Bis(2-amino­thia­zole-4-acetato)aquazinc(II)

In the title compound, [Zn(C(5)H(5)N(2)O(2)S)(2)(H(2)O)], the central Zn atom (2 site symmetry) is five-coordinated by two N and three O atoms [Zn—N = 2.047 (3) Å, Zn—O = 2.099 (2) and 1.974 (4) Å] in a distorted square-pyramidal geometry. Besides one O atom from a water mol­ecule, two 2-amino­thia­...

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Detalles Bibliográficos
Autores principales: Zhang, Lai-Jun, Shen, Xing-Can, Yang, Yan, Liang, Hong
Formato: Texto
Lenguaje:English
Publicado: International Union of Crystallography 2009
Materias:
Metal-Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2971890/
https://www.ncbi.nlm.nih.gov/pubmed/21578564
http://dx.doi.org/10.1107/S1600536809045589
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author Zhang, Lai-Jun
Shen, Xing-Can
Yang, Yan
Liang, Hong
author_facet Zhang, Lai-Jun
Shen, Xing-Can
Yang, Yan
Liang, Hong
author_sort Zhang, Lai-Jun
collection PubMed
description In the title compound, [Zn(C(5)H(5)N(2)O(2)S)(2)(H(2)O)], the central Zn atom (2 site symmetry) is five-coordinated by two N and three O atoms [Zn—N = 2.047 (3) Å, Zn—O = 2.099 (2) and 1.974 (4) Å] in a distorted square-pyramidal geometry. Besides one O atom from a water mol­ecule, two 2-amino­thia­zole-4-acetate ligands provide two N and two O atoms as coordinated atoms. In the crystal structure, inter­molecular O—H⋯O and N—H⋯O hydrogen bonds connect the mol­ecules into an infinite three-dimensional framework.
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spelling pubmed-29718902010-12-30 Bis(2-amino­thia­zole-4-acetato)aquazinc(II) Zhang, Lai-Jun Shen, Xing-Can Yang, Yan Liang, Hong Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers In the title compound, [Zn(C(5)H(5)N(2)O(2)S)(2)(H(2)O)], the central Zn atom (2 site symmetry) is five-coordinated by two N and three O atoms [Zn—N = 2.047 (3) Å, Zn—O = 2.099 (2) and 1.974 (4) Å] in a distorted square-pyramidal geometry. Besides one O atom from a water mol­ecule, two 2-amino­thia­zole-4-acetate ligands provide two N and two O atoms as coordinated atoms. In the crystal structure, inter­molecular O—H⋯O and N—H⋯O hydrogen bonds connect the mol­ecules into an infinite three-dimensional framework. International Union of Crystallography 2009-11-04 /pmc/articles/PMC2971890/ /pubmed/21578564 http://dx.doi.org/10.1107/S1600536809045589 Text en © Zhang et al. 2009 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Metal-Organic Papers
Zhang, Lai-Jun
Shen, Xing-Can
Yang, Yan
Liang, Hong
Bis(2-amino­thia­zole-4-acetato)aquazinc(II)
title Bis(2-amino­thia­zole-4-acetato)aquazinc(II)
title_full Bis(2-amino­thia­zole-4-acetato)aquazinc(II)
title_fullStr Bis(2-amino­thia­zole-4-acetato)aquazinc(II)
title_full_unstemmed Bis(2-amino­thia­zole-4-acetato)aquazinc(II)
title_short Bis(2-amino­thia­zole-4-acetato)aquazinc(II)
title_sort bis(2-amino­thia­zole-4-acetato)aquazinc(ii)
topic Metal-Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2971890/
https://www.ncbi.nlm.nih.gov/pubmed/21578564
http://dx.doi.org/10.1107/S1600536809045589
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AT shenxingcan bis2aminothiazole4acetatoaquazincii
AT yangyan bis2aminothiazole4acetatoaquazincii
AT lianghong bis2aminothiazole4acetatoaquazincii

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