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Poly[triaqua­(μ-butane-1,2,3,4-tetra­carboxyl­ato)dicadmium(II)]

The asymmetric unit of the title Cd(II) coordination polymer, [Cd(2)(C(8)H(6)O(8))(H(2)O)(3)](n), contains two crystallographically independent Cd(II) cations, one-half each of two independent anionic butane-1,2,3,4-tetra­carboxyl­ate units (L) and three water mol­ecules. Both anionic units lie on i...

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Detalles Bibliográficos
Autores principales: Ma, Chun-Hong, Yan, Yong-Sheng
Formato: Texto
Lenguaje:English
Publicado: International Union of Crystallography 2009
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2971854/
https://www.ncbi.nlm.nih.gov/pubmed/21578592
http://dx.doi.org/10.1107/S1600536809045255
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author Ma, Chun-Hong
Yan, Yong-Sheng
author_facet Ma, Chun-Hong
Yan, Yong-Sheng
author_sort Ma, Chun-Hong
collection PubMed
description The asymmetric unit of the title Cd(II) coordination polymer, [Cd(2)(C(8)H(6)O(8))(H(2)O)(3)](n), contains two crystallographically independent Cd(II) cations, one-half each of two independent anionic butane-1,2,3,4-tetra­carboxyl­ate units (L) and three water mol­ecules. Both anionic units lie on inversion centers. One of the Cd(II) ions is six-coordinated by four carboxyl­ate O atoms from four L anions and two water O atoms in a distorted octa­hedral coordination environment. The other Cd(II) ion is eight-coordinated by seven carboxyl­ate O atoms from four L anions and one water O atom. The anionic units bridge neighboring Cd(II) centers, forming a three-dimensional framework. O—H⋯O hydrogen-bonding inter­actions between the water mol­ecules and carboxyl­ate O atoms further stabilize the structure.
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spelling pubmed-29718542010-12-30 Poly[triaqua­(μ-butane-1,2,3,4-tetra­carboxyl­ato)dicadmium(II)] Ma, Chun-Hong Yan, Yong-Sheng Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers The asymmetric unit of the title Cd(II) coordination polymer, [Cd(2)(C(8)H(6)O(8))(H(2)O)(3)](n), contains two crystallographically independent Cd(II) cations, one-half each of two independent anionic butane-1,2,3,4-tetra­carboxyl­ate units (L) and three water mol­ecules. Both anionic units lie on inversion centers. One of the Cd(II) ions is six-coordinated by four carboxyl­ate O atoms from four L anions and two water O atoms in a distorted octa­hedral coordination environment. The other Cd(II) ion is eight-coordinated by seven carboxyl­ate O atoms from four L anions and one water O atom. The anionic units bridge neighboring Cd(II) centers, forming a three-dimensional framework. O—H⋯O hydrogen-bonding inter­actions between the water mol­ecules and carboxyl­ate O atoms further stabilize the structure. International Union of Crystallography 2009-11-11 /pmc/articles/PMC2971854/ /pubmed/21578592 http://dx.doi.org/10.1107/S1600536809045255 Text en © Ma and Yan 2009 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Metal-Organic Papers
Ma, Chun-Hong
Yan, Yong-Sheng
Poly[triaqua­(μ-butane-1,2,3,4-tetra­carboxyl­ato)dicadmium(II)]
title Poly[triaqua­(μ-butane-1,2,3,4-tetra­carboxyl­ato)dicadmium(II)]
title_full Poly[triaqua­(μ-butane-1,2,3,4-tetra­carboxyl­ato)dicadmium(II)]
title_fullStr Poly[triaqua­(μ-butane-1,2,3,4-tetra­carboxyl­ato)dicadmium(II)]
title_full_unstemmed Poly[triaqua­(μ-butane-1,2,3,4-tetra­carboxyl­ato)dicadmium(II)]
title_short Poly[triaqua­(μ-butane-1,2,3,4-tetra­carboxyl­ato)dicadmium(II)]
title_sort poly[triaqua­(μ-butane-1,2,3,4-tetra­carboxyl­ato)dicadmium(ii)]
topic Metal-Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2971854/
https://www.ncbi.nlm.nih.gov/pubmed/21578592
http://dx.doi.org/10.1107/S1600536809045255
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