular C—H⋯S interactions are also observed. International Union of Crystallography 2009-11-21 /pmc/articles/PMC2971831/ /pubmed/21578885 http://dx.doi.org/10.1107/S1600536809046492 Text en © Dutkiewicz et al. 2009 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited. |
spellingShingle | Organic Papers Dutkiewicz, Grzegorz Chidan Kumar, C. S. Yathirajan, H. S. Mayekar, A. N. Kubicki, Maciej 2-Isopropyl-5-methylcyclohexyl 5-acetoxy-1,3-oxathiolane-2-carboxylate |
title | 2-Isopropyl-5-methylcyclohexyl 5-acetoxy-1,3-oxathiolane-2-carboxylate |
title_full | 2-Isopropyl-5-methylcyclohexyl 5-acetoxy-1,3-oxathiolane-2-carboxylate |
title_fullStr | 2-Isopropyl-5-methylcyclohexyl 5-acetoxy-1,3-oxathiolane-2-carboxylate |
title_full_unstemmed | 2-Isopropyl-5-methylcyclohexyl 5-acetoxy-1,3-oxathiolane-2-carboxylate |
title_short | 2-Isopropyl-5-methylcyclohexyl 5-acetoxy-1,3-oxathiolane-2-carboxylate |
title_sort | 2-isopropyl-5-methylcyclohexyl 5-acetoxy-1,3-oxathiolane-2-carboxylate |
topic | Organic Papers |
url | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2971831/ https://www.ncbi.nlm.nih.gov/pubmed/21578885 http://dx.doi.org/10.1107/S1600536809046492 |
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