trans-Bis[4-amino-N-(pyrimidin-2-yl)benzene­sulfonamidato]dipyridine­nickel(II) hemihydrate

The asymmetric unit of the title compound, [Ni(C(10)H(9)N(4)O(2)S)(2)(C(5)H(5)N)(2)]·0.5H(2)O, contains the distorted octa­hedral trans-[Ni(sdz)(2)(py)(2)] (sdz is the sulfadiazine anion and py is pyridine) complex mol­ecule and half of a water mol­ecule. A three-dimensional network is generated by...

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Detalles Bibliográficos
Autores principales: Wang, Yan-Fei, Li, Fu-Xing, Peng, Yan, Chen, Zhen-Feng, Liang, Hong
Formato: Texto
Lenguaje:English
Publicado: International Union of Crystallography 2009
Materias:
Metal-Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2971836/
https://www.ncbi.nlm.nih.gov/pubmed/21578614
http://dx.doi.org/10.1107/S1600536809043621
Descripción
Sumario:The asymmetric unit of the title compound, [Ni(C(10)H(9)N(4)O(2)S)(2)(C(5)H(5)N)(2)]·0.5H(2)O, contains the distorted octa­hedral trans-[Ni(sdz)(2)(py)(2)] (sdz is the sulfadiazine anion and py is pyridine) complex mol­ecule and half of a water mol­ecule. A three-dimensional network is generated by N—H⋯O and O—H⋯O hydrogen bonds and C—H⋯O inter­actions between the complex and the water mol­ecules.

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