1,5-Dimethyl-3-oxo-2-phenyl-2,3-di­hy­dro-1H-pyrazol-4-aminium 2-hydroxy­benzoate

In the title salt, C(11)H(14)N(3)O(+)·C(7)H(5)O(3) (−), the phenyl ring of the cation is oriented at an angle of 67.0 (1)° with respect to the five-membered pyrazolone ring. The carboxyl­ate plane of the anion is twisted out from the plane of the aromatic ring at an angle of 13.7 (3)°. In the crysta...

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Detalles Bibliográficos
Autores principales: Chitradevi, A., Athimoolam, S., Sridhar, B., Bahadur, S. Asath
Formato: Texto
Lenguaje:English
Publicado: International Union of Crystallography 2009
Materias:
Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2971850/
https://www.ncbi.nlm.nih.gov/pubmed/21578776
http://dx.doi.org/10.1107/S1600536809045760
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author Chitradevi, A.
Athimoolam, S.
Sridhar, B.
Bahadur, S. Asath
author_facet Chitradevi, A.
Athimoolam, S.
Sridhar, B.
Bahadur, S. Asath
author_sort Chitradevi, A.
collection PubMed
description In the title salt, C(11)H(14)N(3)O(+)·C(7)H(5)O(3) (−), the phenyl ring of the cation is oriented at an angle of 67.0 (1)° with respect to the five-membered pyrazolone ring. The carboxyl­ate plane of the anion is twisted out from the plane of the aromatic ring at an angle of 13.7 (3)°. In the crystal, the cations form hydrogen-bonded dimers with an R (2) (2)(10) ring motif. The salicylate anion has an intra­molecular O—H⋯O hydrogen bond.
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spelling pubmed-29718502010-12-30 1,5-Dimethyl-3-oxo-2-phenyl-2,3-di­hy­dro-1H-pyrazol-4-aminium 2-hydroxy­benzoate Chitradevi, A. Athimoolam, S. Sridhar, B. Bahadur, S. Asath Acta Crystallogr Sect E Struct Rep Online Organic Papers In the title salt, C(11)H(14)N(3)O(+)·C(7)H(5)O(3) (−), the phenyl ring of the cation is oriented at an angle of 67.0 (1)° with respect to the five-membered pyrazolone ring. The carboxyl­ate plane of the anion is twisted out from the plane of the aromatic ring at an angle of 13.7 (3)°. In the crystal, the cations form hydrogen-bonded dimers with an R (2) (2)(10) ring motif. The salicylate anion has an intra­molecular O—H⋯O hydrogen bond. International Union of Crystallography 2009-11-07 /pmc/articles/PMC2971850/ /pubmed/21578776 http://dx.doi.org/10.1107/S1600536809045760 Text en © Chitradevi et al. 2009 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Organic Papers
Chitradevi, A.
Athimoolam, S.
Sridhar, B.
Bahadur, S. Asath
1,5-Dimethyl-3-oxo-2-phenyl-2,3-di­hy­dro-1H-pyrazol-4-aminium 2-hydroxy­benzoate
title 1,5-Dimethyl-3-oxo-2-phenyl-2,3-di­hy­dro-1H-pyrazol-4-aminium 2-hydroxy­benzoate
title_full 1,5-Dimethyl-3-oxo-2-phenyl-2,3-di­hy­dro-1H-pyrazol-4-aminium 2-hydroxy­benzoate
title_fullStr 1,5-Dimethyl-3-oxo-2-phenyl-2,3-di­hy­dro-1H-pyrazol-4-aminium 2-hydroxy­benzoate
title_full_unstemmed 1,5-Dimethyl-3-oxo-2-phenyl-2,3-di­hy­dro-1H-pyrazol-4-aminium 2-hydroxy­benzoate
title_short 1,5-Dimethyl-3-oxo-2-phenyl-2,3-di­hy­dro-1H-pyrazol-4-aminium 2-hydroxy­benzoate
title_sort 1,5-dimethyl-3-oxo-2-phenyl-2,3-di­hy­dro-1h-pyrazol-4-aminium 2-hydroxy­benzoate
topic Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2971850/
https://www.ncbi.nlm.nih.gov/pubmed/21578776
http://dx.doi.org/10.1107/S1600536809045760
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AT athimoolams 15dimethyl3oxo2phenyl23dihydro1hpyrazol4aminium2hydroxybenzoate
AT sridharb 15dimethyl3oxo2phenyl23dihydro1hpyrazol4aminium2hydroxybenzoate
AT bahadursasath 15dimethyl3oxo2phenyl23dihydro1hpyrazol4aminium2hydroxybenzoate

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