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[N,N-Bis(diphenylphosphino)propylamine-κ(2) P,P]bromidotricarbonylrhenium(I)
In the title compound, [ReBr(C(27)H(27)NP(2))(CO)(3)], the Re(I) atom is octahedrally surrounded by three carbonyl ligands in a facial arrangement, a bromide ligand and the P,P′-bidentate ligand Bis(diphenylphosphino)propylamine. The compound exhibits substitutional disorder of the bromide ligand...
Autores principales: | , , |
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Formato: | Texto |
Lenguaje: | English |
Publicado: |
International Union of Crystallography
2009
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Materias: | |
Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2971857/ https://www.ncbi.nlm.nih.gov/pubmed/21578608 http://dx.doi.org/10.1107/S1600536809047242 |
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author | Schutte, Marietjie Visser, Hendrik G. Brink, Alice |
author_facet | Schutte, Marietjie Visser, Hendrik G. Brink, Alice |
author_sort | Schutte, Marietjie |
collection | PubMed |
description | In the title compound, [ReBr(C(27)H(27)NP(2))(CO)(3)], the Re(I) atom is octahedrally surrounded by three carbonyl ligands in a facial arrangement, a bromide ligand and the P,P′-bidentate ligand Bis(diphenylphosphino)propylamine. The compound exhibits substitutional disorder of the bromide ligand and the axial carbonyl ligand, with almost 50% occupancy for both Br amd CO [0.538 (4) and 0.462 (4), respectively]. In addition, the propyl chain on the N atom of the bidentate ligand exhibits a 0.648 (9):0.352 (9) disorder. C—H⋯O and C—H⋯Br hydrogen bonding consolidates the crystal packing. |
format | Text |
id | pubmed-2971857 |
institution | National Center for Biotechnology Information |
language | English |
publishDate | 2009 |
publisher | International Union of Crystallography |
record_format | MEDLINE/PubMed |
spelling | pubmed-29718572010-12-30 [N,N-Bis(diphenylphosphino)propylamine-κ(2) P,P]bromidotricarbonylrhenium(I) Schutte, Marietjie Visser, Hendrik G. Brink, Alice Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers In the title compound, [ReBr(C(27)H(27)NP(2))(CO)(3)], the Re(I) atom is octahedrally surrounded by three carbonyl ligands in a facial arrangement, a bromide ligand and the P,P′-bidentate ligand Bis(diphenylphosphino)propylamine. The compound exhibits substitutional disorder of the bromide ligand and the axial carbonyl ligand, with almost 50% occupancy for both Br amd CO [0.538 (4) and 0.462 (4), respectively]. In addition, the propyl chain on the N atom of the bidentate ligand exhibits a 0.648 (9):0.352 (9) disorder. C—H⋯O and C—H⋯Br hydrogen bonding consolidates the crystal packing. International Union of Crystallography 2009-11-14 /pmc/articles/PMC2971857/ /pubmed/21578608 http://dx.doi.org/10.1107/S1600536809047242 Text en © Schutte et al. 2009 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited. |
spellingShingle | Metal-Organic Papers Schutte, Marietjie Visser, Hendrik G. Brink, Alice [N,N-Bis(diphenylphosphino)propylamine-κ(2) P,P]bromidotricarbonylrhenium(I) |
title | [N,N-Bis(diphenylphosphino)propylamine-κ(2)
P,P]bromidotricarbonylrhenium(I) |
title_full | [N,N-Bis(diphenylphosphino)propylamine-κ(2)
P,P]bromidotricarbonylrhenium(I) |
title_fullStr | [N,N-Bis(diphenylphosphino)propylamine-κ(2)
P,P]bromidotricarbonylrhenium(I) |
title_full_unstemmed | [N,N-Bis(diphenylphosphino)propylamine-κ(2)
P,P]bromidotricarbonylrhenium(I) |
title_short | [N,N-Bis(diphenylphosphino)propylamine-κ(2)
P,P]bromidotricarbonylrhenium(I) |
title_sort | [n,n-bis(diphenylphosphino)propylamine-κ(2)
p,p]bromidotricarbonylrhenium(i) |
topic | Metal-Organic Papers |
url | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2971857/ https://www.ncbi.nlm.nih.gov/pubmed/21578608 http://dx.doi.org/10.1107/S1600536809047242 |
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