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Bis(1-ferrocenylmethylidene-4-phenylthiosemicarbazidato-κ(2) N (1),S)zinc(II) monohydrate
In the title compound, [Fe(2)Zn(C(5)H(5))(2)(C(13)H(11)N(3)S)(2)]·H(2)O, the Zn(II) ion is in a distorted tetrahedral geometry being coordinated by two thiosemicarbazone ligands via N and S atoms. One of the Cp rings is disordered over two positions with occupancies of 0.55 and 0.45. The dihedral...
| Autores principales: | , , , |
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| Formato: | Texto |
| Lenguaje: | English |
| Publicado: |
International Union of Crystallography
2009
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| Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2971859/ https://www.ncbi.nlm.nih.gov/pubmed/21578570 http://dx.doi.org/10.1107/S1600536809046078 |
| _version_ | 1782190686486921216 |
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| author | Vikneswaran, M. R. Teoh, Siang Guan Yeap, Chin Sing Fun, Hoong-Kun |
| author_facet | Vikneswaran, M. R. Teoh, Siang Guan Yeap, Chin Sing Fun, Hoong-Kun |
| author_sort | Vikneswaran, M. R. |
| collection | PubMed |
| description | In the title compound, [Fe(2)Zn(C(5)H(5))(2)(C(13)H(11)N(3)S)(2)]·H(2)O, the Zn(II) ion is in a distorted tetrahedral geometry being coordinated by two thiosemicarbazone ligands via N and S atoms. One of the Cp rings is disordered over two positions with occupancies of 0.55 and 0.45. The dihedral angle between the substituted Cp rings is 56.1 (5)° and the two phenyl rings are orientated at a dihedral angle of 41.7 (4)°. In the crystal structure, intermolecular O—H⋯S, N—H⋯O and C—H⋯N hydrogen bonds link the molecules into chains along the b axis. The structure is further consolidated by O—H⋯π interactions. |
| format | Text |
| id | pubmed-2971859 |
| institution | National Center for Biotechnology Information |
| language | English |
| publishDate | 2009 |
| publisher | International Union of Crystallography |
| record_format | MEDLINE/PubMed |
| spelling | pubmed-29718592010-12-30 Bis(1-ferrocenylmethylidene-4-phenylthiosemicarbazidato-κ(2) N (1),S)zinc(II) monohydrate Vikneswaran, M. R. Teoh, Siang Guan Yeap, Chin Sing Fun, Hoong-Kun Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers In the title compound, [Fe(2)Zn(C(5)H(5))(2)(C(13)H(11)N(3)S)(2)]·H(2)O, the Zn(II) ion is in a distorted tetrahedral geometry being coordinated by two thiosemicarbazone ligands via N and S atoms. One of the Cp rings is disordered over two positions with occupancies of 0.55 and 0.45. The dihedral angle between the substituted Cp rings is 56.1 (5)° and the two phenyl rings are orientated at a dihedral angle of 41.7 (4)°. In the crystal structure, intermolecular O—H⋯S, N—H⋯O and C—H⋯N hydrogen bonds link the molecules into chains along the b axis. The structure is further consolidated by O—H⋯π interactions. International Union of Crystallography 2009-11-07 /pmc/articles/PMC2971859/ /pubmed/21578570 http://dx.doi.org/10.1107/S1600536809046078 Text en © Vikneswaran et al. 2009 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited. |
| spellingShingle | Metal-Organic Papers Vikneswaran, M. R. Teoh, Siang Guan Yeap, Chin Sing Fun, Hoong-Kun Bis(1-ferrocenylmethylidene-4-phenylthiosemicarbazidato-κ(2) N (1),S)zinc(II) monohydrate |
| title | Bis(1-ferrocenylmethylidene-4-phenylthiosemicarbazidato-κ(2)
N
(1),S)zinc(II) monohydrate |
| title_full | Bis(1-ferrocenylmethylidene-4-phenylthiosemicarbazidato-κ(2)
N
(1),S)zinc(II) monohydrate |
| title_fullStr | Bis(1-ferrocenylmethylidene-4-phenylthiosemicarbazidato-κ(2)
N
(1),S)zinc(II) monohydrate |
| title_full_unstemmed | Bis(1-ferrocenylmethylidene-4-phenylthiosemicarbazidato-κ(2)
N
(1),S)zinc(II) monohydrate |
| title_short | Bis(1-ferrocenylmethylidene-4-phenylthiosemicarbazidato-κ(2)
N
(1),S)zinc(II) monohydrate |
| title_sort | bis(1-ferrocenylmethylidene-4-phenylthiosemicarbazidato-κ(2)
n
(1),s)zinc(ii) monohydrate |
| topic | Metal-Organic Papers |
| url | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2971859/ https://www.ncbi.nlm.nih.gov/pubmed/21578570 http://dx.doi.org/10.1107/S1600536809046078 |
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