Bis(2-amino­pyrazine-κN (1))tetra­aqua­cadmium(II) bis­(perchlorate)–2-amino­pyrazine (1/4)

In the title compound, [Cd(C(4)H(5)N(3))(2)(H(2)O)(4)](ClO(4))(2)·4C(4)H(5)N(3), the Cd(II) atom (site symmetry [Image: see text]) is coordinated by two N-heterocycles and four water mol­ecules, resulting in a distorted trans-CdN(2)O(4) octa­hedral geometry for the metal. In the crystal, the cation,...

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Detalles Bibliográficos
Autores principales: Cheng, Xiao-Li, Gao, Shan, Ng, Seik Weng
Formato: Texto
Lenguaje:English
Publicado: International Union of Crystallography 2009
Materias:
Metal-Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2971899/
https://www.ncbi.nlm.nih.gov/pubmed/21578651
http://dx.doi.org/10.1107/S1600536809048387
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author Cheng, Xiao-Li
Gao, Shan
Ng, Seik Weng
author_facet Cheng, Xiao-Li
Gao, Shan
Ng, Seik Weng
author_sort Cheng, Xiao-Li
collection PubMed
description In the title compound, [Cd(C(4)H(5)N(3))(2)(H(2)O)(4)](ClO(4))(2)·4C(4)H(5)N(3), the Cd(II) atom (site symmetry [Image: see text]) is coordinated by two N-heterocycles and four water mol­ecules, resulting in a distorted trans-CdN(2)O(4) octa­hedral geometry for the metal. In the crystal, the cation, anion and free N-heterocycle mol­ecules are linked by N—H⋯N, N—H⋯O, O—H⋯N and O—H⋯O hydrogen bonds, forming a three-dimensional network.
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spelling pubmed-29718992010-12-30 Bis(2-amino­pyrazine-κN (1))tetra­aqua­cadmium(II) bis­(perchlorate)–2-amino­pyrazine (1/4) Cheng, Xiao-Li Gao, Shan Ng, Seik Weng Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers In the title compound, [Cd(C(4)H(5)N(3))(2)(H(2)O)(4)](ClO(4))(2)·4C(4)H(5)N(3), the Cd(II) atom (site symmetry [Image: see text]) is coordinated by two N-heterocycles and four water mol­ecules, resulting in a distorted trans-CdN(2)O(4) octa­hedral geometry for the metal. In the crystal, the cation, anion and free N-heterocycle mol­ecules are linked by N—H⋯N, N—H⋯O, O—H⋯N and O—H⋯O hydrogen bonds, forming a three-dimensional network. International Union of Crystallography 2009-11-21 /pmc/articles/PMC2971899/ /pubmed/21578651 http://dx.doi.org/10.1107/S1600536809048387 Text en © Cheng et al. 2009 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Metal-Organic Papers
Cheng, Xiao-Li
Gao, Shan
Ng, Seik Weng
Bis(2-amino­pyrazine-κN (1))tetra­aqua­cadmium(II) bis­(perchlorate)–2-amino­pyrazine (1/4)
title Bis(2-amino­pyrazine-κN (1))tetra­aqua­cadmium(II) bis­(perchlorate)–2-amino­pyrazine (1/4)
title_full Bis(2-amino­pyrazine-κN (1))tetra­aqua­cadmium(II) bis­(perchlorate)–2-amino­pyrazine (1/4)
title_fullStr Bis(2-amino­pyrazine-κN (1))tetra­aqua­cadmium(II) bis­(perchlorate)–2-amino­pyrazine (1/4)
title_full_unstemmed Bis(2-amino­pyrazine-κN (1))tetra­aqua­cadmium(II) bis­(perchlorate)–2-amino­pyrazine (1/4)
title_short Bis(2-amino­pyrazine-κN (1))tetra­aqua­cadmium(II) bis­(perchlorate)–2-amino­pyrazine (1/4)
title_sort bis(2-amino­pyrazine-κn (1))tetra­aqua­cadmium(ii) bis­(perchlorate)–2-amino­pyrazine (1/4)
topic Metal-Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2971899/
https://www.ncbi.nlm.nih.gov/pubmed/21578651
http://dx.doi.org/10.1107/S1600536809048387
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