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Tetrakis(μ(2)-5-methylpyrazine-2-carboxylato)-1:2κ(3) N (1),O:O;2:3κ(3) O:N (1),O;1:2κ(2) O:O′;3:4κ(2) O:O′-octaoctyl-1κ(2) C,2κ(2) C,3κ(2) C,4κ(2) C-di-μ(3)-oxido-1:2:3κ(3) O;1:3:4κ(3) O-tetratin(IV)
The title compound, [Sn(4)(C(8)H(17))(8)O(2)(C(6)H(5)N(2)O(2))(4)], is a tetranuclear Sn(IV) complex, built up by inversion symmetry around the central Sn(2)O(2) ring. The Sn(IV) coordination geometries are distorted SnO(3)C(2) trigonal-bipyramidal and distorted SnO(4)C(2) octahedral. The three-co...
| Autores principales: | , |
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| Formato: | Texto |
| Lenguaje: | English |
| Publicado: |
International Union of Crystallography
2009
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| Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2971844/ https://www.ncbi.nlm.nih.gov/pubmed/21578611 http://dx.doi.org/10.1107/S1600536809047345 |
| _version_ | 1782190682886111232 |
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| author | Gao, Zhongjun Li, Fahui |
| author_facet | Gao, Zhongjun Li, Fahui |
| author_sort | Gao, Zhongjun |
| collection | PubMed |
| description | The title compound, [Sn(4)(C(8)H(17))(8)O(2)(C(6)H(5)N(2)O(2))(4)], is a tetranuclear Sn(IV) complex, built up by inversion symmetry around the central Sn(2)O(2) ring. The Sn(IV) coordination geometries are distorted SnO(3)C(2) trigonal-bipyramidal and distorted SnO(4)C(2) octahedral. The three-coordinate μ(3)-oxido bridging O atom in the Sn(2)O(2) ring is attached to three Sn atoms. All non-H atoms, with the exception of the Sn-bonded octyl groups, lie approximately on a non-crystallographic mirror plane. |
| format | Text |
| id | pubmed-2971844 |
| institution | National Center for Biotechnology Information |
| language | English |
| publishDate | 2009 |
| publisher | International Union of Crystallography |
| record_format | MEDLINE/PubMed |
| spelling | pubmed-29718442010-12-30 Tetrakis(μ(2)-5-methylpyrazine-2-carboxylato)-1:2κ(3) N (1),O:O;2:3κ(3) O:N (1),O;1:2κ(2) O:O′;3:4κ(2) O:O′-octaoctyl-1κ(2) C,2κ(2) C,3κ(2) C,4κ(2) C-di-μ(3)-oxido-1:2:3κ(3) O;1:3:4κ(3) O-tetratin(IV) Gao, Zhongjun Li, Fahui Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers The title compound, [Sn(4)(C(8)H(17))(8)O(2)(C(6)H(5)N(2)O(2))(4)], is a tetranuclear Sn(IV) complex, built up by inversion symmetry around the central Sn(2)O(2) ring. The Sn(IV) coordination geometries are distorted SnO(3)C(2) trigonal-bipyramidal and distorted SnO(4)C(2) octahedral. The three-coordinate μ(3)-oxido bridging O atom in the Sn(2)O(2) ring is attached to three Sn atoms. All non-H atoms, with the exception of the Sn-bonded octyl groups, lie approximately on a non-crystallographic mirror plane. International Union of Crystallography 2009-11-14 /pmc/articles/PMC2971844/ /pubmed/21578611 http://dx.doi.org/10.1107/S1600536809047345 Text en © Gao and Li 2009 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited. |
| spellingShingle | Metal-Organic Papers Gao, Zhongjun Li, Fahui Tetrakis(μ(2)-5-methylpyrazine-2-carboxylato)-1:2κ(3) N (1),O:O;2:3κ(3) O:N (1),O;1:2κ(2) O:O′;3:4κ(2) O:O′-octaoctyl-1κ(2) C,2κ(2) C,3κ(2) C,4κ(2) C-di-μ(3)-oxido-1:2:3κ(3) O;1:3:4κ(3) O-tetratin(IV) |
| title | Tetrakis(μ(2)-5-methylpyrazine-2-carboxylato)-1:2κ(3)
N
(1),O:O;2:3κ(3)
O:N
(1),O;1:2κ(2)
O:O′;3:4κ(2)
O:O′-octaoctyl-1κ(2)
C,2κ(2)
C,3κ(2)
C,4κ(2)
C-di-μ(3)-oxido-1:2:3κ(3)
O;1:3:4κ(3)
O-tetratin(IV) |
| title_full | Tetrakis(μ(2)-5-methylpyrazine-2-carboxylato)-1:2κ(3)
N
(1),O:O;2:3κ(3)
O:N
(1),O;1:2κ(2)
O:O′;3:4κ(2)
O:O′-octaoctyl-1κ(2)
C,2κ(2)
C,3κ(2)
C,4κ(2)
C-di-μ(3)-oxido-1:2:3κ(3)
O;1:3:4κ(3)
O-tetratin(IV) |
| title_fullStr | Tetrakis(μ(2)-5-methylpyrazine-2-carboxylato)-1:2κ(3)
N
(1),O:O;2:3κ(3)
O:N
(1),O;1:2κ(2)
O:O′;3:4κ(2)
O:O′-octaoctyl-1κ(2)
C,2κ(2)
C,3κ(2)
C,4κ(2)
C-di-μ(3)-oxido-1:2:3κ(3)
O;1:3:4κ(3)
O-tetratin(IV) |
| title_full_unstemmed | Tetrakis(μ(2)-5-methylpyrazine-2-carboxylato)-1:2κ(3)
N
(1),O:O;2:3κ(3)
O:N
(1),O;1:2κ(2)
O:O′;3:4κ(2)
O:O′-octaoctyl-1κ(2)
C,2κ(2)
C,3κ(2)
C,4κ(2)
C-di-μ(3)-oxido-1:2:3κ(3)
O;1:3:4κ(3)
O-tetratin(IV) |
| title_short | Tetrakis(μ(2)-5-methylpyrazine-2-carboxylato)-1:2κ(3)
N
(1),O:O;2:3κ(3)
O:N
(1),O;1:2κ(2)
O:O′;3:4κ(2)
O:O′-octaoctyl-1κ(2)
C,2κ(2)
C,3κ(2)
C,4κ(2)
C-di-μ(3)-oxido-1:2:3κ(3)
O;1:3:4κ(3)
O-tetratin(IV) |
| title_sort | tetrakis(μ(2)-5-methylpyrazine-2-carboxylato)-1:2κ(3)
n
(1),o:o;2:3κ(3)
o:n
(1),o;1:2κ(2)
o:o′;3:4κ(2)
o:o′-octaoctyl-1κ(2)
c,2κ(2)
c,3κ(2)
c,4κ(2)
c-di-μ(3)-oxido-1:2:3κ(3)
o;1:3:4κ(3)
o-tetratin(iv) |
| topic | Metal-Organic Papers |
| url | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2971844/ https://www.ncbi.nlm.nih.gov/pubmed/21578611 http://dx.doi.org/10.1107/S1600536809047345 |
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