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catena-Poly[[bis(2,2′-bipyridine-κ(2) N,N′)cadmium(II)]-μ-9,10-dioxoanthracene-1,5-disulfonato-κ(2) O (1):O (5)]
The title complex, [Cd(C(14)H(6)O(8)S(2))(C(10)H(8)N(2))(2)](n), exhibits a chain-like polymeric structure with 9,10-dioxoanthracene-1,5-disulfonate anions bridging Cd(II) atoms in a bis-monodentate mode. The Cd(II) atom shows a distorted octahedral environment, with four N atoms from two chelating...
Autores principales: | , , |
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Formato: | Texto |
Lenguaje: | English |
Publicado: |
International Union of Crystallography
2009
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Materias: | |
Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2971852/ https://www.ncbi.nlm.nih.gov/pubmed/21578612 http://dx.doi.org/10.1107/S1600536809046881 |
Sumario: | The title complex, [Cd(C(14)H(6)O(8)S(2))(C(10)H(8)N(2))(2)](n), exhibits a chain-like polymeric structure with 9,10-dioxoanthracene-1,5-disulfonate anions bridging Cd(II) atoms in a bis-monodentate mode. The Cd(II) atom shows a distorted octahedral environment, with four N atoms from two chelating 2,2′-bipyridine ligands forming the equatorial plane and two sulfonate O atoms from two 9,10-dioxoanthracene-1,5-disulfonate anions occupying the apical positions. Weak C—H⋯O hydrogen-bonding contacts and π–π interactions [centroid–centroid distances = 3.6920 (12) and 3.7095 (12) Å] connect the complex molecules into a three-dimensional supramolecular framework. |
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