Cargando…
catena-Poly[[bis(2,2′-bipyridine-κ(2) N,N′)cadmium(II)]-μ-9,10-dioxoanthracene-1,5-disulfonato-κ(2) O (1):O (5)]
The title complex, [Cd(C(14)H(6)O(8)S(2))(C(10)H(8)N(2))(2)](n), exhibits a chain-like polymeric structure with 9,10-dioxoanthracene-1,5-disulfonate anions bridging Cd(II) atoms in a bis-monodentate mode. The Cd(II) atom shows a distorted octahedral environment, with four N atoms from two chelating...
| Autores principales: | , , |
|---|---|
| Formato: | Texto |
| Lenguaje: | English |
| Publicado: |
International Union of Crystallography
2009
|
| Materias: | |
| Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2971852/ https://www.ncbi.nlm.nih.gov/pubmed/21578612 http://dx.doi.org/10.1107/S1600536809046881 |
| _version_ | 1782190684781936640 |
|---|---|
| author | Jia, Jia Zhang, Youdi Zhao, Yanhui |
| author_facet | Jia, Jia Zhang, Youdi Zhao, Yanhui |
| author_sort | Jia, Jia |
| collection | PubMed |
| description | The title complex, [Cd(C(14)H(6)O(8)S(2))(C(10)H(8)N(2))(2)](n), exhibits a chain-like polymeric structure with 9,10-dioxoanthracene-1,5-disulfonate anions bridging Cd(II) atoms in a bis-monodentate mode. The Cd(II) atom shows a distorted octahedral environment, with four N atoms from two chelating 2,2′-bipyridine ligands forming the equatorial plane and two sulfonate O atoms from two 9,10-dioxoanthracene-1,5-disulfonate anions occupying the apical positions. Weak C—H⋯O hydrogen-bonding contacts and π–π interactions [centroid–centroid distances = 3.6920 (12) and 3.7095 (12) Å] connect the complex molecules into a three-dimensional supramolecular framework. |
| format | Text |
| id | pubmed-2971852 |
| institution | National Center for Biotechnology Information |
| language | English |
| publishDate | 2009 |
| publisher | International Union of Crystallography |
| record_format | MEDLINE/PubMed |
| spelling | pubmed-29718522010-12-30 catena-Poly[[bis(2,2′-bipyridine-κ(2) N,N′)cadmium(II)]-μ-9,10-dioxoanthracene-1,5-disulfonato-κ(2) O (1):O (5)] Jia, Jia Zhang, Youdi Zhao, Yanhui Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers The title complex, [Cd(C(14)H(6)O(8)S(2))(C(10)H(8)N(2))(2)](n), exhibits a chain-like polymeric structure with 9,10-dioxoanthracene-1,5-disulfonate anions bridging Cd(II) atoms in a bis-monodentate mode. The Cd(II) atom shows a distorted octahedral environment, with four N atoms from two chelating 2,2′-bipyridine ligands forming the equatorial plane and two sulfonate O atoms from two 9,10-dioxoanthracene-1,5-disulfonate anions occupying the apical positions. Weak C—H⋯O hydrogen-bonding contacts and π–π interactions [centroid–centroid distances = 3.6920 (12) and 3.7095 (12) Å] connect the complex molecules into a three-dimensional supramolecular framework. International Union of Crystallography 2009-11-14 /pmc/articles/PMC2971852/ /pubmed/21578612 http://dx.doi.org/10.1107/S1600536809046881 Text en © Jia et al. 2009 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited. |
| spellingShingle | Metal-Organic Papers Jia, Jia Zhang, Youdi Zhao, Yanhui catena-Poly[[bis(2,2′-bipyridine-κ(2) N,N′)cadmium(II)]-μ-9,10-dioxoanthracene-1,5-disulfonato-κ(2) O (1):O (5)] |
| title |
catena-Poly[[bis(2,2′-bipyridine-κ(2)
N,N′)cadmium(II)]-μ-9,10-dioxoanthracene-1,5-disulfonato-κ(2)
O
(1):O
(5)] |
| title_full |
catena-Poly[[bis(2,2′-bipyridine-κ(2)
N,N′)cadmium(II)]-μ-9,10-dioxoanthracene-1,5-disulfonato-κ(2)
O
(1):O
(5)] |
| title_fullStr |
catena-Poly[[bis(2,2′-bipyridine-κ(2)
N,N′)cadmium(II)]-μ-9,10-dioxoanthracene-1,5-disulfonato-κ(2)
O
(1):O
(5)] |
| title_full_unstemmed |
catena-Poly[[bis(2,2′-bipyridine-κ(2)
N,N′)cadmium(II)]-μ-9,10-dioxoanthracene-1,5-disulfonato-κ(2)
O
(1):O
(5)] |
| title_short |
catena-Poly[[bis(2,2′-bipyridine-κ(2)
N,N′)cadmium(II)]-μ-9,10-dioxoanthracene-1,5-disulfonato-κ(2)
O
(1):O
(5)] |
| title_sort | catena-poly[[bis(2,2′-bipyridine-κ(2)
n,n′)cadmium(ii)]-μ-9,10-dioxoanthracene-1,5-disulfonato-κ(2)
o
(1):o
(5)] |
| topic | Metal-Organic Papers |
| url | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2971852/ https://www.ncbi.nlm.nih.gov/pubmed/21578612 http://dx.doi.org/10.1107/S1600536809046881 |
| work_keys_str_mv | AT jiajia catenapolybis22bipyridinek2nncadmiumiim910dioxoanthracene15disulfonatok2o1o5 AT zhangyoudi catenapolybis22bipyridinek2nncadmiumiim910dioxoanthracene15disulfonatok2o1o5 AT zhaoyanhui catenapolybis22bipyridinek2nncadmiumiim910dioxoanthracene15disulfonatok2o1o5 |