Bis(2-amino­pyrazine-κN (1))tetra­aqua­cadmium(II) bis­(perchlorate)–2-amino­pyrazine (1/4)

In the title compound, [Cd(C(4)H(5)N(3))(2)(H(2)O)(4)](ClO(4))(2)·4C(4)H(5)N(3), the Cd(II) atom (site symmetry [Image: see text]) is coordinated by two N-heterocycles and four water mol­ecules, resulting in a distorted trans-CdN(2)O(4) octa­hedral geometry for the metal. In the crystal, the cation,...

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Detalles Bibliográficos
Autores principales: Cheng, Xiao-Li, Gao, Shan, Ng, Seik Weng
Formato: Texto
Lenguaje:English
Publicado: International Union of Crystallography 2009
Materias:
Metal-Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2971899/
https://www.ncbi.nlm.nih.gov/pubmed/21578651
http://dx.doi.org/10.1107/S1600536809048387
Descripción
Sumario:In the title compound, [Cd(C(4)H(5)N(3))(2)(H(2)O)(4)](ClO(4))(2)·4C(4)H(5)N(3), the Cd(II) atom (site symmetry [Image: see text]) is coordinated by two N-heterocycles and four water mol­ecules, resulting in a distorted trans-CdN(2)O(4) octa­hedral geometry for the metal. In the crystal, the cation, anion and free N-heterocycle mol­ecules are linked by N—H⋯N, N—H⋯O, O—H⋯N and O—H⋯O hydrogen bonds, forming a three-dimensional network.

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