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2-Iodo-3-methoxy-6-methylpyridine
The title compound, C(7)H(8)INO, which crystallizes with three independent molecules in the asymmetric unit, was prepared by the reaction of 3-methoxy-6-methylpyridine with KI and I(2) in tetrahydrofuran solution. In the crystal structure, the three independent molecules are arranged in a simi...
Autores principales: | , , , |
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Formato: | Texto |
Lenguaje: | English |
Publicado: |
International Union of Crystallography
2009
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Materias: | |
Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2971865/ https://www.ncbi.nlm.nih.gov/pubmed/21578963 http://dx.doi.org/10.1107/S1600536809050739 |
Sumario: | The title compound, C(7)H(8)INO, which crystallizes with three independent molecules in the asymmetric unit, was prepared by the reaction of 3-methoxy-6-methylpyridine with KI and I(2) in tetrahydrofuran solution. In the crystal structure, the three independent molecules are arranged in a similar orientation with the three polar methoxy groups aligned on one side and the three non-polar methyl groups on the other side. The three molecules, excluding methyl H atoms, are essentially planar, with r.m.s. deviations of 0.0141 (1), 0.0081 (1) and 0.0066 (2)Å. The three pyridine rings make dihedral angles of 58.09 (3) 66.64 (4) and 71.5 (3)°. The crystal structure features rather weak intermolecular C—H⋯O hydrogen bonds, which link two molecules into dimers, and short I⋯N contacts [4.046 (3) Å]. |
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