Chlorido(1-cyclo­pentyl­idene-4-ethyl­thio­semicarbazidato-κ(2) N (1),S)diphenyl­tin(IV)

The Sn atom in the title compound, [Sn(C(6)H(5))(2)(C(8)H(14)N(3)S)Cl], is penta­coordinated with a trigonal-bipyramidal coordination geometry. The 1-cyclo­pentyl­idene-4-ethyl­thio­semicarbazidate (cpetsc) ligand coordinates through the S atom and the N atom bonds to the cyclo­pentyl group, forming...

Descripción completa

Detalles Bibliográficos
Autores principales: Venkatraman, Ramaiyer, Sitole, Lungile, Fronczek, Frank R.
Formato: Texto
Lenguaje:English
Publicado: International Union of Crystallography 2009
Materias:
Metal-Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2971835/
https://www.ncbi.nlm.nih.gov/pubmed/21578665
http://dx.doi.org/10.1107/S1600536809047400
Descripción
Sumario:The Sn atom in the title compound, [Sn(C(6)H(5))(2)(C(8)H(14)N(3)S)Cl], is penta­coordinated with a trigonal-bipyramidal coordination geometry. The 1-cyclo­pentyl­idene-4-ethyl­thio­semicarbazidate (cpetsc) ligand coordinates through the S atom and the N atom bonds to the cyclo­pentyl group, forming a five-membered ring with the Sn center. The chloride ligand and the coordinated N atom are in axial positions. In the crystal structure, inter­molecular N—H⋯Cl hydrogen bonds form chains along [101].

Ejemplares similares