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(3E,5E)-3,5-Bis(4-allyl­oxybenzyl­idene)-1-benzyl­piperidin-4-one

In the title compound C(32)H(31)NO(3), the all­yloxy groups on either side of the piperidin-4-one ring are conformationally disordered. The contribution of major and minor components of the allyloxy group at the 3rd position of the ring are 0.576 (4) and 0.424 (4), respectively, and those at the 5th...

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Autores principales: Karthikeyan, N. S., Sathiyanarayanan, K., Aravindan, P. G., Ghosh, H., Rathore, R. S.
Formato: Texto
Lenguaje:English
Publicado: International Union of Crystallography 2009
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2971870/
https://www.ncbi.nlm.nih.gov/pubmed/21578792
http://dx.doi.org/10.1107/S1600536809046716
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author Karthikeyan, N. S.
Sathiyanarayanan, K.
Aravindan, P. G.
Ghosh, H.
Rathore, R. S.
author_facet Karthikeyan, N. S.
Sathiyanarayanan, K.
Aravindan, P. G.
Ghosh, H.
Rathore, R. S.
author_sort Karthikeyan, N. S.
collection PubMed
description In the title compound C(32)H(31)NO(3), the all­yloxy groups on either side of the piperidin-4-one ring are conformationally disordered. The contribution of major and minor components of the allyloxy group at the 3rd position of the ring are 0.576 (4) and 0.424 (4), respectively, and those at the 5th position are 0.885 (3) and 0.115 (3), respectively. The six-membered piperidin-4-one ring adopts a sofa conformation with the benzyl group occupying an equatorial position and the olefinic double bonds possessing an E configuration. Flanking phenyl substituents are stretched out on either side of the six-membered ring. π–π inter­actions with a centroid–centroid distance of 3.885 (1) Å give rise to mol­ecular dimers and short C—H⋯π contacts lead to chains along the c axis.
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spelling pubmed-29718702010-12-30 (3E,5E)-3,5-Bis(4-allyl­oxybenzyl­idene)-1-benzyl­piperidin-4-one Karthikeyan, N. S. Sathiyanarayanan, K. Aravindan, P. G. Ghosh, H. Rathore, R. S. Acta Crystallogr Sect E Struct Rep Online Organic Papers In the title compound C(32)H(31)NO(3), the all­yloxy groups on either side of the piperidin-4-one ring are conformationally disordered. The contribution of major and minor components of the allyloxy group at the 3rd position of the ring are 0.576 (4) and 0.424 (4), respectively, and those at the 5th position are 0.885 (3) and 0.115 (3), respectively. The six-membered piperidin-4-one ring adopts a sofa conformation with the benzyl group occupying an equatorial position and the olefinic double bonds possessing an E configuration. Flanking phenyl substituents are stretched out on either side of the six-membered ring. π–π inter­actions with a centroid–centroid distance of 3.885 (1) Å give rise to mol­ecular dimers and short C—H⋯π contacts lead to chains along the c axis. International Union of Crystallography 2009-11-11 /pmc/articles/PMC2971870/ /pubmed/21578792 http://dx.doi.org/10.1107/S1600536809046716 Text en © Karthikeyan et al. 2009 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Organic Papers
Karthikeyan, N. S.
Sathiyanarayanan, K.
Aravindan, P. G.
Ghosh, H.
Rathore, R. S.
(3E,5E)-3,5-Bis(4-allyl­oxybenzyl­idene)-1-benzyl­piperidin-4-one
title (3E,5E)-3,5-Bis(4-allyl­oxybenzyl­idene)-1-benzyl­piperidin-4-one
title_full (3E,5E)-3,5-Bis(4-allyl­oxybenzyl­idene)-1-benzyl­piperidin-4-one
title_fullStr (3E,5E)-3,5-Bis(4-allyl­oxybenzyl­idene)-1-benzyl­piperidin-4-one
title_full_unstemmed (3E,5E)-3,5-Bis(4-allyl­oxybenzyl­idene)-1-benzyl­piperidin-4-one
title_short (3E,5E)-3,5-Bis(4-allyl­oxybenzyl­idene)-1-benzyl­piperidin-4-one
title_sort (3e,5e)-3,5-bis(4-allyl­oxybenzyl­idene)-1-benzyl­piperidin-4-one
topic Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2971870/
https://www.ncbi.nlm.nih.gov/pubmed/21578792
http://dx.doi.org/10.1107/S1600536809046716
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