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Tetra­kis(μ(2)-phenyl­acetato-κ(2) O:O′)bis­[(isoquinoline-κN)copper(II)]

In the title centrosymmetric binuclear Cu(II) complex, [Cu(2)(C(8)H(7)O(2))(4)(C(9)H(7)N)(2)], the two Cu cations are bridged by four carboxyl­ate groups of the phenyl­acetate anions; each Cu cation is further coordinated by an isoquinoline ligand to complete the distorted CuO(4)N square-pyramidal g...

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Detalles Bibliográficos
Autores principales: Li, Meng-Jiao, Nie, Jing-Jing, Xu, Duan-Jun
Formato: Texto
Lenguaje:English
Publicado: International Union of Crystallography 2009
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2971894/
https://www.ncbi.nlm.nih.gov/pubmed/21578637
http://dx.doi.org/10.1107/S1600536809048697
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author Li, Meng-Jiao
Nie, Jing-Jing
Xu, Duan-Jun
author_facet Li, Meng-Jiao
Nie, Jing-Jing
Xu, Duan-Jun
author_sort Li, Meng-Jiao
collection PubMed
description In the title centrosymmetric binuclear Cu(II) complex, [Cu(2)(C(8)H(7)O(2))(4)(C(9)H(7)N)(2)], the two Cu cations are bridged by four carboxyl­ate groups of the phenyl­acetate anions; each Cu cation is further coordinated by an isoquinoline ligand to complete the distorted CuO(4)N square-pyramidal geometry. The Cu cation is displaced by 0.2092 (8) Å from the basal plane formed by the four O atoms. Within the dinuclear mol­ecule, the Cu⋯Cu separation is 2.6453 (6) Å. Although a parallel, overlapped arrangement of isoquinoline ligands exists in the crystal structure; the longer face-to-face distance of 3.667 (5) Å suggests there is no π–π stacking between isoquinoline ring systems.
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spelling pubmed-29718942010-12-30 Tetra­kis(μ(2)-phenyl­acetato-κ(2) O:O′)bis­[(isoquinoline-κN)copper(II)] Li, Meng-Jiao Nie, Jing-Jing Xu, Duan-Jun Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers In the title centrosymmetric binuclear Cu(II) complex, [Cu(2)(C(8)H(7)O(2))(4)(C(9)H(7)N)(2)], the two Cu cations are bridged by four carboxyl­ate groups of the phenyl­acetate anions; each Cu cation is further coordinated by an isoquinoline ligand to complete the distorted CuO(4)N square-pyramidal geometry. The Cu cation is displaced by 0.2092 (8) Å from the basal plane formed by the four O atoms. Within the dinuclear mol­ecule, the Cu⋯Cu separation is 2.6453 (6) Å. Although a parallel, overlapped arrangement of isoquinoline ligands exists in the crystal structure; the longer face-to-face distance of 3.667 (5) Å suggests there is no π–π stacking between isoquinoline ring systems. International Union of Crystallography 2009-11-21 /pmc/articles/PMC2971894/ /pubmed/21578637 http://dx.doi.org/10.1107/S1600536809048697 Text en © Li et al. 2009 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Metal-Organic Papers
Li, Meng-Jiao
Nie, Jing-Jing
Xu, Duan-Jun
Tetra­kis(μ(2)-phenyl­acetato-κ(2) O:O′)bis­[(isoquinoline-κN)copper(II)]
title Tetra­kis(μ(2)-phenyl­acetato-κ(2) O:O′)bis­[(isoquinoline-κN)copper(II)]
title_full Tetra­kis(μ(2)-phenyl­acetato-κ(2) O:O′)bis­[(isoquinoline-κN)copper(II)]
title_fullStr Tetra­kis(μ(2)-phenyl­acetato-κ(2) O:O′)bis­[(isoquinoline-κN)copper(II)]
title_full_unstemmed Tetra­kis(μ(2)-phenyl­acetato-κ(2) O:O′)bis­[(isoquinoline-κN)copper(II)]
title_short Tetra­kis(μ(2)-phenyl­acetato-κ(2) O:O′)bis­[(isoquinoline-κN)copper(II)]
title_sort tetra­kis(μ(2)-phenyl­acetato-κ(2) o:o′)bis­[(isoquinoline-κn)copper(ii)]
topic Metal-Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2971894/
https://www.ncbi.nlm.nih.gov/pubmed/21578637
http://dx.doi.org/10.1107/S1600536809048697
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