Cargando…
(3E,5E)-3,5-Bis(4-allyloxybenzylidene)-1-benzylpiperidin-4-one
In the title compound C(32)H(31)NO(3), the allyloxy groups on either side of the piperidin-4-one ring are conformationally disordered. The contribution of major and minor components of the allyloxy group at the 3rd position of the ring are 0.576 (4) and 0.424 (4), respectively, and those at the 5th...
Autores principales: | , , , , |
---|---|
Formato: | Texto |
Lenguaje: | English |
Publicado: |
International Union of Crystallography
2009
|
Materias: | |
Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2971870/ https://www.ncbi.nlm.nih.gov/pubmed/21578792 http://dx.doi.org/10.1107/S1600536809046716 |
_version_ | 1782190689109409792 |
---|---|
author | Karthikeyan, N. S. Sathiyanarayanan, K. Aravindan, P. G. Ghosh, H. Rathore, R. S. |
author_facet | Karthikeyan, N. S. Sathiyanarayanan, K. Aravindan, P. G. Ghosh, H. Rathore, R. S. |
author_sort | Karthikeyan, N. S. |
collection | PubMed |
description | In the title compound C(32)H(31)NO(3), the allyloxy groups on either side of the piperidin-4-one ring are conformationally disordered. The contribution of major and minor components of the allyloxy group at the 3rd position of the ring are 0.576 (4) and 0.424 (4), respectively, and those at the 5th position are 0.885 (3) and 0.115 (3), respectively. The six-membered piperidin-4-one ring adopts a sofa conformation with the benzyl group occupying an equatorial position and the olefinic double bonds possessing an E configuration. Flanking phenyl substituents are stretched out on either side of the six-membered ring. π–π interactions with a centroid–centroid distance of 3.885 (1) Å give rise to molecular dimers and short C—H⋯π contacts lead to chains along the c axis. |
format | Text |
id | pubmed-2971870 |
institution | National Center for Biotechnology Information |
language | English |
publishDate | 2009 |
publisher | International Union of Crystallography |
record_format | MEDLINE/PubMed |
spelling | pubmed-29718702010-12-30 (3E,5E)-3,5-Bis(4-allyloxybenzylidene)-1-benzylpiperidin-4-one Karthikeyan, N. S. Sathiyanarayanan, K. Aravindan, P. G. Ghosh, H. Rathore, R. S. Acta Crystallogr Sect E Struct Rep Online Organic Papers In the title compound C(32)H(31)NO(3), the allyloxy groups on either side of the piperidin-4-one ring are conformationally disordered. The contribution of major and minor components of the allyloxy group at the 3rd position of the ring are 0.576 (4) and 0.424 (4), respectively, and those at the 5th position are 0.885 (3) and 0.115 (3), respectively. The six-membered piperidin-4-one ring adopts a sofa conformation with the benzyl group occupying an equatorial position and the olefinic double bonds possessing an E configuration. Flanking phenyl substituents are stretched out on either side of the six-membered ring. π–π interactions with a centroid–centroid distance of 3.885 (1) Å give rise to molecular dimers and short C—H⋯π contacts lead to chains along the c axis. International Union of Crystallography 2009-11-11 /pmc/articles/PMC2971870/ /pubmed/21578792 http://dx.doi.org/10.1107/S1600536809046716 Text en © Karthikeyan et al. 2009 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited. |
spellingShingle | Organic Papers Karthikeyan, N. S. Sathiyanarayanan, K. Aravindan, P. G. Ghosh, H. Rathore, R. S. (3E,5E)-3,5-Bis(4-allyloxybenzylidene)-1-benzylpiperidin-4-one |
title | (3E,5E)-3,5-Bis(4-allyloxybenzylidene)-1-benzylpiperidin-4-one |
title_full | (3E,5E)-3,5-Bis(4-allyloxybenzylidene)-1-benzylpiperidin-4-one |
title_fullStr | (3E,5E)-3,5-Bis(4-allyloxybenzylidene)-1-benzylpiperidin-4-one |
title_full_unstemmed | (3E,5E)-3,5-Bis(4-allyloxybenzylidene)-1-benzylpiperidin-4-one |
title_short | (3E,5E)-3,5-Bis(4-allyloxybenzylidene)-1-benzylpiperidin-4-one |
title_sort | (3e,5e)-3,5-bis(4-allyloxybenzylidene)-1-benzylpiperidin-4-one |
topic | Organic Papers |
url | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2971870/ https://www.ncbi.nlm.nih.gov/pubmed/21578792 http://dx.doi.org/10.1107/S1600536809046716 |
work_keys_str_mv | AT karthikeyanns 3e5e35bis4allyloxybenzylidene1benzylpiperidin4one AT sathiyanarayanank 3e5e35bis4allyloxybenzylidene1benzylpiperidin4one AT aravindanpg 3e5e35bis4allyloxybenzylidene1benzylpiperidin4one AT ghoshh 3e5e35bis4allyloxybenzylidene1benzylpiperidin4one AT rathorers 3e5e35bis4allyloxybenzylidene1benzylpiperidin4one |