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Poly[triaqua(μ-butane-1,2,3,4-tetracarboxylato)dicadmium(II)]
The asymmetric unit of the title Cd(II) coordination polymer, [Cd(2)(C(8)H(6)O(8))(H(2)O)(3)](n), contains two crystallographically independent Cd(II) cations, one-half each of two independent anionic butane-1,2,3,4-tetracarboxylate units (L) and three water molecules. Both anionic units lie on i...
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Formato: | Texto |
Lenguaje: | English |
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International Union of Crystallography
2009
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Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2971854/ https://www.ncbi.nlm.nih.gov/pubmed/21578592 http://dx.doi.org/10.1107/S1600536809045255 |
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author | Ma, Chun-Hong Yan, Yong-Sheng |
author_facet | Ma, Chun-Hong Yan, Yong-Sheng |
author_sort | Ma, Chun-Hong |
collection | PubMed |
description | The asymmetric unit of the title Cd(II) coordination polymer, [Cd(2)(C(8)H(6)O(8))(H(2)O)(3)](n), contains two crystallographically independent Cd(II) cations, one-half each of two independent anionic butane-1,2,3,4-tetracarboxylate units (L) and three water molecules. Both anionic units lie on inversion centers. One of the Cd(II) ions is six-coordinated by four carboxylate O atoms from four L anions and two water O atoms in a distorted octahedral coordination environment. The other Cd(II) ion is eight-coordinated by seven carboxylate O atoms from four L anions and one water O atom. The anionic units bridge neighboring Cd(II) centers, forming a three-dimensional framework. O—H⋯O hydrogen-bonding interactions between the water molecules and carboxylate O atoms further stabilize the structure. |
format | Text |
id | pubmed-2971854 |
institution | National Center for Biotechnology Information |
language | English |
publishDate | 2009 |
publisher | International Union of Crystallography |
record_format | MEDLINE/PubMed |
spelling | pubmed-29718542010-12-30 Poly[triaqua(μ-butane-1,2,3,4-tetracarboxylato)dicadmium(II)] Ma, Chun-Hong Yan, Yong-Sheng Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers The asymmetric unit of the title Cd(II) coordination polymer, [Cd(2)(C(8)H(6)O(8))(H(2)O)(3)](n), contains two crystallographically independent Cd(II) cations, one-half each of two independent anionic butane-1,2,3,4-tetracarboxylate units (L) and three water molecules. Both anionic units lie on inversion centers. One of the Cd(II) ions is six-coordinated by four carboxylate O atoms from four L anions and two water O atoms in a distorted octahedral coordination environment. The other Cd(II) ion is eight-coordinated by seven carboxylate O atoms from four L anions and one water O atom. The anionic units bridge neighboring Cd(II) centers, forming a three-dimensional framework. O—H⋯O hydrogen-bonding interactions between the water molecules and carboxylate O atoms further stabilize the structure. International Union of Crystallography 2009-11-11 /pmc/articles/PMC2971854/ /pubmed/21578592 http://dx.doi.org/10.1107/S1600536809045255 Text en © Ma and Yan 2009 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited. |
spellingShingle | Metal-Organic Papers Ma, Chun-Hong Yan, Yong-Sheng Poly[triaqua(μ-butane-1,2,3,4-tetracarboxylato)dicadmium(II)] |
title | Poly[triaqua(μ-butane-1,2,3,4-tetracarboxylato)dicadmium(II)] |
title_full | Poly[triaqua(μ-butane-1,2,3,4-tetracarboxylato)dicadmium(II)] |
title_fullStr | Poly[triaqua(μ-butane-1,2,3,4-tetracarboxylato)dicadmium(II)] |
title_full_unstemmed | Poly[triaqua(μ-butane-1,2,3,4-tetracarboxylato)dicadmium(II)] |
title_short | Poly[triaqua(μ-butane-1,2,3,4-tetracarboxylato)dicadmium(II)] |
title_sort | poly[triaqua(μ-butane-1,2,3,4-tetracarboxylato)dicadmium(ii)] |
topic | Metal-Organic Papers |
url | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2971854/ https://www.ncbi.nlm.nih.gov/pubmed/21578592 http://dx.doi.org/10.1107/S1600536809045255 |
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