[N′-(5-Chloro-2-oxidobenzyl­idene-κO)-3-hydr­oxy-2-naphthohydrazidato-κ(2) N′,O (2)]diphenyl­tin(IV)

The Sn(IV) atom in the title compound, [Sn(C(6)H(5))(2)(C(18)H(11)ClN(2)O(3))], is O,N,O′-chelated by the deprotonated Schiff base ligand and further bonded by two phenyl rings in a distorted cis-C(2)SnNO(2) trigonal-bipyramidal geometry [C—Sn—C = 125.7 (2)°]. The two phenyl rings are oriented at a...

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Detalles Bibliográficos
Autores principales: Lee, See Mun, Lo, Kong Mun, Ali, Hapipah Mohd, Ng, Seik Weng
Formato: Texto
Lenguaje:English
Publicado: International Union of Crystallography 2009
Materias:
Metal-Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2971880/
https://www.ncbi.nlm.nih.gov/pubmed/21578694
http://dx.doi.org/10.1107/S1600536809050107
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author Lee, See Mun
Lo, Kong Mun
Ali, Hapipah Mohd
Ng, Seik Weng
author_facet Lee, See Mun
Lo, Kong Mun
Ali, Hapipah Mohd
Ng, Seik Weng
author_sort Lee, See Mun
collection PubMed
description The Sn(IV) atom in the title compound, [Sn(C(6)H(5))(2)(C(18)H(11)ClN(2)O(3))], is O,N,O′-chelated by the deprotonated Schiff base ligand and further bonded by two phenyl rings in a distorted cis-C(2)SnNO(2) trigonal-bipyramidal geometry [C—Sn—C = 125.7 (2)°]. The two phenyl rings are oriented at a dihedral angle of 55.2 (3)°. Intra­molecular O—H⋯N hydrogen bonding is present in the crystal structure.
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spelling pubmed-29718802010-12-30 [N′-(5-Chloro-2-oxidobenzyl­idene-κO)-3-hydr­oxy-2-naphthohydrazidato-κ(2) N′,O (2)]diphenyl­tin(IV) Lee, See Mun Lo, Kong Mun Ali, Hapipah Mohd Ng, Seik Weng Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers The Sn(IV) atom in the title compound, [Sn(C(6)H(5))(2)(C(18)H(11)ClN(2)O(3))], is O,N,O′-chelated by the deprotonated Schiff base ligand and further bonded by two phenyl rings in a distorted cis-C(2)SnNO(2) trigonal-bipyramidal geometry [C—Sn—C = 125.7 (2)°]. The two phenyl rings are oriented at a dihedral angle of 55.2 (3)°. Intra­molecular O—H⋯N hydrogen bonding is present in the crystal structure. International Union of Crystallography 2009-11-28 /pmc/articles/PMC2971880/ /pubmed/21578694 http://dx.doi.org/10.1107/S1600536809050107 Text en © Lee et al. 2009 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Metal-Organic Papers
Lee, See Mun
Lo, Kong Mun
Ali, Hapipah Mohd
Ng, Seik Weng
[N′-(5-Chloro-2-oxidobenzyl­idene-κO)-3-hydr­oxy-2-naphthohydrazidato-κ(2) N′,O (2)]diphenyl­tin(IV)
title [N′-(5-Chloro-2-oxidobenzyl­idene-κO)-3-hydr­oxy-2-naphthohydrazidato-κ(2) N′,O (2)]diphenyl­tin(IV)
title_full [N′-(5-Chloro-2-oxidobenzyl­idene-κO)-3-hydr­oxy-2-naphthohydrazidato-κ(2) N′,O (2)]diphenyl­tin(IV)
title_fullStr [N′-(5-Chloro-2-oxidobenzyl­idene-κO)-3-hydr­oxy-2-naphthohydrazidato-κ(2) N′,O (2)]diphenyl­tin(IV)
title_full_unstemmed [N′-(5-Chloro-2-oxidobenzyl­idene-κO)-3-hydr­oxy-2-naphthohydrazidato-κ(2) N′,O (2)]diphenyl­tin(IV)
title_short [N′-(5-Chloro-2-oxidobenzyl­idene-κO)-3-hydr­oxy-2-naphthohydrazidato-κ(2) N′,O (2)]diphenyl­tin(IV)
title_sort [n′-(5-chloro-2-oxidobenzyl­idene-κo)-3-hydr­oxy-2-naphthohydrazidato-κ(2) n′,o (2)]diphenyl­tin(iv)
topic Metal-Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2971880/
https://www.ncbi.nlm.nih.gov/pubmed/21578694
http://dx.doi.org/10.1107/S1600536809050107
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