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[N,N-Bis(diphenyl­phosphino)propyl­amine-κ(2) P,P]bromidotricarbonyl­rhenium(I)

In the title compound, [ReBr(C(27)H(27)NP(2))(CO)(3)], the Re(I) atom is octa­hedrally surrounded by three carbonyl ligands in a facial arrangement, a bromide ligand and the P,P′-bidentate ligand Bis(diphenyl­phosphino)propyl­amine. The compound exhibits substitutional disorder of the bromide ligand...

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Detalles Bibliográficos
Autores principales: Schutte, Marietjie, Visser, Hendrik G., Brink, Alice
Formato: Texto
Lenguaje:English
Publicado: International Union of Crystallography 2009
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2971857/
https://www.ncbi.nlm.nih.gov/pubmed/21578608
http://dx.doi.org/10.1107/S1600536809047242
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author Schutte, Marietjie
Visser, Hendrik G.
Brink, Alice
author_facet Schutte, Marietjie
Visser, Hendrik G.
Brink, Alice
author_sort Schutte, Marietjie
collection PubMed
description In the title compound, [ReBr(C(27)H(27)NP(2))(CO)(3)], the Re(I) atom is octa­hedrally surrounded by three carbonyl ligands in a facial arrangement, a bromide ligand and the P,P′-bidentate ligand Bis(diphenyl­phosphino)propyl­amine. The compound exhibits substitutional disorder of the bromide ligand and the axial carbonyl ligand, with almost 50% occupancy for both Br amd CO [0.538 (4) and 0.462 (4), respectively]. In addition, the propyl chain on the N atom of the bidentate ligand exhibits a 0.648 (9):0.352 (9) disorder. C—H⋯O and C—H⋯Br hydrogen bonding consolidates the crystal packing.
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spelling pubmed-29718572010-12-30 [N,N-Bis(diphenyl­phosphino)propyl­amine-κ(2) P,P]bromidotricarbonyl­rhenium(I) Schutte, Marietjie Visser, Hendrik G. Brink, Alice Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers In the title compound, [ReBr(C(27)H(27)NP(2))(CO)(3)], the Re(I) atom is octa­hedrally surrounded by three carbonyl ligands in a facial arrangement, a bromide ligand and the P,P′-bidentate ligand Bis(diphenyl­phosphino)propyl­amine. The compound exhibits substitutional disorder of the bromide ligand and the axial carbonyl ligand, with almost 50% occupancy for both Br amd CO [0.538 (4) and 0.462 (4), respectively]. In addition, the propyl chain on the N atom of the bidentate ligand exhibits a 0.648 (9):0.352 (9) disorder. C—H⋯O and C—H⋯Br hydrogen bonding consolidates the crystal packing. International Union of Crystallography 2009-11-14 /pmc/articles/PMC2971857/ /pubmed/21578608 http://dx.doi.org/10.1107/S1600536809047242 Text en © Schutte et al. 2009 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Metal-Organic Papers
Schutte, Marietjie
Visser, Hendrik G.
Brink, Alice
[N,N-Bis(diphenyl­phosphino)propyl­amine-κ(2) P,P]bromidotricarbonyl­rhenium(I)
title [N,N-Bis(diphenyl­phosphino)propyl­amine-κ(2) P,P]bromidotricarbonyl­rhenium(I)
title_full [N,N-Bis(diphenyl­phosphino)propyl­amine-κ(2) P,P]bromidotricarbonyl­rhenium(I)
title_fullStr [N,N-Bis(diphenyl­phosphino)propyl­amine-κ(2) P,P]bromidotricarbonyl­rhenium(I)
title_full_unstemmed [N,N-Bis(diphenyl­phosphino)propyl­amine-κ(2) P,P]bromidotricarbonyl­rhenium(I)
title_short [N,N-Bis(diphenyl­phosphino)propyl­amine-κ(2) P,P]bromidotricarbonyl­rhenium(I)
title_sort [n,n-bis(diphenyl­phosphino)propyl­amine-κ(2) p,p]bromidotricarbonyl­rhenium(i)
topic Metal-Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2971857/
https://www.ncbi.nlm.nih.gov/pubmed/21578608
http://dx.doi.org/10.1107/S1600536809047242
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