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1-[6-(9H-Carbazol-9-yl)hex­yl]-2-phenyl-1H-benzimidazole

The mol­ecule of the title compound, C(31)H(29)N(3), contains a hexyl chain, a coordination unit (benzimidazole) and a functional group (carbazole). The benzimidazole ring is not coplanar with either the phenyl ring or the carbazole system, making dihedral angles of 43.26 (3) and 39.03 (2)°, respect...

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Detalles Bibliográficos
Autores principales: Zhao, Yu-Ling, Yu, Tian-Zhi, Meng, Jing
Formato: Texto
Lenguaje:English
Publicado: International Union of Crystallography 2009
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2971855/
https://www.ncbi.nlm.nih.gov/pubmed/21578806
http://dx.doi.org/10.1107/S1600536809046820
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author Zhao, Yu-Ling
Yu, Tian-Zhi
Meng, Jing
author_facet Zhao, Yu-Ling
Yu, Tian-Zhi
Meng, Jing
author_sort Zhao, Yu-Ling
collection PubMed
description The mol­ecule of the title compound, C(31)H(29)N(3), contains a hexyl chain, a coordination unit (benzimidazole) and a functional group (carbazole). The benzimidazole ring is not coplanar with either the phenyl ring or the carbazole system, making dihedral angles of 43.26 (3) and 39.03 (2)°, respectively. The dihedral angle between the phenyl ring and the carbazole system is 24.42 (3)°. The hexyl C(β) atom (with respect to benzimidazole) deviates by 1.124 (2) Å from the benzimidazole plane, although the C(α) atom lies in the plane. The hexyl C(β) atom (with respect to carbazole) deviates by 1.315 (1) Å from the carbazole plane, although the C(α) atom lies in the plane. The crystal structure is stabilized by inter­molecular C—H⋯π inter­actions.
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spelling pubmed-29718552010-12-30 1-[6-(9H-Carbazol-9-yl)hex­yl]-2-phenyl-1H-benzimidazole Zhao, Yu-Ling Yu, Tian-Zhi Meng, Jing Acta Crystallogr Sect E Struct Rep Online Organic Papers The mol­ecule of the title compound, C(31)H(29)N(3), contains a hexyl chain, a coordination unit (benzimidazole) and a functional group (carbazole). The benzimidazole ring is not coplanar with either the phenyl ring or the carbazole system, making dihedral angles of 43.26 (3) and 39.03 (2)°, respectively. The dihedral angle between the phenyl ring and the carbazole system is 24.42 (3)°. The hexyl C(β) atom (with respect to benzimidazole) deviates by 1.124 (2) Å from the benzimidazole plane, although the C(α) atom lies in the plane. The hexyl C(β) atom (with respect to carbazole) deviates by 1.315 (1) Å from the carbazole plane, although the C(α) atom lies in the plane. The crystal structure is stabilized by inter­molecular C—H⋯π inter­actions. International Union of Crystallography 2009-11-14 /pmc/articles/PMC2971855/ /pubmed/21578806 http://dx.doi.org/10.1107/S1600536809046820 Text en © Zhao et al. 2009 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Organic Papers
Zhao, Yu-Ling
Yu, Tian-Zhi
Meng, Jing
1-[6-(9H-Carbazol-9-yl)hex­yl]-2-phenyl-1H-benzimidazole
title 1-[6-(9H-Carbazol-9-yl)hex­yl]-2-phenyl-1H-benzimidazole
title_full 1-[6-(9H-Carbazol-9-yl)hex­yl]-2-phenyl-1H-benzimidazole
title_fullStr 1-[6-(9H-Carbazol-9-yl)hex­yl]-2-phenyl-1H-benzimidazole
title_full_unstemmed 1-[6-(9H-Carbazol-9-yl)hex­yl]-2-phenyl-1H-benzimidazole
title_short 1-[6-(9H-Carbazol-9-yl)hex­yl]-2-phenyl-1H-benzimidazole
title_sort 1-[6-(9h-carbazol-9-yl)hex­yl]-2-phenyl-1h-benzimidazole
topic Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2971855/
https://www.ncbi.nlm.nih.gov/pubmed/21578806
http://dx.doi.org/10.1107/S1600536809046820
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