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Bis(2-ethoxycarbonylethyl-κ(2) C (1),O)(2-thioxo-1,3-dithiole-4,5-dithiolato-κ(2) S (4),S (5))tin(IV)
In the title compound, [Sn(C(5)H(9)O(2))(2)(C(3)S(5))], the immediate environment around the Sn centre is defined by two S and two C atoms that define an approximately tetrahedral geometry. The close approach of the pendant carbonyl O atoms [Sn—O = 2.577 (3) and 2.573 (3) Å] increases the coordinat...
| Autores principales: | , , , |
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| Formato: | Texto |
| Lenguaje: | English |
| Publicado: |
International Union of Crystallography
2009
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| Materias: | |
| Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2971863/ https://www.ncbi.nlm.nih.gov/pubmed/21578652 http://dx.doi.org/10.1107/S1600536809048971 |
| _version_ | 1782190687410716672 |
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| author | de Lima, Geraldo M. Wardell, Solange M. S. V. Wardell, James L. Tiekink, Edward R. T. |
| author_facet | de Lima, Geraldo M. Wardell, Solange M. S. V. Wardell, James L. Tiekink, Edward R. T. |
| author_sort | de Lima, Geraldo M. |
| collection | PubMed |
| description | In the title compound, [Sn(C(5)H(9)O(2))(2)(C(3)S(5))], the immediate environment around the Sn centre is defined by two S and two C atoms that define an approximately tetrahedral geometry. The close approach of the pendant carbonyl O atoms [Sn—O = 2.577 (3) and 2.573 (3) Å] increases the coordination number to six. Supramolecular chains are formed along the a axis in the crystal structure owing to the presence of C—H⋯O contacts. |
| format | Text |
| id | pubmed-2971863 |
| institution | National Center for Biotechnology Information |
| language | English |
| publishDate | 2009 |
| publisher | International Union of Crystallography |
| record_format | MEDLINE/PubMed |
| spelling | pubmed-29718632010-12-30 Bis(2-ethoxycarbonylethyl-κ(2) C (1),O)(2-thioxo-1,3-dithiole-4,5-dithiolato-κ(2) S (4),S (5))tin(IV) de Lima, Geraldo M. Wardell, Solange M. S. V. Wardell, James L. Tiekink, Edward R. T. Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers In the title compound, [Sn(C(5)H(9)O(2))(2)(C(3)S(5))], the immediate environment around the Sn centre is defined by two S and two C atoms that define an approximately tetrahedral geometry. The close approach of the pendant carbonyl O atoms [Sn—O = 2.577 (3) and 2.573 (3) Å] increases the coordination number to six. Supramolecular chains are formed along the a axis in the crystal structure owing to the presence of C—H⋯O contacts. International Union of Crystallography 2009-11-21 /pmc/articles/PMC2971863/ /pubmed/21578652 http://dx.doi.org/10.1107/S1600536809048971 Text en © Lima et al. 2009 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited. |
| spellingShingle | Metal-Organic Papers de Lima, Geraldo M. Wardell, Solange M. S. V. Wardell, James L. Tiekink, Edward R. T. Bis(2-ethoxycarbonylethyl-κ(2) C (1),O)(2-thioxo-1,3-dithiole-4,5-dithiolato-κ(2) S (4),S (5))tin(IV) |
| title | Bis(2-ethoxycarbonylethyl-κ(2)
C
(1),O)(2-thioxo-1,3-dithiole-4,5-dithiolato-κ(2)
S
(4),S
(5))tin(IV) |
| title_full | Bis(2-ethoxycarbonylethyl-κ(2)
C
(1),O)(2-thioxo-1,3-dithiole-4,5-dithiolato-κ(2)
S
(4),S
(5))tin(IV) |
| title_fullStr | Bis(2-ethoxycarbonylethyl-κ(2)
C
(1),O)(2-thioxo-1,3-dithiole-4,5-dithiolato-κ(2)
S
(4),S
(5))tin(IV) |
| title_full_unstemmed | Bis(2-ethoxycarbonylethyl-κ(2)
C
(1),O)(2-thioxo-1,3-dithiole-4,5-dithiolato-κ(2)
S
(4),S
(5))tin(IV) |
| title_short | Bis(2-ethoxycarbonylethyl-κ(2)
C
(1),O)(2-thioxo-1,3-dithiole-4,5-dithiolato-κ(2)
S
(4),S
(5))tin(IV) |
| title_sort | bis(2-ethoxycarbonylethyl-κ(2)
c
(1),o)(2-thioxo-1,3-dithiole-4,5-dithiolato-κ(2)
s
(4),s
(5))tin(iv) |
| topic | Metal-Organic Papers |
| url | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2971863/ https://www.ncbi.nlm.nih.gov/pubmed/21578652 http://dx.doi.org/10.1107/S1600536809048971 |
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