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Chlorido(1-cyclopentylidene-4-ethylthiosemicarbazidato-κ(2) N (1),S)diphenyltin(IV)
The Sn atom in the title compound, [Sn(C(6)H(5))(2)(C(8)H(14)N(3)S)Cl], is pentacoordinated with a trigonal-bipyramidal coordination geometry. The 1-cyclopentylidene-4-ethylthiosemicarbazidate (cpetsc) ligand coordinates through the S atom and the N atom bonds to the cyclopentyl group, forming...
Autores principales: | , , |
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Formato: | Texto |
Lenguaje: | English |
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International Union of Crystallography
2009
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Materias: | |
Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2971835/ https://www.ncbi.nlm.nih.gov/pubmed/21578665 http://dx.doi.org/10.1107/S1600536809047400 |
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author | Venkatraman, Ramaiyer Sitole, Lungile Fronczek, Frank R. |
author_facet | Venkatraman, Ramaiyer Sitole, Lungile Fronczek, Frank R. |
author_sort | Venkatraman, Ramaiyer |
collection | PubMed |
description | The Sn atom in the title compound, [Sn(C(6)H(5))(2)(C(8)H(14)N(3)S)Cl], is pentacoordinated with a trigonal-bipyramidal coordination geometry. The 1-cyclopentylidene-4-ethylthiosemicarbazidate (cpetsc) ligand coordinates through the S atom and the N atom bonds to the cyclopentyl group, forming a five-membered ring with the Sn center. The chloride ligand and the coordinated N atom are in axial positions. In the crystal structure, intermolecular N—H⋯Cl hydrogen bonds form chains along [101]. |
format | Text |
id | pubmed-2971835 |
institution | National Center for Biotechnology Information |
language | English |
publishDate | 2009 |
publisher | International Union of Crystallography |
record_format | MEDLINE/PubMed |
spelling | pubmed-29718352010-12-30 Chlorido(1-cyclopentylidene-4-ethylthiosemicarbazidato-κ(2) N (1),S)diphenyltin(IV) Venkatraman, Ramaiyer Sitole, Lungile Fronczek, Frank R. Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers The Sn atom in the title compound, [Sn(C(6)H(5))(2)(C(8)H(14)N(3)S)Cl], is pentacoordinated with a trigonal-bipyramidal coordination geometry. The 1-cyclopentylidene-4-ethylthiosemicarbazidate (cpetsc) ligand coordinates through the S atom and the N atom bonds to the cyclopentyl group, forming a five-membered ring with the Sn center. The chloride ligand and the coordinated N atom are in axial positions. In the crystal structure, intermolecular N—H⋯Cl hydrogen bonds form chains along [101]. International Union of Crystallography 2009-11-21 /pmc/articles/PMC2971835/ /pubmed/21578665 http://dx.doi.org/10.1107/S1600536809047400 Text en © Venkatraman et al. 2009 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited. |
spellingShingle | Metal-Organic Papers Venkatraman, Ramaiyer Sitole, Lungile Fronczek, Frank R. Chlorido(1-cyclopentylidene-4-ethylthiosemicarbazidato-κ(2) N (1),S)diphenyltin(IV) |
title | Chlorido(1-cyclopentylidene-4-ethylthiosemicarbazidato-κ(2)
N
(1),S)diphenyltin(IV) |
title_full | Chlorido(1-cyclopentylidene-4-ethylthiosemicarbazidato-κ(2)
N
(1),S)diphenyltin(IV) |
title_fullStr | Chlorido(1-cyclopentylidene-4-ethylthiosemicarbazidato-κ(2)
N
(1),S)diphenyltin(IV) |
title_full_unstemmed | Chlorido(1-cyclopentylidene-4-ethylthiosemicarbazidato-κ(2)
N
(1),S)diphenyltin(IV) |
title_short | Chlorido(1-cyclopentylidene-4-ethylthiosemicarbazidato-κ(2)
N
(1),S)diphenyltin(IV) |
title_sort | chlorido(1-cyclopentylidene-4-ethylthiosemicarbazidato-κ(2)
n
(1),s)diphenyltin(iv) |
topic | Metal-Organic Papers |
url | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2971835/ https://www.ncbi.nlm.nih.gov/pubmed/21578665 http://dx.doi.org/10.1107/S1600536809047400 |
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