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Tetrakis(μ(2)-phenylacetato-κ(2) O:O′)bis[(isoquinoline-κN)copper(II)]
In the title centrosymmetric binuclear Cu(II) complex, [Cu(2)(C(8)H(7)O(2))(4)(C(9)H(7)N)(2)], the two Cu cations are bridged by four carboxylate groups of the phenylacetate anions; each Cu cation is further coordinated by an isoquinoline ligand to complete the distorted CuO(4)N square-pyramidal g...
Autores principales: | , , |
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Formato: | Texto |
Lenguaje: | English |
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International Union of Crystallography
2009
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Materias: | |
Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2971894/ https://www.ncbi.nlm.nih.gov/pubmed/21578637 http://dx.doi.org/10.1107/S1600536809048697 |
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author | Li, Meng-Jiao Nie, Jing-Jing Xu, Duan-Jun |
author_facet | Li, Meng-Jiao Nie, Jing-Jing Xu, Duan-Jun |
author_sort | Li, Meng-Jiao |
collection | PubMed |
description | In the title centrosymmetric binuclear Cu(II) complex, [Cu(2)(C(8)H(7)O(2))(4)(C(9)H(7)N)(2)], the two Cu cations are bridged by four carboxylate groups of the phenylacetate anions; each Cu cation is further coordinated by an isoquinoline ligand to complete the distorted CuO(4)N square-pyramidal geometry. The Cu cation is displaced by 0.2092 (8) Å from the basal plane formed by the four O atoms. Within the dinuclear molecule, the Cu⋯Cu separation is 2.6453 (6) Å. Although a parallel, overlapped arrangement of isoquinoline ligands exists in the crystal structure; the longer face-to-face distance of 3.667 (5) Å suggests there is no π–π stacking between isoquinoline ring systems. |
format | Text |
id | pubmed-2971894 |
institution | National Center for Biotechnology Information |
language | English |
publishDate | 2009 |
publisher | International Union of Crystallography |
record_format | MEDLINE/PubMed |
spelling | pubmed-29718942010-12-30 Tetrakis(μ(2)-phenylacetato-κ(2) O:O′)bis[(isoquinoline-κN)copper(II)] Li, Meng-Jiao Nie, Jing-Jing Xu, Duan-Jun Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers In the title centrosymmetric binuclear Cu(II) complex, [Cu(2)(C(8)H(7)O(2))(4)(C(9)H(7)N)(2)], the two Cu cations are bridged by four carboxylate groups of the phenylacetate anions; each Cu cation is further coordinated by an isoquinoline ligand to complete the distorted CuO(4)N square-pyramidal geometry. The Cu cation is displaced by 0.2092 (8) Å from the basal plane formed by the four O atoms. Within the dinuclear molecule, the Cu⋯Cu separation is 2.6453 (6) Å. Although a parallel, overlapped arrangement of isoquinoline ligands exists in the crystal structure; the longer face-to-face distance of 3.667 (5) Å suggests there is no π–π stacking between isoquinoline ring systems. International Union of Crystallography 2009-11-21 /pmc/articles/PMC2971894/ /pubmed/21578637 http://dx.doi.org/10.1107/S1600536809048697 Text en © Li et al. 2009 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited. |
spellingShingle | Metal-Organic Papers Li, Meng-Jiao Nie, Jing-Jing Xu, Duan-Jun Tetrakis(μ(2)-phenylacetato-κ(2) O:O′)bis[(isoquinoline-κN)copper(II)] |
title | Tetrakis(μ(2)-phenylacetato-κ(2)
O:O′)bis[(isoquinoline-κN)copper(II)] |
title_full | Tetrakis(μ(2)-phenylacetato-κ(2)
O:O′)bis[(isoquinoline-κN)copper(II)] |
title_fullStr | Tetrakis(μ(2)-phenylacetato-κ(2)
O:O′)bis[(isoquinoline-κN)copper(II)] |
title_full_unstemmed | Tetrakis(μ(2)-phenylacetato-κ(2)
O:O′)bis[(isoquinoline-κN)copper(II)] |
title_short | Tetrakis(μ(2)-phenylacetato-κ(2)
O:O′)bis[(isoquinoline-κN)copper(II)] |
title_sort | tetrakis(μ(2)-phenylacetato-κ(2)
o:o′)bis[(isoquinoline-κn)copper(ii)] |
topic | Metal-Organic Papers |
url | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2971894/ https://www.ncbi.nlm.nih.gov/pubmed/21578637 http://dx.doi.org/10.1107/S1600536809048697 |
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