Poly[bis­[μ-1,4-bis­(imidazol-1-yl)butane]dicyanato­cadmium(II)]

The coordination geometry of the Cd(II) atom in the title complex, [Cd(NCO)(2)(C(10)H(14)N(4))(2)](n) or [Cd(NCO)(2)(bimb)(2)](n), where bimb is 1,4-bis­(imidazol-1-yl)butane, is distorted octa­hedral with the Cd(II) atom located on an inversion center and connected to four N atoms from the imidazol...

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Detalles Bibliográficos
Autores principales: Zhu, Xia, Guo, Ying, Zou, Yun-Ling
Formato: Texto
Lenguaje:English
Publicado: International Union of Crystallography 2009
Materias:
Metal-Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2971904/
https://www.ncbi.nlm.nih.gov/pubmed/21578557
http://dx.doi.org/10.1107/S1600536809043104
Descripción
Sumario:The coordination geometry of the Cd(II) atom in the title complex, [Cd(NCO)(2)(C(10)H(14)N(4))(2)](n) or [Cd(NCO)(2)(bimb)(2)](n), where bimb is 1,4-bis­(imidazol-1-yl)butane, is distorted octa­hedral with the Cd(II) atom located on an inversion center and connected to four N atoms from the imidazole units of four symmetry-related bimb ligands and two O atoms from two symmetry-related NCO(−) ligands. The Cd(II) atoms are bridged by four bimb ligands, forming a two-dimensional (4,4) network.

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