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Poly[triaqua(μ-butane-1,2,3,4-tetracarboxylato)dicadmium(II)]
The asymmetric unit of the title Cd(II) coordination polymer, [Cd(2)(C(8)H(6)O(8))(H(2)O)(3)](n), contains two crystallographically independent Cd(II) cations, one-half each of two independent anionic butane-1,2,3,4-tetracarboxylate units (L) and three water molecules. Both anionic units lie on i...
Autores principales: | , |
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Formato: | Texto |
Lenguaje: | English |
Publicado: |
International Union of Crystallography
2009
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Materias: | |
Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2971854/ https://www.ncbi.nlm.nih.gov/pubmed/21578592 http://dx.doi.org/10.1107/S1600536809045255 |
Sumario: | The asymmetric unit of the title Cd(II) coordination polymer, [Cd(2)(C(8)H(6)O(8))(H(2)O)(3)](n), contains two crystallographically independent Cd(II) cations, one-half each of two independent anionic butane-1,2,3,4-tetracarboxylate units (L) and three water molecules. Both anionic units lie on inversion centers. One of the Cd(II) ions is six-coordinated by four carboxylate O atoms from four L anions and two water O atoms in a distorted octahedral coordination environment. The other Cd(II) ion is eight-coordinated by seven carboxylate O atoms from four L anions and one water O atom. The anionic units bridge neighboring Cd(II) centers, forming a three-dimensional framework. O—H⋯O hydrogen-bonding interactions between the water molecules and carboxylate O atoms further stabilize the structure. |
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