trans-Bis(4,6-dimethyl­pyrimidine-2-thiol­ato-κ(2) N,S)bis­(thio­urea-κS)nickel(II)

In the title complex, [Ni(C(6)H(7)N(2)S)(2)(CH(4)N(2)S)(2)], the central Ni atom (located on a centre of inversion) is six-coordinated by two monoanionic N,S-chelating 4,6-dimethyl­pyrimidine-2-thiol­ate ligands and two trans S-coordinating thio­urea groups. The trans-N(2)S(4) donor set defines a di...

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Detalles Bibliográficos
Autores principales: Zhu, Jing, Wang, Jian-Gang, Duan, Taike, Zhang, Qian-Feng
Formato: Texto
Lenguaje:English
Publicado: International Union of Crystallography 2009
Materias:
Metal-Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2971843/
https://www.ncbi.nlm.nih.gov/pubmed/21578701
http://dx.doi.org/10.1107/S1600536809050223
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author Zhu, Jing
Wang, Jian-Gang
Duan, Taike
Zhang, Qian-Feng
author_facet Zhu, Jing
Wang, Jian-Gang
Duan, Taike
Zhang, Qian-Feng
author_sort Zhu, Jing
collection PubMed
description In the title complex, [Ni(C(6)H(7)N(2)S)(2)(CH(4)N(2)S)(2)], the central Ni atom (located on a centre of inversion) is six-coordinated by two monoanionic N,S-chelating 4,6-dimethyl­pyrimidine-2-thiol­ate ligands and two trans S-coordinating thio­urea groups. The trans-N(2)S(4) donor set defines a distorted octa­hedral geometry.
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spelling pubmed-29718432010-12-30 trans-Bis(4,6-dimethyl­pyrimidine-2-thiol­ato-κ(2) N,S)bis­(thio­urea-κS)nickel(II) Zhu, Jing Wang, Jian-Gang Duan, Taike Zhang, Qian-Feng Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers In the title complex, [Ni(C(6)H(7)N(2)S)(2)(CH(4)N(2)S)(2)], the central Ni atom (located on a centre of inversion) is six-coordinated by two monoanionic N,S-chelating 4,6-dimethyl­pyrimidine-2-thiol­ate ligands and two trans S-coordinating thio­urea groups. The trans-N(2)S(4) donor set defines a distorted octa­hedral geometry. International Union of Crystallography 2009-11-28 /pmc/articles/PMC2971843/ /pubmed/21578701 http://dx.doi.org/10.1107/S1600536809050223 Text en © Zhu et al. 2009 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Metal-Organic Papers
Zhu, Jing
Wang, Jian-Gang
Duan, Taike
Zhang, Qian-Feng
trans-Bis(4,6-dimethyl­pyrimidine-2-thiol­ato-κ(2) N,S)bis­(thio­urea-κS)nickel(II)
title trans-Bis(4,6-dimethyl­pyrimidine-2-thiol­ato-κ(2) N,S)bis­(thio­urea-κS)nickel(II)
title_full trans-Bis(4,6-dimethyl­pyrimidine-2-thiol­ato-κ(2) N,S)bis­(thio­urea-κS)nickel(II)
title_fullStr trans-Bis(4,6-dimethyl­pyrimidine-2-thiol­ato-κ(2) N,S)bis­(thio­urea-κS)nickel(II)
title_full_unstemmed trans-Bis(4,6-dimethyl­pyrimidine-2-thiol­ato-κ(2) N,S)bis­(thio­urea-κS)nickel(II)
title_short trans-Bis(4,6-dimethyl­pyrimidine-2-thiol­ato-κ(2) N,S)bis­(thio­urea-κS)nickel(II)
title_sort trans-bis(4,6-dimethyl­pyrimidine-2-thiol­ato-κ(2) n,s)bis­(thio­urea-κs)nickel(ii)
topic Metal-Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2971843/
https://www.ncbi.nlm.nih.gov/pubmed/21578701
http://dx.doi.org/10.1107/S1600536809050223
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AT zhangqianfeng transbis46dimethylpyrimidine2thiolatok2nsbisthioureaksnickelii

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