trans-Bis(4,6-dimethyl­pyrimidine-2-thiol­ato-κ(2) N,S)bis­(thio­urea-κS)nickel(II)

In the title complex, [Ni(C(6)H(7)N(2)S)(2)(CH(4)N(2)S)(2)], the central Ni atom (located on a centre of inversion) is six-coordinated by two monoanionic N,S-chelating 4,6-dimethyl­pyrimidine-2-thiol­ate ligands and two trans S-coordinating thio­urea groups. The trans-N(2)S(4) donor set defines a di...

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Detalles Bibliográficos
Autores principales: Zhu, Jing, Wang, Jian-Gang, Duan, Taike, Zhang, Qian-Feng
Formato: Texto
Lenguaje:English
Publicado: International Union of Crystallography 2009
Materias:
Metal-Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2971843/
https://www.ncbi.nlm.nih.gov/pubmed/21578701
http://dx.doi.org/10.1107/S1600536809050223
Descripción
Sumario:In the title complex, [Ni(C(6)H(7)N(2)S)(2)(CH(4)N(2)S)(2)], the central Ni atom (located on a centre of inversion) is six-coordinated by two monoanionic N,S-chelating 4,6-dimethyl­pyrimidine-2-thiol­ate ligands and two trans S-coordinating thio­urea groups. The trans-N(2)S(4) donor set defines a distorted octa­hedral geometry.

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