3-Acetyl-6-chloro-2-methyl-4-phenyl­quinolinium hydrogen sulfate

In the title salt, C(18)H(15)ClNO(+)·HSO(4) (−), the quinolinium ring system is approximately planar, with a maximum deviation of 0.028 (2) Å, and forms a dihedral angle of 78.43 (4)° with the attached phenyl ring. A pair of inter­molecular O—H⋯O hydrogen bonds links two hydrogen sulfate anions into...

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Autores principales: Loh, Wan-Sin, Fun, Hoong-Kun, Sarveswari, S., Vijayakumar, V., Reddy, B. Palakshi
Formato: Texto
Lenguaje:English
Publicado: International Union of Crystallography 2009
Materias:
Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2971847/
https://www.ncbi.nlm.nih.gov/pubmed/21578864
http://dx.doi.org/10.1107/S1600536809048934
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author Loh, Wan-Sin
Fun, Hoong-Kun
Sarveswari, S.
Vijayakumar, V.
Reddy, B. Palakshi
author_facet Loh, Wan-Sin
Fun, Hoong-Kun
Sarveswari, S.
Vijayakumar, V.
Reddy, B. Palakshi
author_sort Loh, Wan-Sin
collection PubMed
description In the title salt, C(18)H(15)ClNO(+)·HSO(4) (−), the quinolinium ring system is approximately planar, with a maximum deviation of 0.028 (2) Å, and forms a dihedral angle of 78.43 (4)° with the attached phenyl ring. A pair of inter­molecular O—H⋯O hydrogen bonds links two hydrogen sulfate anions into a dimer, generating a R (2) (2)(8) ring motif. Inter­molecular N—H⋯O hydrogen bonds and C—H⋯O contacts link the ions into a three-dimensional network. The structure is further stabilized by C—H⋯π inter­actions
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spelling pubmed-29718472010-12-30 3-Acetyl-6-chloro-2-methyl-4-phenyl­quinolinium hydrogen sulfate Loh, Wan-Sin Fun, Hoong-Kun Sarveswari, S. Vijayakumar, V. Reddy, B. Palakshi Acta Crystallogr Sect E Struct Rep Online Organic Papers In the title salt, C(18)H(15)ClNO(+)·HSO(4) (−), the quinolinium ring system is approximately planar, with a maximum deviation of 0.028 (2) Å, and forms a dihedral angle of 78.43 (4)° with the attached phenyl ring. A pair of inter­molecular O—H⋯O hydrogen bonds links two hydrogen sulfate anions into a dimer, generating a R (2) (2)(8) ring motif. Inter­molecular N—H⋯O hydrogen bonds and C—H⋯O contacts link the ions into a three-dimensional network. The structure is further stabilized by C—H⋯π inter­actions International Union of Crystallography 2009-11-21 /pmc/articles/PMC2971847/ /pubmed/21578864 http://dx.doi.org/10.1107/S1600536809048934 Text en © Loh et al. 2009 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Organic Papers
Loh, Wan-Sin
Fun, Hoong-Kun
Sarveswari, S.
Vijayakumar, V.
Reddy, B. Palakshi
3-Acetyl-6-chloro-2-methyl-4-phenyl­quinolinium hydrogen sulfate
title 3-Acetyl-6-chloro-2-methyl-4-phenyl­quinolinium hydrogen sulfate
title_full 3-Acetyl-6-chloro-2-methyl-4-phenyl­quinolinium hydrogen sulfate
title_fullStr 3-Acetyl-6-chloro-2-methyl-4-phenyl­quinolinium hydrogen sulfate
title_full_unstemmed 3-Acetyl-6-chloro-2-methyl-4-phenyl­quinolinium hydrogen sulfate
title_short 3-Acetyl-6-chloro-2-methyl-4-phenyl­quinolinium hydrogen sulfate
title_sort 3-acetyl-6-chloro-2-methyl-4-phenyl­quinolinium hydrogen sulfate
topic Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2971847/
https://www.ncbi.nlm.nih.gov/pubmed/21578864
http://dx.doi.org/10.1107/S1600536809048934
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AT vijayakumarv 3acetyl6chloro2methyl4phenylquinoliniumhydrogensulfate
AT reddybpalakshi 3acetyl6chloro2methyl4phenylquinoliniumhydrogensulfate

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