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Poly[[μ(2)-acetato-aquadi-μ(3)-isonicotinato-erbium(III)silver(I)] perchlorate]
In the title three-dimensional heterometallic complex, {[AgEr(C(6)H(4)NO(2))(2)(C(2)H(3)O(2))(H(2)O)]ClO(4)}(n), the eight-coordinate Er(III) ion adopts a distorted bicapped trigonal-prismatic geometry, being coordinated by four O atoms from four different isonicotinate ligands, three O atoms from...
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Formato: | Texto |
Lenguaje: | English |
Publicado: |
International Union of Crystallography
2009
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Materias: | |
Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2971902/ https://www.ncbi.nlm.nih.gov/pubmed/21578641 http://dx.doi.org/10.1107/S1600536809048429 |
Sumario: | In the title three-dimensional heterometallic complex, {[AgEr(C(6)H(4)NO(2))(2)(C(2)H(3)O(2))(H(2)O)]ClO(4)}(n), the eight-coordinate Er(III) ion adopts a distorted bicapped trigonal-prismatic geometry, being coordinated by four O atoms from four different isonicotinate ligands, three O atoms from two different acetate ligands and one O atom of the water molecule. The two-coordinate Ag(I) ion is surrounded by two N atoms from two different isonicotinate anions in a slightly bent configuration. These building blocks are connected by bridging isonicotinate and acetate ligands, generating a three-dimensional network. Ths structure is consolidated by O—H⋯O hydrogen bonding between the coordinated water molecule and a carboxylate group of the acetate ligand. The perchlorate anion is disordered over two sites with site-occupancy factors of 0.526 (13) and 0.474 (13), while the methyl group of the acetate ligand is equally disordered over two sites. |
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