Poly[bis­[μ-1,4-bis­(imidazol-1-yl)butane]dicyanato­cadmium(II)]

The coordination geometry of the Cd(II) atom in the title complex, [Cd(NCO)(2)(C(10)H(14)N(4))(2)](n) or [Cd(NCO)(2)(bimb)(2)](n), where bimb is 1,4-bis­(imidazol-1-yl)butane, is distorted octa­hedral with the Cd(II) atom located on an inversion center and connected to four N atoms from the imidazol...

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Detalles Bibliográficos
Autores principales: Zhu, Xia, Guo, Ying, Zou, Yun-Ling
Formato: Texto
Lenguaje:English
Publicado: International Union of Crystallography 2009
Materias:
Metal-Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2971904/
https://www.ncbi.nlm.nih.gov/pubmed/21578557
http://dx.doi.org/10.1107/S1600536809043104
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author Zhu, Xia
Guo, Ying
Zou, Yun-Ling
author_facet Zhu, Xia
Guo, Ying
Zou, Yun-Ling
author_sort Zhu, Xia
collection PubMed
description The coordination geometry of the Cd(II) atom in the title complex, [Cd(NCO)(2)(C(10)H(14)N(4))(2)](n) or [Cd(NCO)(2)(bimb)(2)](n), where bimb is 1,4-bis­(imidazol-1-yl)butane, is distorted octa­hedral with the Cd(II) atom located on an inversion center and connected to four N atoms from the imidazole units of four symmetry-related bimb ligands and two O atoms from two symmetry-related NCO(−) ligands. The Cd(II) atoms are bridged by four bimb ligands, forming a two-dimensional (4,4) network.
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spelling pubmed-29719042010-12-30 Poly[bis­[μ-1,4-bis­(imidazol-1-yl)butane]dicyanato­cadmium(II)] Zhu, Xia Guo, Ying Zou, Yun-Ling Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers The coordination geometry of the Cd(II) atom in the title complex, [Cd(NCO)(2)(C(10)H(14)N(4))(2)](n) or [Cd(NCO)(2)(bimb)(2)](n), where bimb is 1,4-bis­(imidazol-1-yl)butane, is distorted octa­hedral with the Cd(II) atom located on an inversion center and connected to four N atoms from the imidazole units of four symmetry-related bimb ligands and two O atoms from two symmetry-related NCO(−) ligands. The Cd(II) atoms are bridged by four bimb ligands, forming a two-dimensional (4,4) network. International Union of Crystallography 2009-11-04 /pmc/articles/PMC2971904/ /pubmed/21578557 http://dx.doi.org/10.1107/S1600536809043104 Text en © Zhu et al. 2009 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Metal-Organic Papers
Zhu, Xia
Guo, Ying
Zou, Yun-Ling
Poly[bis­[μ-1,4-bis­(imidazol-1-yl)butane]dicyanato­cadmium(II)]
title Poly[bis­[μ-1,4-bis­(imidazol-1-yl)butane]dicyanato­cadmium(II)]
title_full Poly[bis­[μ-1,4-bis­(imidazol-1-yl)butane]dicyanato­cadmium(II)]
title_fullStr Poly[bis­[μ-1,4-bis­(imidazol-1-yl)butane]dicyanato­cadmium(II)]
title_full_unstemmed Poly[bis­[μ-1,4-bis­(imidazol-1-yl)butane]dicyanato­cadmium(II)]
title_short Poly[bis­[μ-1,4-bis­(imidazol-1-yl)butane]dicyanato­cadmium(II)]
title_sort poly[bis­[μ-1,4-bis­(imidazol-1-yl)butane]dicyanato­cadmium(ii)]
topic Metal-Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2971904/
https://www.ncbi.nlm.nih.gov/pubmed/21578557
http://dx.doi.org/10.1107/S1600536809043104
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