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(3-Allyloxypicolinato-κ(2) N,O (2))bis[3,5-difluoro-2-(2-pyridyl)phenyl-κ(2)C(1),N]iridium(III)
The title complex, [Ir(C(11)H(6)F(2)N)(2)(C(9)H(8)NO(3))], consists of one Ir(III) ion, two C,N-bidentate 3,5-difluoro-2-(2-pyridyl)phenyl (F(2)ppy) ligands and one N,O-bidentate 3-allyloxypicolinate (pic-3-Oall) ligand. The Ir(III) ion is hexacoordinated by two C atoms and two N atoms from the F...
Autores principales: | , |
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Formato: | Texto |
Lenguaje: | English |
Publicado: |
International Union of Crystallography
2009
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Materias: | |
Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2971841/ https://www.ncbi.nlm.nih.gov/pubmed/21578586 http://dx.doi.org/10.1107/S1600536809046479 |
Sumario: | The title complex, [Ir(C(11)H(6)F(2)N)(2)(C(9)H(8)NO(3))], consists of one Ir(III) ion, two C,N-bidentate 3,5-difluoro-2-(2-pyridyl)phenyl (F(2)ppy) ligands and one N,O-bidentate 3-allyloxypicolinate (pic-3-Oall) ligand. The Ir(III) ion is hexacoordinated by two C atoms and two N atoms from the F(2)ppy ligands and one N atom and one carboxylate O atom from the pic-3-Oall ligand, displaying a distorted octahedral geometry. In the crystal structure, weak intermolecular C—H⋯F and C—H⋯O hydrogen bonds link the complex molecules into a three-dimensional supramolecular structure. |
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