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Poly[[μ(2)-acetato-aquadi-μ(3)-isonicotinato-erbium(III)silver(I)] perchlorate]

In the title three-dimensional heterometallic complex, {[AgEr(C(6)H(4)NO(2))(2)(C(2)H(3)O(2))(H(2)O)]ClO(4)}(n), the eight-coordin­ate Er(III) ion adopts a distorted bicapped trigonal-prismatic geometry, being coordinated by four O atoms from four different isonicotinate ligands, three O atoms from...

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Detalles Bibliográficos
Autor principal: Zhu, Li-Cai
Formato: Texto
Lenguaje:English
Publicado: International Union of Crystallography 2009
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2971902/
https://www.ncbi.nlm.nih.gov/pubmed/21578641
http://dx.doi.org/10.1107/S1600536809048429
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author Zhu, Li-Cai
author_facet Zhu, Li-Cai
author_sort Zhu, Li-Cai
collection PubMed
description In the title three-dimensional heterometallic complex, {[AgEr(C(6)H(4)NO(2))(2)(C(2)H(3)O(2))(H(2)O)]ClO(4)}(n), the eight-coordin­ate Er(III) ion adopts a distorted bicapped trigonal-prismatic geometry, being coordinated by four O atoms from four different isonicotinate ligands, three O atoms from two different acetate ligands and one O atom of the water mol­ecule. The two-coordinate Ag(I) ion is surrounded by two N atoms from two different isonicotinate anions in a slightly bent configuration. These building blocks are connected by bridging isonicotinate and acetate ligands, generating a three-dimensional network. Ths structure is consolidated by O—H⋯O hydrogen bonding between the coordinated water mol­ecule and a carboxyl­ate group of the acetate ligand. The perchlorate anion is disordered over two sites with site-occupancy factors of 0.526 (13) and 0.474 (13), while the methyl group of the acetate ligand is equally disordered over two sites.
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spelling pubmed-29719022010-12-30 Poly[[μ(2)-acetato-aquadi-μ(3)-isonicotinato-erbium(III)silver(I)] perchlorate] Zhu, Li-Cai Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers In the title three-dimensional heterometallic complex, {[AgEr(C(6)H(4)NO(2))(2)(C(2)H(3)O(2))(H(2)O)]ClO(4)}(n), the eight-coordin­ate Er(III) ion adopts a distorted bicapped trigonal-prismatic geometry, being coordinated by four O atoms from four different isonicotinate ligands, three O atoms from two different acetate ligands and one O atom of the water mol­ecule. The two-coordinate Ag(I) ion is surrounded by two N atoms from two different isonicotinate anions in a slightly bent configuration. These building blocks are connected by bridging isonicotinate and acetate ligands, generating a three-dimensional network. Ths structure is consolidated by O—H⋯O hydrogen bonding between the coordinated water mol­ecule and a carboxyl­ate group of the acetate ligand. The perchlorate anion is disordered over two sites with site-occupancy factors of 0.526 (13) and 0.474 (13), while the methyl group of the acetate ligand is equally disordered over two sites. International Union of Crystallography 2009-11-21 /pmc/articles/PMC2971902/ /pubmed/21578641 http://dx.doi.org/10.1107/S1600536809048429 Text en © Li-Cai Zhu 2009 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Metal-Organic Papers
Zhu, Li-Cai
Poly[[μ(2)-acetato-aquadi-μ(3)-isonicotinato-erbium(III)silver(I)] perchlorate]
title Poly[[μ(2)-acetato-aquadi-μ(3)-isonicotinato-erbium(III)silver(I)] perchlorate]
title_full Poly[[μ(2)-acetato-aquadi-μ(3)-isonicotinato-erbium(III)silver(I)] perchlorate]
title_fullStr Poly[[μ(2)-acetato-aquadi-μ(3)-isonicotinato-erbium(III)silver(I)] perchlorate]
title_full_unstemmed Poly[[μ(2)-acetato-aquadi-μ(3)-isonicotinato-erbium(III)silver(I)] perchlorate]
title_short Poly[[μ(2)-acetato-aquadi-μ(3)-isonicotinato-erbium(III)silver(I)] perchlorate]
title_sort poly[[μ(2)-acetato-aquadi-μ(3)-isonicotinato-erbium(iii)silver(i)] perchlorate]
topic Metal-Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2971902/
https://www.ncbi.nlm.nih.gov/pubmed/21578641
http://dx.doi.org/10.1107/S1600536809048429
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