Chlorido(1-cyclo­pentyl­idene-4-ethyl­thio­semicarbazidato-κ(2) N (1),S)diphenyl­tin(IV)

The Sn atom in the title compound, [Sn(C(6)H(5))(2)(C(8)H(14)N(3)S)Cl], is penta­coordinated with a trigonal-bipyramidal coordination geometry. The 1-cyclo­pentyl­idene-4-ethyl­thio­semicarbazidate (cpetsc) ligand coordinates through the S atom and the N atom bonds to the cyclo­pentyl group, forming...

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Detalles Bibliográficos
Autores principales: Venkatraman, Ramaiyer, Sitole, Lungile, Fronczek, Frank R.
Formato: Texto
Lenguaje:English
Publicado: International Union of Crystallography 2009
Materias:
Metal-Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2971835/
https://www.ncbi.nlm.nih.gov/pubmed/21578665
http://dx.doi.org/10.1107/S1600536809047400
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author Venkatraman, Ramaiyer
Sitole, Lungile
Fronczek, Frank R.
author_facet Venkatraman, Ramaiyer
Sitole, Lungile
Fronczek, Frank R.
author_sort Venkatraman, Ramaiyer
collection PubMed
description The Sn atom in the title compound, [Sn(C(6)H(5))(2)(C(8)H(14)N(3)S)Cl], is penta­coordinated with a trigonal-bipyramidal coordination geometry. The 1-cyclo­pentyl­idene-4-ethyl­thio­semicarbazidate (cpetsc) ligand coordinates through the S atom and the N atom bonds to the cyclo­pentyl group, forming a five-membered ring with the Sn center. The chloride ligand and the coordinated N atom are in axial positions. In the crystal structure, inter­molecular N—H⋯Cl hydrogen bonds form chains along [101].
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spelling pubmed-29718352010-12-30 Chlorido(1-cyclo­pentyl­idene-4-ethyl­thio­semicarbazidato-κ(2) N (1),S)diphenyl­tin(IV) Venkatraman, Ramaiyer Sitole, Lungile Fronczek, Frank R. Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers The Sn atom in the title compound, [Sn(C(6)H(5))(2)(C(8)H(14)N(3)S)Cl], is penta­coordinated with a trigonal-bipyramidal coordination geometry. The 1-cyclo­pentyl­idene-4-ethyl­thio­semicarbazidate (cpetsc) ligand coordinates through the S atom and the N atom bonds to the cyclo­pentyl group, forming a five-membered ring with the Sn center. The chloride ligand and the coordinated N atom are in axial positions. In the crystal structure, inter­molecular N—H⋯Cl hydrogen bonds form chains along [101]. International Union of Crystallography 2009-11-21 /pmc/articles/PMC2971835/ /pubmed/21578665 http://dx.doi.org/10.1107/S1600536809047400 Text en © Venkatraman et al. 2009 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Metal-Organic Papers
Venkatraman, Ramaiyer
Sitole, Lungile
Fronczek, Frank R.
Chlorido(1-cyclo­pentyl­idene-4-ethyl­thio­semicarbazidato-κ(2) N (1),S)diphenyl­tin(IV)
title Chlorido(1-cyclo­pentyl­idene-4-ethyl­thio­semicarbazidato-κ(2) N (1),S)diphenyl­tin(IV)
title_full Chlorido(1-cyclo­pentyl­idene-4-ethyl­thio­semicarbazidato-κ(2) N (1),S)diphenyl­tin(IV)
title_fullStr Chlorido(1-cyclo­pentyl­idene-4-ethyl­thio­semicarbazidato-κ(2) N (1),S)diphenyl­tin(IV)
title_full_unstemmed Chlorido(1-cyclo­pentyl­idene-4-ethyl­thio­semicarbazidato-κ(2) N (1),S)diphenyl­tin(IV)
title_short Chlorido(1-cyclo­pentyl­idene-4-ethyl­thio­semicarbazidato-κ(2) N (1),S)diphenyl­tin(IV)
title_sort chlorido(1-cyclo­pentyl­idene-4-ethyl­thio­semicarbazidato-κ(2) n (1),s)diphenyl­tin(iv)
topic Metal-Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2971835/
https://www.ncbi.nlm.nih.gov/pubmed/21578665
http://dx.doi.org/10.1107/S1600536809047400
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AT fronczekfrankr chlorido1cyclopentylidene4ethylthiosemicarbazidatok2n1sdiphenyltiniv

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