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Poly[[μ(2)-acetato-aquadi-μ(3)-isonicotinato-erbium(III)silver(I)] perchlorate]
In the title three-dimensional heterometallic complex, {[AgEr(C(6)H(4)NO(2))(2)(C(2)H(3)O(2))(H(2)O)]ClO(4)}(n), the eight-coordinate Er(III) ion adopts a distorted bicapped trigonal-prismatic geometry, being coordinated by four O atoms from four different isonicotinate ligands, three O atoms from...
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Formato: | Texto |
Lenguaje: | English |
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International Union of Crystallography
2009
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Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2971902/ https://www.ncbi.nlm.nih.gov/pubmed/21578641 http://dx.doi.org/10.1107/S1600536809048429 |
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author | Zhu, Li-Cai |
author_facet | Zhu, Li-Cai |
author_sort | Zhu, Li-Cai |
collection | PubMed |
description | In the title three-dimensional heterometallic complex, {[AgEr(C(6)H(4)NO(2))(2)(C(2)H(3)O(2))(H(2)O)]ClO(4)}(n), the eight-coordinate Er(III) ion adopts a distorted bicapped trigonal-prismatic geometry, being coordinated by four O atoms from four different isonicotinate ligands, three O atoms from two different acetate ligands and one O atom of the water molecule. The two-coordinate Ag(I) ion is surrounded by two N atoms from two different isonicotinate anions in a slightly bent configuration. These building blocks are connected by bridging isonicotinate and acetate ligands, generating a three-dimensional network. Ths structure is consolidated by O—H⋯O hydrogen bonding between the coordinated water molecule and a carboxylate group of the acetate ligand. The perchlorate anion is disordered over two sites with site-occupancy factors of 0.526 (13) and 0.474 (13), while the methyl group of the acetate ligand is equally disordered over two sites. |
format | Text |
id | pubmed-2971902 |
institution | National Center for Biotechnology Information |
language | English |
publishDate | 2009 |
publisher | International Union of Crystallography |
record_format | MEDLINE/PubMed |
spelling | pubmed-29719022010-12-30 Poly[[μ(2)-acetato-aquadi-μ(3)-isonicotinato-erbium(III)silver(I)] perchlorate] Zhu, Li-Cai Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers In the title three-dimensional heterometallic complex, {[AgEr(C(6)H(4)NO(2))(2)(C(2)H(3)O(2))(H(2)O)]ClO(4)}(n), the eight-coordinate Er(III) ion adopts a distorted bicapped trigonal-prismatic geometry, being coordinated by four O atoms from four different isonicotinate ligands, three O atoms from two different acetate ligands and one O atom of the water molecule. The two-coordinate Ag(I) ion is surrounded by two N atoms from two different isonicotinate anions in a slightly bent configuration. These building blocks are connected by bridging isonicotinate and acetate ligands, generating a three-dimensional network. Ths structure is consolidated by O—H⋯O hydrogen bonding between the coordinated water molecule and a carboxylate group of the acetate ligand. The perchlorate anion is disordered over two sites with site-occupancy factors of 0.526 (13) and 0.474 (13), while the methyl group of the acetate ligand is equally disordered over two sites. International Union of Crystallography 2009-11-21 /pmc/articles/PMC2971902/ /pubmed/21578641 http://dx.doi.org/10.1107/S1600536809048429 Text en © Li-Cai Zhu 2009 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited. |
spellingShingle | Metal-Organic Papers Zhu, Li-Cai Poly[[μ(2)-acetato-aquadi-μ(3)-isonicotinato-erbium(III)silver(I)] perchlorate] |
title | Poly[[μ(2)-acetato-aquadi-μ(3)-isonicotinato-erbium(III)silver(I)] perchlorate] |
title_full | Poly[[μ(2)-acetato-aquadi-μ(3)-isonicotinato-erbium(III)silver(I)] perchlorate] |
title_fullStr | Poly[[μ(2)-acetato-aquadi-μ(3)-isonicotinato-erbium(III)silver(I)] perchlorate] |
title_full_unstemmed | Poly[[μ(2)-acetato-aquadi-μ(3)-isonicotinato-erbium(III)silver(I)] perchlorate] |
title_short | Poly[[μ(2)-acetato-aquadi-μ(3)-isonicotinato-erbium(III)silver(I)] perchlorate] |
title_sort | poly[[μ(2)-acetato-aquadi-μ(3)-isonicotinato-erbium(iii)silver(i)] perchlorate] |
topic | Metal-Organic Papers |
url | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2971902/ https://www.ncbi.nlm.nih.gov/pubmed/21578641 http://dx.doi.org/10.1107/S1600536809048429 |
work_keys_str_mv | AT zhulicai polym2acetatoaquadim3isonicotinatoerbiumiiisilveriperchlorate |