Bis(2-amino­thia­zole-4-acetato)aquazinc(II)

In the title compound, [Zn(C(5)H(5)N(2)O(2)S)(2)(H(2)O)], the central Zn atom (2 site symmetry) is five-coordinated by two N and three O atoms [Zn—N = 2.047 (3) Å, Zn—O = 2.099 (2) and 1.974 (4) Å] in a distorted square-pyramidal geometry. Besides one O atom from a water mol­ecule, two 2-amino­thia­...

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Detalles Bibliográficos
Autores principales: Zhang, Lai-Jun, Shen, Xing-Can, Yang, Yan, Liang, Hong
Formato: Texto
Lenguaje:English
Publicado: International Union of Crystallography 2009
Materias:
Metal-Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2971890/
https://www.ncbi.nlm.nih.gov/pubmed/21578564
http://dx.doi.org/10.1107/S1600536809045589
Descripción
Sumario:In the title compound, [Zn(C(5)H(5)N(2)O(2)S)(2)(H(2)O)], the central Zn atom (2 site symmetry) is five-coordinated by two N and three O atoms [Zn—N = 2.047 (3) Å, Zn—O = 2.099 (2) and 1.974 (4) Å] in a distorted square-pyramidal geometry. Besides one O atom from a water mol­ecule, two 2-amino­thia­zole-4-acetate ligands provide two N and two O atoms as coordinated atoms. In the crystal structure, inter­molecular O—H⋯O and N—H⋯O hydrogen bonds connect the mol­ecules into an infinite three-dimensional framework.

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