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1-[6-(9H-Carbazol-9-yl)hexyl]-2-phenyl-1H-benzimidazole
The molecule of the title compound, C(31)H(29)N(3), contains a hexyl chain, a coordination unit (benzimidazole) and a functional group (carbazole). The benzimidazole ring is not coplanar with either the phenyl ring or the carbazole system, making dihedral angles of 43.26 (3) and 39.03 (2)°, respect...
Autores principales: | , , |
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Formato: | Texto |
Lenguaje: | English |
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International Union of Crystallography
2009
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Materias: | |
Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2971855/ https://www.ncbi.nlm.nih.gov/pubmed/21578806 http://dx.doi.org/10.1107/S1600536809046820 |
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author | Zhao, Yu-Ling Yu, Tian-Zhi Meng, Jing |
author_facet | Zhao, Yu-Ling Yu, Tian-Zhi Meng, Jing |
author_sort | Zhao, Yu-Ling |
collection | PubMed |
description | The molecule of the title compound, C(31)H(29)N(3), contains a hexyl chain, a coordination unit (benzimidazole) and a functional group (carbazole). The benzimidazole ring is not coplanar with either the phenyl ring or the carbazole system, making dihedral angles of 43.26 (3) and 39.03 (2)°, respectively. The dihedral angle between the phenyl ring and the carbazole system is 24.42 (3)°. The hexyl C(β) atom (with respect to benzimidazole) deviates by 1.124 (2) Å from the benzimidazole plane, although the C(α) atom lies in the plane. The hexyl C(β) atom (with respect to carbazole) deviates by 1.315 (1) Å from the carbazole plane, although the C(α) atom lies in the plane. The crystal structure is stabilized by intermolecular C—H⋯π interactions. |
format | Text |
id | pubmed-2971855 |
institution | National Center for Biotechnology Information |
language | English |
publishDate | 2009 |
publisher | International Union of Crystallography |
record_format | MEDLINE/PubMed |
spelling | pubmed-29718552010-12-30 1-[6-(9H-Carbazol-9-yl)hexyl]-2-phenyl-1H-benzimidazole Zhao, Yu-Ling Yu, Tian-Zhi Meng, Jing Acta Crystallogr Sect E Struct Rep Online Organic Papers The molecule of the title compound, C(31)H(29)N(3), contains a hexyl chain, a coordination unit (benzimidazole) and a functional group (carbazole). The benzimidazole ring is not coplanar with either the phenyl ring or the carbazole system, making dihedral angles of 43.26 (3) and 39.03 (2)°, respectively. The dihedral angle between the phenyl ring and the carbazole system is 24.42 (3)°. The hexyl C(β) atom (with respect to benzimidazole) deviates by 1.124 (2) Å from the benzimidazole plane, although the C(α) atom lies in the plane. The hexyl C(β) atom (with respect to carbazole) deviates by 1.315 (1) Å from the carbazole plane, although the C(α) atom lies in the plane. The crystal structure is stabilized by intermolecular C—H⋯π interactions. International Union of Crystallography 2009-11-14 /pmc/articles/PMC2971855/ /pubmed/21578806 http://dx.doi.org/10.1107/S1600536809046820 Text en © Zhao et al. 2009 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited. |
spellingShingle | Organic Papers Zhao, Yu-Ling Yu, Tian-Zhi Meng, Jing 1-[6-(9H-Carbazol-9-yl)hexyl]-2-phenyl-1H-benzimidazole |
title | 1-[6-(9H-Carbazol-9-yl)hexyl]-2-phenyl-1H-benzimidazole |
title_full | 1-[6-(9H-Carbazol-9-yl)hexyl]-2-phenyl-1H-benzimidazole |
title_fullStr | 1-[6-(9H-Carbazol-9-yl)hexyl]-2-phenyl-1H-benzimidazole |
title_full_unstemmed | 1-[6-(9H-Carbazol-9-yl)hexyl]-2-phenyl-1H-benzimidazole |
title_short | 1-[6-(9H-Carbazol-9-yl)hexyl]-2-phenyl-1H-benzimidazole |
title_sort | 1-[6-(9h-carbazol-9-yl)hexyl]-2-phenyl-1h-benzimidazole |
topic | Organic Papers |
url | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2971855/ https://www.ncbi.nlm.nih.gov/pubmed/21578806 http://dx.doi.org/10.1107/S1600536809046820 |
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